胆酸分子印迹的PDVB/PTAIC IPN的合成及其吸附性能 |
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引用本文: | 黄淑芳,;朱卓越,;邓敏超.胆酸分子印迹的PDVB/PTAIC IPN的合成及其吸附性能[J].娄底师专学报,2009(2):18-20. |
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作者姓名: | 黄淑芳 ;朱卓越 ;邓敏超 |
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作者单位: | [1]长沙环境保护职业技术学院,湖南长沙410004; [2]湖南中烟公司,湖南长沙410004; [3]湖南人文科技学院,湖南娄底417001 |
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摘 要: | 将异氰尿酸三烯酯和致孔剂溶胀到磺化聚二乙烯基苯树脂球中,通过悬浮聚合合成了胆酸分子印迹和非分子印迹的大孔聚二乙烯基苯/聚异氰尿酸三烯酯互穿聚合物网络(PDVB/PTAIC IPN)珠体,测定两种IPN的结构及其对胆酸的吸附性能。结果表明,两种IPN的物理和化学结构相近,但分子印迹IPN对印迹分子具有较好吸附作用,从而实现了以较简单的方法合成分子印迹效果好的大孔交联聚合物。
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关 键 词: | 分子印迹 互穿聚合物网络 聚二乙烯基苯 异氰尿酸三烯酯 胆酸 吸附 |
Synthesis and Adsorption Properties on PDVB/PTAIC IPN of Acid Molecula Imprint |
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Institution: | HUANG Shu-fang, ZHU Zhuo-yue, DENG Ming-chao ( 1. Changsha Vocational and Technical School of Environmental Protection, 410004, China; 2. Tobacco Company in Hunan, Changsha, 410004, China; 3. Hunan Institute of Humanities, Science and Technology, Loudi, 417001 ,China) |
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Abstract: | Triene acid esters and swelling porogen to DVB Sulfonated poly resin ball through suspension polymerization acid synthesized molecularly imprinted and non - molecularly imprinted macroporous poly vinyl benzene / poly iso triene acid ester interpenetrating polymer networks ( PDVB / PTAIC IPN) beads body, determined the structure of the two IPN and its effect on the adsorption properties of acid. The results showed that two types of IPN' s physical and chemical structure similar to, but molecularly imprinted IPN for molecular imprinting has good adsorption in order to achieve a synthesis of relatively simple methods and effective molecularly imprinted macrooporous cross - linked polymer. |
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Keywords: | molecular imprint IPN poly vinyl benzene triene acid ester acid adsorption |
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