首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 125 毫秒
1.
凝胶法制备了Nd离子掺杂TiO2纳米颗粒,采用X射线衍射(XRD)表征了催化剂的晶体结构·以甲基橙为有机底物,测试了Nd掺杂TiO2纳米颗粒光催化活性·结果表明:二氧化钛的主要晶相为锐钛矿相,Nd掺杂可阻止晶相转移·Nd掺杂量为1·5%时,催化活性最高,达到90%以上·  相似文献   

2.
采用溶胶-凝胶法制备了系列La3+掺杂的纳米TiO2,用X射线衍射(XRD)、扫描电镜(SEM)、X-射线能谱仪(EDS)等测试方法对催化剂进行表征,并以甲基橙溶液为降解目标,测定其紫外光光催化活性.结果表明:La3+的掺杂能有效抑制TiO2纳米颗粒的增长,提高晶相转变温度;稀土La3+的掺杂能有效提高TiO2纳米粉体的光催化活性,最佳初始掺杂物质的量比为0.02%.  相似文献   

3.
在通过溶胶-凝胶法制备出铜和氮共掺杂的纳米二氧化钛(TiO2)的基础上,利用XRD和UV-Vis光谱等技术对其结构、掺杂效果、光催化活性等进行了表征,结果表明,掺入了铜和氮的纳米TiO2结构为锐钛矿晶型,其吸收阈值达到590nm,可见光吸收率比未掺杂的纳米TiO2有了很大提高,最终导致其光催化降解二甲酚橙的活性得到显著增强.  相似文献   

4.
铝改性纳米二氧化钛的制备及其光催化性能   总被引:1,自引:0,他引:1  
采用溶胶-凝胶法制备Al3+掺杂纳米TiO2光催化剂,以亚基蓝为污染物,在160W的高压汞灯下,考察了Al3+掺杂对TiO2光催化性能的影响,并通过XRD对其结构进行了表征。结果表明:Al3+掺杂能够提高了TiO2光催化活性;Al3+-TiO2的最佳制备条件为硝酸铝为掺杂前驱体,r(Al:Ti)为0.01,焙烧温度500℃时光催化活性最佳。  相似文献   

5.
通过溶胶-凝胶法制备了稀土金属离子Y^3+掺杂的TiO2光催化剂,用XRD进行了分析和表征.以紫外灯为光源,通过对结晶紫的降解反应,研究了掺杂稀土离子钇的TiO2催化活性.结果表明,Y^3+的掺杂减小了TiO2的粒径,提高了TiO2的光催化活性,反应体系在Y^3+掺杂量为1.2%,催化剂用量1.5g/L,经500℃煅烧的条件下制备的Y^3+-TiO2催化下效果最好.降解浓度4.0mg/L结晶紫2小时后,降解率可达90%.  相似文献   

6.
稀土掺杂TiO2光催化剂的制备及其光催化活性的研究   总被引:4,自引:0,他引:4  
采用溶胶-凝胶法和浸渍法制备稀土掺杂TiO2光催化剂RE/TiO2(RE=Pr、Nd、Gd、Er),利用XRD、BET、DRS、SPS等手段进行表征,研究了稀土掺杂对TiO2的晶相结构、比表面积、吸光性能的影响,考察了RE/TiO2催化剂降解C2H4的气-固相光催化氧化反应性能.结果表明:掺杂适量的稀土离子可以抑制锐钛矿晶型向金红石晶型转变,细化晶粒,增加比表面积,提高光催化活性.  相似文献   

7.
二氧化钛溶胶体系光催化降解甲基橙研究   总被引:1,自引:0,他引:1  
以无机钛源为原料,通过共沉淀-解胶法制备了Ce4 -TiO2,Nd3 -TiO2、La3 -TiO2溶胶及纯溶胶光催化剂.利用XRD表征所制溶胶均为锐钛矿溶胶,利用8W-黑光灯(UVA)作为光源,以甲基橙为目标降解物,研究了前驱物及稀土掺杂对溶胶光催化降解效果的影响,研究发现:以不同原料所制溶胶的降解效率高低依次为H2TiO3>TiCl4>TiOSO4>Ti(SO4)2;以偏钛酸为原料的稀土掺杂溶胶均表现较高的降解效果,其中1% Ce4 掺杂80分钟降解率达到了98.99%.  相似文献   

8.
以无机钛源为原料,通过共沉淀-解胶法制备了Ce4 -TiO2,Nd3 -TiO2、La3 -TiO2溶胶及纯溶胶光催化剂.利用XRD表征所制溶胶均为锐钛矿溶胶,利用8W-黑光灯(UVA)作为光源,以甲基橙为目标降解物,研究了前驱物及稀土掺杂对溶胶光催化降解效果的影响,研究发现:以不同原料所制溶胶的降解效率高低依次为H2TiO3>TiCl4>TiOSO4>Ti(SO4)2;以偏钛酸为原料的稀土掺杂溶胶均表现较高的降解效果,其中1?4 掺杂80分钟降解率达到了98.99%.  相似文献   

9.
纳米TiO2因其禁带宽和光生电子与空穴容易复合,而表现出较低的光催化活性,阻止了光催化剂纳米TiO2走向实用化.介绍了利用掺杂与共掺杂、金属与非金属掺杂手段对纳米TiO2进行改性的方法,对进一步扩大纳米TiO2的应用范围,实现纳米TiO2的工业化应用奠定了基础.  相似文献   

10.
采用溶胶-凝胶法制备碳铈共掺杂的纳米二氧化钛(C—Ce-TiO2)光催化剂,经X一射线粉末衍射(XRD)、扫描电子显微镜(SEM)和紫外-可见漫反射光谱(Uv-Vis-DRS)表征,在9W日光灯照射下,催化降解高效氟氯氰菊酯.结果表明:C—Ce—TiO2在可见光区吸光度提高,其禁带宽度比未掺杂的二氧化钛小,XRD显示制备得到的C—Ce—TiO2主要为锐钛矿晶型,光催化降解试验发现C—Ce—TiO2对高效氟氯氰菊酯的降解能力高于纳米二氧化钛,降解率可达92%左右.  相似文献   

11.
《海外英语》2007,(5):44-45
It is worthy of noting that, whilst Crookston Castle witnessed the earlier and happier portion of Mary's variegated life,  相似文献   

12.
一、吃和喝吃苹果 eat an apple, 吃药 take medicine,吃糖 have some sweets,吃饭 have one's meals,吃馆子 dine out,吃惊 be surprised/  相似文献   

13.
《海外英语》2007,(5):10-11
Many college freshmen arrive woefully unprepared to do college work, and as disadvantaged populations continue to grow, the share of the American work force that has made it through college is expected to plummet. Many experts blame that educational failure not just on high schools but also on colleges. School & College, a special report by The Chronicle, looks at efforts to fix the system. What reforms would better prepare students for college? What should schools and colleges be doing differently? How should state and federal officials help?  相似文献   

14.
The communication of people partially is the communication of cultures. Culture has a direct effect on international commercial activities in all aspects. Different conceptions about time, space, equality, law and the like, lead people to deal with things in different ways. So to know cultures of the counterpart is to facil-itate our enterprises so as to have a smooth and successful communication in commercial activity.  相似文献   

15.
《海外英语》2007,(4):36
There are numbers of crossroads on our long and unpredictable life journey where we totally have no idea about which direction to choose. No matter what our decision is, we should not turn back, but face the music and go ahead instead. I am this kind of girl who always does try without regretting, one example is how I dealt with my love.  相似文献   

16.
王菲 《华章》2007,(12):273-273
Migration occurs behind a variety of reasons and has a great effect on the whole world. People may migrate in order to improve their economic situation, or in order to escape civil strife, persecution, and environmental disasters. The impact of migration is complex, bringing both benefits anddisadvantages. This paper briefly talks about the causes of migration, the allocation of benefits, and the ways in which individual countries and the international community deal with this important subject.  相似文献   

17.
风的曲线     
Rosco and I wait for the fishermen to return.I sit at a wooden bench near the store at Mt.Baker Resort and watch the clouds change shape. Rosco has my belt around his neck and an eight foot tow chain hooked to a tree. Dogs must be on a leash. Ducks and rabbits are loose.  相似文献   

18.
裴水妹 《华章》2007,(11):196
Sister Carrie is one of the most controversial characters in American literature.Thought as a "fallen woman" firstly,she was defined as a "new woman" by some critics later. However, by digging into the motivaton behind the whole process of Carrie's "success", the relationship between Carrie and her creator (the author), the social conditions of then American, it can be found that Carrie has never been free-standing on her thought and she has never found her real-sdf even after becoming a famous actress. In a society dominated by mass consumerism Carrie is only an adherent of her own desires. She also is a representative of all those country girls flooded into cities, a symbol and a sacrifice of the urbanization of America in a time countryside was overcome by cities.  相似文献   

19.
20.
1.IntroductionOne-cyclecontrolmethod,whichwasproposedaboutonedecadeago[1],hasbecomeanattractivemethodinspecialfieldssuchaspowerfactorcorrection[2-6],switchingamplifiers[7,8],etc.Themainideaofthiscontrollerisbasedonintegrationofdiodevoltageinone-cycleandforcesittobeexactlyequaltothereferencevalue.Themainadvantageofthiscontrollerisitsrealtimeabilitytorejectthevariationofinputvoltage[1].Despitethisgreatability,ithasnogoodperformancesinrejectingofloaddisturbanceandfollowingreferencecommands.Espec…  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号