液体混合物导热系数理想模型的建立及其应用

根据液体结构的特点,通过建立液体混合物导热系数的理想模型,发展了计算混合液体导热系数的新方法.对288种含水和非水液体混合物2 060个数据点的拟合结果表明,计算值与实验值的一致性令人满意,平均误差0.98%,计算精度优于文献方法.据此发展了一种根据纯物质导热系数预测混合液体导热系数的方法,预测结果的平均误差为1.69%,小于文献方法的误差.

An Ideal Model of Liquid Mixture for Thermal Conductivity and Its Application

Based on the characteristics of liquid structure,a new method which can be used to calculate the thermal conductivity of liquid mixtures was developed by means of establishing an ideal model of liquid mixture.The results showed that the calculated values of thermal conductivity were in good agreement with the experimental data,and the mean deviation was 0.98% for 288 kinds of aqueous mixtures and non-aqueous mixtures,and had an advantage over the existing methods.An effective predicting method was also proposed which can be used to predict the thermal conductivity of liquids mixtures from the information of pure components,and the mean relative deviation were 1.69% for 288 kinds of aqueous mixtures and non-aqueous mixtures with 2060 data points.