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J.L. Finck 《Journal of The Franklin Institute》1938,225(4):411-435
This paper considers the fundamental assumptions involved in thermodynamic theory concerning states of physico-chemical equilibrium, and considers the possibility of enlarging the assemblage of states by including states outside those of the range of the mass-action law, and also states of supersaturation. Catalysis is introduced as a new factor, and it is found that this makes it possible to enlarge the scope of thermodynamics. This thought is developed and it is shown that a single gaseous phase is thermodynamically analogous to a liquid-vapor system. Clapeyron-Clausius equation is generalized to apply to reactions in the gaseous phase, and it is shown that Van't Hoff's reaction isochore is a special case of the former equation.It is shown how this theory can explain in a simple manner, endothermic and exothermic reactions, and the critical point. 相似文献
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由于电子商务的迅速发展产生了一系列新的社会关系,而传统的法律对这种新兴利益的调整具有滞后性。试图以域名纠纷与隐私权为全我对此进行探讨并提出立法建议。 相似文献
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《Journal of The Franklin Institute》1969,287(3):261-265
Schrödinger's equation is solved to first-order accuracy in the charge for approximate vacuum, one-electron, and one-photon dressed stationary states. 相似文献
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Schaffer S 《Isis; an international review devoted to the history of science and its cultural influences》2011,102(4):706-717
There has been much scholarly attention to definitions of the term "scientific instrument." Rather more mundane work by makers, curators, and users is devoted to instruments' maintenance and repair. A familiar argument holds that when a tool breaks, its character and recalcitrance become evident. Much can be gained from historical study of instruments' breakages, defects, and recuperation. Maintenance and repair technologies have been a vital aspect of relations between makers and other users. Their history illuminates systems of instruction, support, and abuse. These systems were, for example, evident in the development of astronomical instruments around 1800 within and beyond the European sphere. Episodes from that milieu are used to explore how instrument users sought autonomy, how instruments' mutable character was defined, and how judgments of instruments' failure or success were ever secured. 相似文献
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