| 2,3-二氨基-9,10-二氮(杂)蒽超分子化合物的合成及晶体结构 |
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| 引用本文： | 李云平,吴海霞,杜巧云.2,3-二氨基-9,10-二氮(杂)蒽超分子化合物的合成及晶体结构[J].洛阳师范学院学报,2008,27(5). |
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| 作者姓名： | 李云平 吴海霞 杜巧云 |
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| 作者单位： | 洛阳师范学院化学化工学院,河南,洛阳,471022 |
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| 基金项目： | 河南省教育厅资助项目 |
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| 摘 要： | 一个新的三维超分子化合物(C12N4H10)(C12N4H11)Cl](H2O)7通过溶液法合成。该化合物为三斜晶系,P-1空间群,晶胞参数:a=7.1350(14),b=12.594(2),c=16.210(3),α=82.675(3)°,β=78.588(3)°,γ=84.198(3)°,V=1411.8(5)3,Z=2,Dc=1.372Mg.m-3,F(000)=616,Mr=583.05,最终偏离因子R1=0.0798,wR2=0.2100。化合物通过O-H…O,O-H…Cl,O-H…N,N-H…O和N-H…Cl多种氢键作用连接成三维超分子结构。
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| 关 键 词： | 邻苯二胺 氮(杂)蒽 晶体结构 超分子 |
Synthesis and Structure of Supramolecular Compound Constructed by Hydrogen Bond with 2, 3 - Diamino -9,10 - Di - Naphthazine |
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| LI Yun-ping,WU Hai-xia,DU Qiao-yun.Synthesis and Structure of Supramolecular Compound Constructed by Hydrogen Bond with 2, 3 - Diamino -9,10 - Di - Naphthazine[J].Journal of Luoyang Teachers College,2008,27(5). |
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| Authors: | LI Yun-ping WU Hai-xia DU Qiao-yun |
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| Institution: | LI Yun-ping; WU Hai-xia; DU Qiao-yun(College of Chemistry and Chemical Engineering; Luoyang Normal University; Luoyang 471022; China); |
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| Abstract: | A novel supramolecular compound(C12N4H10) (C12N4H11)Cl](H2O)7 have been synthesized by solution method and structurally characterized by X-ray diffraction analysis.It crystallizes in the thrclinic system,space group P-1,with a=7.1350(14),b=12.594(2),c=16.210(3),α=82.675(3)°,β=78.588(3)°,γ=84.198(3) °,V=1411.8(5)3,Z=2,Dc=1.372Mg.m-3,F(000)=616,Mr=583.05,R1=0.0798,wR2=0.2100.X-ray diffraction analysis reveals that a 3D extended supermolecular network was formed though O-H…O,O-H…Cl,O-H…N,N-H…O and N-H…Cl ... |
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| Keywords: | 1 2-phenylenediamine naphthazine crystal structure supramolecular |
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