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溶剂调控谷氨酸衍生物自组装纳米结构的研究
引用本文:程林秀,刘威,刘春华,范玉兰,李亿保,李勋,范小林.溶剂调控谷氨酸衍生物自组装纳米结构的研究[J].赣南师范学院学报,2014(6):27-29.
作者姓名:程林秀  刘威  刘春华  范玉兰  李亿保  李勋  范小林
作者单位:赣南师范学院化学化工学院,江西赣州,341000
基金项目:国家自然科学基金(21303024,21365003,21463003);江西省教育厅项目
摘    要:通过调节溶剂中水的比例来调控N,N'-二谷氨酸-3,4,9,10-苝四甲酸二酰亚胺(GP)的自组装行为.通过扫描电子显微镜(SEM)、红外和紫外等手段对组装结构进行了表征.结果表明溶剂对N,N'-二谷氨酸-3,4,9,10-苝四甲酸二酰亚胺(GP)自组装过程影响较为显著,导致形成不同组装纳米结构.这归因于水溶剂参与了分子间的组装过程,从而调节了分子间的相互作用力.

关 键 词:N  N'-二谷氨酸-3  4  9  10-苝四甲酸二酰亚胺  溶剂诱导  纳米结构

Solvent Tuned Glutamic Derivatives into Biologic Self?Assembled Nanostructures
CHENG Linxiu,LIU Wei,LIU Chunhua,FAN Yulan,LI Yibao,LI Xun,FAN Xiaolin.Solvent Tuned Glutamic Derivatives into Biologic Self?Assembled Nanostructures[J].Journal of Gannan Teachers' College(Social Science(2)),2014(6):27-29.
Authors:CHENG Linxiu  LIU Wei  LIU Chunhua  FAN Yulan  LI Yibao  LI Xun  FAN Xiaolin
Institution:(Key Laboratory of Organo-pharmaceutical Chemistry, Gannan Normal University, Ganzhou 341000, China)
Abstract:The self-assembly behavior of N, N'-diglutamate -3,4, 9, 10-peryleneimide (GP) were tuned by controlled ratio of wa- ter in solvent. The self-assembly structures were investigated by means of Scanning Electron Microscopy ( SEM), Fourier Transform In- frared Spectroscopy (FTIR) and Ultraviolet Spectra (UV). The results demonstrate that solvent deeply affects the self-assembly of GP molecules, which lead to different nanostructures. This phenomenon was due to the participation of water in self-assembly of GP mole- cules, thus tuned the interactions between molecules.
Keywords:N  N'-diglutamate -3  4  9  10-peryleneimide  Solvent induced  nanostructure
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