| [Cu_2(C_8H_7O_2N_2)_4(C_(12)N_2H_8)_2]的合成及晶体结构解析 |
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| 引用本文： | 梁国营.[Cu_2(C_8H_7O_2N_2)_4(C_(12)N_2H_8)_2]的合成及晶体结构解析[J].德州学院学报,2009,25(2). |
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| 作者姓名： | 梁国营 |
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| 作者单位： | 山东省高校生物物理重点实验室,山东德州,253023 |
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| 摘 要： | 用苯乙酸做配体合成了苯乙酸铜的配合物,在配合物中,三个苯乙酸根参与配位,而一个苯乙酸根做为平衡离子存在于晶体中,邻啡罗啉提供两个N原子参与配位,形成铜的五配位双核配合物.分子内氢键和分子间氢键将分子连接成三维网状结构.
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| 关 键 词： | 铜 苯乙酸 合成 晶体结构 |
Synthesis and Structure of [Cu_2(C_8H_7O_2N_2)_4(C_(12)N_2H_8)_2] |
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| LIANG Guo-ying.Synthesis and Structure of [Cu_2(C_8H_7O_2N_2)_4(C_(12)N_2H_8)_2][J].Journal of Dezhou University,2009,25(2). |
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| Authors: | LIANG Guo-ying |
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| Institution: | Key Lab of Biophysics in University of Shandong;Dezhou Shandong 253023;China |
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| Abstract: | The compound Cu2(C8H7O2N2)4(C12N2H8)2 is compoused by phenylacetate it is blue crystal,in Cu2(C8H7O2N2)4(C12N2H8)2 three of the phenylacetate anions acted as ligands,two phen offer N atoms.There are hydrogen bonds that make the units join together to form a long line. |
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| Keywords: | copper phenylacetate synthesis crystal structure |
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