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1.
INTRODUCTIONHeterodinuclearcomplexesareofgreatim portanceforthestudyofthesynergisticeffectsfoundinbimetalliccatalysis (Adams,1 988;Reddyetal.,1 989;Zhengetal.,1 989;Werneretal.,1 992 ) ,whichindicateddistinc tiveelectronic ,electrochemicalandmagneticpropertiesarisingfro… 相似文献
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INTRODUCTION Chlorinated phenols compounds used widely in industry were intentionally or inadvertently released into environment in large quantities. These chlorin-ated aromatic compounds have strong resistance to physical, chemical and biological treatments and have been listed as a priority pollutant by the U.S. Envi-ronmental Protection Agency (Lin and Tseng, 1999). Wastewater containing chlorophenols has malodor-ous odor, high toxicity, bioaccumulation and car-cinogenic potential. … 相似文献
3.
自从Ziegler-Natta催化剂发现以来,人们已对该类催化剂作了许多的研究,以MgCl_2为载体的高效催化剂的巨大成功,引起了人们对载体和过渡金属元素的相互作用的浓厚兴趣,近年来许多文献和专利报道了对复合载体催化剂的大量的研究成果,似有可能出现具有更优特性的高效催化剂. 本文就复合载体催化剂的研究现状作一综述. 相似文献
4.
采用反相悬浮聚合法合成了聚丙烯酰胺-甲基丙烯酸(P(AM-co-MAA))微凝胶,并以其作为模板,通过热解法制备了一系列微米级、表面具有特异结构的P(AM-co-MAA)/SnO2有机-无机复合微球材料.详细考察了反应时间、SnCl4的浓度和热解温度等因素对复合微球的形貌结构的影响.通过SEM,XRD,FT-IR,TG等手段来表征复合微球的结构、形貌、含量.微球上沉积的SnO2层随着SnCl4的浓度增大而加厚.采用模板法制备复合材料具有操作过程简单、反应条件温和等特点,因此,可将此方法可进一步拓展到其他有机-无机复合材料的制备中. 相似文献
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The chaos characteristics of melt index have been first explored, and the Hilbert–Huang transform method and time delay embedding method are applied to multiscale dynamic analysis on the time series of the melt index (MI) in the propylene polymerization industry. The research results show that the embedding delay is 2, the embedding dimension is 5, the correlation dimension D2 is 1.57, and the maximum Lyapunov exponent is 0.143 for the melt index series, which provide clear evidence of chaotic multiscale features in the propylene polymerization process. Three intrinsic mode functions (IMFs) are decomposed from the melt index time series; the presence of non-integer fractal correlation dimension and positive finite maximum Lyapunov exponent are found in some IMF components. The PP melt index series are divided into two chaotic signals, a determined signal and a random signal respectively, and its complexity is therefore reduced. Furthermore, the coupling of subscale structures of the propylene polymerization is explored with the dimension of interaction dynamics and a robust algorithm for detecting interdependence. It is found that IMF(2) is the main driver in the coupling system of IMF(1)and IMF(2). All these provide a guideline for studying propylene polymerization process with chaotic multiscale theory and may offer more candidate tools to model and control propylene polymerization system in the future. 相似文献
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利用协同反应模型和EHCO-ASED量子化学方法,对具有不同侧基的固态二乙炔拓扑聚合反应的势能曲线进行了计算,并对其轨道对称性以及能隙随反应坐标的变化进行了分析。很好地解决了文献中用Woodward-Hoffmann轨道对称守恒原理对此类反应进行分析的结果与实验事实相矛盾的问题,指出了此类反应既是光允许,也可以是热允许的原因。对此类反应的侧基效应进行的研究结果表明,侧基电子亲和势的变化对该类反应的反应机理及活化能影响较小,但对产物热力学稳定性的影响则较为显著。 相似文献
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We report a case of a diabetic, heterozygote with near normal hematology, marginally low level of hemoglobin A2(HbA2) having an increased level of hemoglobin F(HbF) that was pancellularly distributed among the red cells. BioRad DiaSTAT measurements
gave a high glycated hemoglobin A1c(HbA1c) of 31.5% and the BioRad Variant analyzer recorded an HbA1c value which was very
low, in discordance with the detected blood glucose levels. Flow cytometry and polymerization chain reaction (PCR) based studies
were carried out which revealed the case to be that of the common hereditary persistence of fetal hemoglobin (HPFH)-3, an
Asian Indian mutation. Fructosamine estimation and HbA1c by Boronate affinity chromatography were able to resolve the discordant
value detected and was able to confirm the diabetes status. The case would have been a diagnostic dilemma, if reported without
correlation. 相似文献
9.
采用过氧化氢作为氧化剂制备聚合硫酸铁,探讨了硫酸用量、过氧化氢用量、反应温度这三个反应条件对产品各项质量指标的影响。结果表明,当硫酸与硫酸亚铁的摩尔比在0.31~0.41之间,过氧化氢与硫酸亚铁的摩尔比为2∶1,反应温度控制在20~35℃之间,制备所得的聚合硫酸铁的各项质量指标均符合国家标准。 相似文献
10.