| (C_6H_6ClNO_3S)_2(H_2O)_2的合成和晶体结构 |
| |
| 引用本文： | 王哗,马宁.(C_6H_6ClNO_3S)_2(H_2O)_2的合成和晶体结构[J].洛阳师范学院学报,2011,30(5):56-58. |
| |
| 作者姓名： | 王哗 马宁 |
| |
| 作者单位： | 洛阳师范学院化学化工学院,河南,洛阳,471022 |
| |
| 摘 要： | 合成了一种新的化合物(C6H6C lNO3S)2(H2O)2,测定了其结构.晶体数据表明该配合物属三斜晶系,P-1空间群,晶胞参数为:a=5.8626(8),b=11.7993(17),c=12.7680(18),α=88.286(2)°,β=87.534(2)°,γ=84.121(2)°,V=877.5(2)3,Z=2,Dc=1.708 mg/m3,Rgt(F)=0.0418,wR2(F2)=0.0974,F(000)=464,数据完整度为99.3%,标题化合物含有3种氢键,形成一种三维网状的稳定结构.
|
| 关 键 词： | 3-氨基-4-氯苯磺酸 合成 晶体结构 |
Synthesis and Crystal Structure of(C6H6ClNO3S)2(H2O)2 |
| |
| WANG Ye,MA Ning.Synthesis and Crystal Structure of(C6H6ClNO3S)2(H2O)2[J].Journal of Luoyang Teachers College,2011,30(5):56-58. |
| |
| Authors: | WANG Ye MA Ning |
| |
| Institution: | WANG Ye,MA Ning(College of Chemistry and Chemical Engineering,Luoyang Normal University,Luoyang 471022,China) |
| |
| Abstract: | The title complex, （（C6H6ClNO3S）2（H2O）2, was synthesized. The crystal structure of the complex was determined by X-ray single crystal diffraction. Its crystal belongs to triclinic with space group P-1, a = 5. 8626 （8） A^°, b =11.7993（17）A^°, c =12.7680（18） A,α =88.286（2）°, β= 87.534（2）°, γ = 84. 121（2）°, V= 877.5（2）A^°3, Z=2, Dc=1.798mg/m^3, F（000） =464, R 1（F） = 0.0418, wR2（F2） = 0.0974. There are three kind of hydrogen bonds, and an extended two-dimensional network of hydrogen bonds contributes to the stabil- ity structure. |
| |
| Keywords: | 3-animo-4-chlorobenzenesulphonic acid synthesis crystal structure |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
