云南宾川-永胜-丽江地区低钛玄武岩和苦橄岩的岩石成因与源区性质

云南宾川-永胜-丽江地区是峨眉山玄武岩厚度最大、喷发最早的地区，最主要的岩石类型是低钛和高钛玄武岩，并有少量摘要云南宾川-永胜-丽江地区是峨眉山玄武岩厚度最大、喷发最早的地区，最主要的岩石类型是低钛和高钛玄武岩，并有少量的苦橄质玄武岩、苦橄岩和麦美奇岩。大部分火山岩的岩石化学组成属于拉斑玄武岩系列，少数低钛玄武岩属碱性玄武岩系列。它们不同程度地富集大离子亲石元素和轻稀土元素，相对亏损重稀土元素，稀土元素分馏明显，显著亏损相容元素（Co，V，Cr，Ni）。陆壳物质对低钛玄武岩浆的混染程度明显大于对苦橄质岩浆的影响程度。而且混染作用对于Sr同位素和大离子亲石元素的影响程度明显大于对Nd同位素和稀土元素的影响程度。Nd和Sr同位素证明，混染物主要是下地壳变质岩，也有少量上部陆壳物质。未受混染的样品具有适度亏损的Nd、Sr同位素组成。低钛玄武岩和苦橄岩类岩石是不同原生岩浆分异演化的产物。低钛玄武岩的原生岩浆是高镁拉斑玄武岩浆，原生苦橄质岩浆以EM-55为代表（MgO=16．56％）。此外，还有一种比EM-55更富镁的原生岩浆。高镁拉斑玄武岩浆分异过程中的主要分离结晶相／堆晶相是单斜辉石，并有少量斜长石。苦橄岩浆分异过程中的主要分离结晶相／堆晶相是橄榄石，并有少量单斜辉石。参考相关的实验岩石学成果，可以证明，地幔柱源区由两种岩石组成：一种是50％榴辉岩和50％橄榄岩反应形成的石榴石辉石岩，另一种是橄榄岩。在地幔柱绝热上升过程中，位于其轴部的石榴石辉石岩的熔融作用始于≈165km，主要的熔融作用发生于165～128km，持续到66km。熔融产物为苦橄岩浆。橄榄岩的部分熔融始于≈150km，持续到66km，熔融产物是比EM-55更富镁的岩浆。地幔柱头部的熔融作用始于≈100km，终止于66km，主要的熔融作用发生于尖晶石稳定域，熔融产物为低钛玄武岩浆。     

花岗岩混合问题:与玄武岩对比的启示——关于花岗岩研究的思考之一

最近,花岗岩混合成了花岗岩研究的热点,国内外许多学者探讨了花岗岩混合问题,并尝试用不同端元组分不同比例的混合来解释花岗岩的地球化学变化.本文从花岗岩与玄武岩的对比出发,探讨了花岗岩混合的可能性和局限性.作者认为,花岗岩混合的现象是普遍存在的,但是次要的和局部的.岩浆混合的能力或能干性(competence of mixing)主要取决于岩浆的黏性和温度,而黏性又与硅氧四面体有关.相对于玄武岩,花岗岩的SiO2含量高,温度低,因此,花岗质岩浆的混合能干性很低.玄武质岩浆的混合是mixing(以化学混合为主),而花岗质岩浆的混合通常只是mingling(以机械混合为主),只有在少数情况下才能达到mixing的程度,例如,埃达克岩与地幔混合形成的高镁安山岩或高镁埃达克岩.许多人认为,花岗岩中的暗色微粒包体是花岗质岩浆混合作用最显著、最直接证据.研究表明,花岗岩中的暗色微粒包体大多是闪长质成分的,其初始成分大多是玄武质的.因此,暗色微粒包体不是花岗质岩浆混合作用最显著、最直接证据,而是玄武质岩浆混合能力强过花岗质岩浆的证据.与玄武质岩浆的起源比较,花岗质岩浆从一开始熔融就是不均一的,这源于源区的不均一及熔融过程的复杂性.花岗质岩浆原始均一性的假定是不可能的.花岗岩成分的变化以及在哈克图解中成分点的"连续谱系",主要是由源区不均一性引起的,混合和分异可能有一定的作用,但毕竟是次要的.花岗质岩浆从源区生成、迁移、直至在地表喷出或在浅部定位的全过程,是一个不断均一化和不均一化的过程.但是,由于花岗质岩浆的黏性大,上述过程及岩浆演化的程度和规模都受到限制,也限制了岩浆混合的程度和规模.许多人仅从花岗岩地球化学成分的变化来研究花岗岩的成因,而很少考虑花岗岩物理性质对岩浆演化的制约.对比玄武岩与花岗岩,我们认为,地球化学方法在花岗岩中应用的范围和程度可能远远不及玄武岩,我们应当重新考虑花岗岩的地球化学应用问题.     

华北龙岗第四纪玄武岩：岩石成因和源区性质

华北克拉通东北缘龙岗第四纪玄武岩的地球化学研究为大陆碱性玄武岩的成因以及源区的性质提供了重要的依据.龙岗第四纪玄武岩为碱性玄武岩,具有类似OIB的REE和微量元素分配特征.岩石的Sr-Nd同位素轻度亏损（87Sr/86Sr =0.7044～0.7048,εNd=0.6～2.1）,具有Dupal异常的高放射性成因Pb同位素组成（^206 Pb/^204 Pb=17.734～18.194,^207 Pb/^204 Pb=15.553～15.594,^208 Pb/%204 Pb=38.322～38.707）.这种地球化学特征指示了原始岩浆起源于＜70km深度的地幔,并经历了一定程度的橄榄岩、单斜辉石和钛.铁氧化物的结晶分异.岩浆源区中以来类似MORB软流圈物质的熔体为主,另外有少量来自EM Ⅰ性质的富集岩石圈地幔以及俯冲流体/熔体的物质贡献,显示了深部岩石圈-软流圈一定程度的相互作用以及太平洋板块俯冲的影响.岩浆源区多种端元组分的存在表明该地区岩石圈的减薄/置换受到多种因素的影响.     

塔里木板块东北部柳园粗面玄武岩带：软流圈地幔减压熔融的产物

在塔里木东北部，甘肃省西部敦煌市柳园镇南侧，有一条近东西向展布的粗面玄武岩带，长度约150kin，宽度达10km，厚度为1900m。这条粗面石玄武岩带属下二叠统哲斯群，岩浆喷发方式以裂隙式溢流为主，枕状构造特别发育。在玄武岩层间夹有很薄的酸性凝灰岩和沉凝灰岩层，属典型的双峰式火山岩组合。按照岩石化学组成的TAS分类命名，主要岩石类型为玄武岩、夏威夷岩和橄榄粗安岩。主要造岩矿物为钠长石（Ab91～100）和普通辉石。普通辉石斑晶、钠长石斑晶和部分基质中的钠长石具有中空结构，并被层状硅酸盐微晶充填。这些岩石基本属碱性玄武岩系列和过渡型系列，大部分属演化的岩浆。演化程度较低的样品具有轻稀土元素亏损型配分曲线，微量元素地球化学具有MORB亲和性，εNd（t）-＋10．14～10．89。玄武质岩浆与陆壳物质之间有较轻的同化混染作用。普通辉石、铁钛氧化物的分离结晶作用是岩浆演化的主要机制。玄武质岩浆源区属于软流圈地幔．部分熔融发生于尖晶石稳定域．是软流圈地幔减压（上涌）熔融的产物。     

赣南中侏罗世正长岩-辉长岩的起源及其地质意义

正长岩-辉长岩组合的形成通常与板内伸展构造有关,它们可由同源岩浆演化形成,也可以由两种独立起源的岩浆结晶形成.本文选择赣南晚中生代早期黄埠正长岩和车步辉长岩进行了详细的年代学和岩石地球化学研究,旨在探讨它们的起源及其与岩石圈地幔演化的关系.LA-ICP-MS锆石U-Pb定年结果表明：黄埠正长岩和车步辉长岩形成于≈178Ma,为同时期岩浆作用的产物.主量元素、微量元素和Nd同位素地球化学特征表明它们并非由同源岩浆演化形成.初步研究表明,黄埠正长岩和车步辉长岩可能都起源于受软流圈来源熔体交代富集的岩石圈地幔,熔融发生在上地幔尖晶石-石榴石相转换带深度,且岩浆在结晶演化过程中发生了较低程度的地壳混染作用.与车步辉长岩相比,黄埠正长岩有高的不相容元素含量、Ce/Yb、La/Yb、Sm/Yb比值和高的εNd（t）值,表明黄埠正长岩的岩浆起源相对更深,且其岩石圈地幔源区经历了更高程度的交代作用.因此,赣南正长岩-辉长岩是板内伸展构造背景下,不同程度软流圈-岩石圈相互作用的反映.     

广西合浦烟墩岭火山岩的K-Ar年代学和地球化学初步研究

广西合浦县烟墩岭火山是一座第四纪小型中心式喷发的火山,是我国华南火山在第四纪喷发活动的代表之一.烟墩岭火山岩岩性为粗面玄武岩,Mg#值（59～69）中等偏高,而钛和碱质成分相对较高.烟墩岭火山岩及周边的烟头岭样品的稀土含量较为稳定,配分型式极其相似,几乎一样,REE丰度模式呈稍陡的向HREE倾斜的轻稀土富集型.它们的微量元素原始地幔配分型式也很相似,暗示有共同的岩浆源区.烟墩岭火山岩的Ba/Nb比值变化范围远小于琼北和涠洲岛玄武岩,而La/Nb比值三者相近,都是低而稳定,与洋岛玄武岩数值接近,不相容元素Nb/U-Th图解也说明烟墩岭火山岩来自于类似于洋岛玄武岩的地幔源区.岩石学和地球化学化学证据都表明,烟墩岭地区火山岩虽不是原生地幔玄武岩浆的喷出物,但只经过低程度演化,未受到强烈的结晶分异的影响,也未受到地壳的混染.其^87 Sr/^86 Sr和^143 Nd/^144 Nd数据变化范围很小,具有低Sr同位素比值和高Nd同位素比值的特点.本文采用火山岩K-Ar法测定了烟墩岭火山活动的时代,结合火山岩地质特征和前人资料,火山活动时代确定为第四纪早更新世,与北部湾涠洲岛早期火山活动及琼北早更新世多文岭期火山活动时代大致相当.     

浅析内蒙古集宁地区新生代玄武岩基本特征

本文主要研究了内蒙古集宁地区新生代玄武岩的特征,为探讨新生代岩浆作用过程、岩浆源区及岩石产生的地球动力学环境奠定了基础.     

花岗岩结晶分离作用问题——关于花岗岩研究的思考之二

岩浆结晶分离作用是一个古老的话题,很早就有学者指出,地球内部生成的岩浆大多是玄武质岩浆,大多数花岗岩是由玄武岩结晶分离形成的.本文在考察了岩浆结晶分离作用的制约因素、比较了不同性质岩浆结晶分离作用的特征之后指出：玄武质岩浆可以发生结晶分离作用,因为有与其相关的堆晶岩产出;安山质岩浆也可以发生结晶分离作用,因为也有与其相关的堆晶岩产出.但是,花岗质岩浆似乎不大可能发生结晶分离作用,因为,很少见到有与（富硅的）花岗质岩浆相伴的堆晶岩产出.花岗质岩浆之所以不大可能发生结晶分离作用的原因在于：（1）岩浆的黏性大,它不仅阻滞了矿物的结晶作用（使斜长石不能发育为自形晶）,而且阻止了密度大的矿物（例如角闪石）下沉;（2）主要造岩矿物（例如斜长石）的密度与花岗质岩浆的密度相差无几,使结晶分离作用难以进行.本文详细考察了花岗质岩浆中斜长石的行为,指出在花岗质岩浆中斜长石结晶分离几乎是不可能的.那么,文献中大量充斥的花岗岩结晶分离作用的说法是依据什么呢？作者认为,文献中的许多说法可能主要是根据哈克图解得出的,而不是根据实际观察和理论研究得出的.作者认为,玄武岩和花岗岩不仅来源不同,成分不同,而且解释也不同.哈克图解中许多适合玄武岩的解释未必适合花岗岩.由于鲍文反应原理是结晶分离作用的理论基础,因此,文中也对鲍文反应原理进行了评述,并指出文献中存在的一些需要认真对待的问题,例如,从玄武岩-安山岩-英安岩-流纹岩的连续演化序列是不可能的;单元-超单元填图方法是不科学的;中国东部中生代大规模花岗岩不可能是玄武质岩浆结晶分离形成的等等.本文还以Ajaji et al.（1998）报道的摩洛哥Tanncherfi花岗岩为例,指出结晶分离作用的解释是不可能的.作者认为,花岗岩类的成分变化大,主要可能与源区组成、温度、压力、挥发分、部分熔融程度和过程、混合作用、岩浆分异及结晶分离作用有关.其中,源区组成可能是花岗岩多样性的最重要的原因,而结晶分离作用的影响可能是微乎其微的.本文认为,花岗岩结晶分离作用对于花岗岩成因的意义已经被大大地夸大了,我们应当重新思考结晶分离作用对于花岗质岩浆的意义.由于花岗岩的极端复杂性,许多问题还得不到比较合理的解释,本文的认识只是初步的.     

青藏高原新生代火车头山碱性及钙碱性两套火山岩的地球化学特征及其物源讨论

藏北羌塘火车头山新生代火山岩可区分为钙碱性及碱性两个不同的系列.钙碱性火山岩主要岩石组合为玄武岩-安山岩-英安岩,其SiO2介于49%～70%之间,Al2O3＞10%,Na2O/K2O＞1;其中玄武岩具平坦型稀土配分型式,LREE/HREE为1.3～1.8,（La/Yb）N为2.87～4.45,无明显铕异常,δEu为0.96～1.09;该套岩石的Mg#与SiO2相关关系以及La/Sm-La等亲岩浆元素与超亲岩浆元素协变关系表明,它们应为幔源岩浆经分离结晶演化的产物,其岩石组合类型以及低的Sm/Yb值（Sm/Yb=1.53～5.35）表明它们的原始岩浆应来源于岩石圈地幔尖晶石二辉橄榄岩的局部熔融.本区碱性火山岩为一套典型的钾质岩石系列,主要岩石组合类型为碱玄岩-碱玄质响岩-响岩,其SiO2介于44%～59%之间,Al2O3＞14%,Na2O/K2O介于0.47～1.51之间;岩石轻稀土强烈富集,LREE/HREE为13.20～15.76,（La/Yb）N=50.44～91.99;其岩石组合类型以及Mg^#与SiO2相关关系以及La/Sm-La协变关系同样表明它们为共源岩浆分离结晶演化的产物;然而,其较高的Sm/Yb值（Sm/Yb=2.63～13.98）表明它们并非地幔橄榄岩直接局部熔融的产物,岩石弱的负Eu异常（δEu=0.77～0.85）以及Th、U的强烈富集和Nb、Ta的相对亏损,又反映了原始岩浆中有显著的地壳物质的贡献;该套钾质碱性系列岩石在La/Co-Th/Co同分母协变图上呈直线型分布,而在La/Co-Sc/Th异分母协变图上呈显著的双曲线分布,从而表明其源区为二源混合型,是青藏高原特殊的壳幔混合层局部熔融的产物,这些特征是新生代青藏高原壳幔层圈物质交换的重要岩石学证据.     

新疆北部阿尔泰南缘晚古生代高钾高硅熔结凝灰岩的地球化学、岩浆成因及构造背景

新疆北部阿尔泰南缘分布着一条晚古生代的火山岩带。通过岩石学和地球化学的研究，我们从克朗和麦兹火山．沉积盆地的下泥盆统康布铁堡组地层的火山岩中，厘定出一种高钾高硅熔结凝灰岩（Ignimbrite），前人称之为钾质流纹岩。高钾高硅熔结凝灰岩主要由钾长石（微斜长石）、石英和黑云母，以及少量白云母组成。其岩石化学成分的特征为过铝质的（A／CNK=1．01～1．36）、高硅（SiO2=69％～80％）、高钾（K2O=5％-11％）、高钾钠比值，并富集大离子亲石元素（Rb，Ba，K，La），亏损高场强元素（Nb，Ta，Ti，P）和低的Nb／Y比值，以及富LREE和亏损Eu的REE分布模式。以上这些特征体现它们继承了形成硅质岩浆的大陆地壳源区特点。微量元素的构造环境判别图解显示，本区高钾高硅熔结凝灰岩形成于活动大陆边缘的岛弧构造环境。综合岩石学和地球化学研究的结果，作者提出高钾高硅熔结凝灰岩岩浆的二阶段成因模型：1）地幔楔二辉橄榄岩部分熔融产生的大体积玄武岩岩浆侵入导致其上部地壳发生部分熔融形成了高硅的熔结凝灰岩岩浆；2）高硅岩浆经富钠斜长石的分离结晶作用最终形成高钾高硅的熔结凝灰岩浆。     

The onset of deep recycling of supracrustal materials at the Paleo-Mesoarchean boundary

The recycling of supracrustal materials, and in particular hydrated rocks, has a profound impact on mantle composition and thus on the formation of continental crust, because water modifies the physical properties of lithological systems and the mechanisms of partial melting and fractional fractionation. On the modern Earth, plate tectonics offers an efficient mechanism for mass transport from the Earth''s surface to its interior, but how far this mechanism dates back in the Earth''s history is still uncertain. Here, we use zircon oxygen (O) isotopes to track recycling of supracrustal materials into the magma sources of early Archean igneous suites from the Kaapvaal Craton, southern Africa. The mean δ¹⁸O values of zircon from TTG (tonalite–trondhjemite–granodiorite) rocks abruptly increase at the Paleo-Mesoarchean boundary (ca. 3230 million years ago; Ma), from mantle zircon values of 5‰–6‰ to approaching 7.1‰, and this increase occurs in ≤3230 Ma rocks with elevated Dy/Yb ratios. The ¹⁸O enrichment is a unique signature of low-temperature water–rock interaction on the Earth''s surface. Because the later phase was emplaced into the same crustal level as the older one and TTG magmas would derive from melting processes in the garnet stability field (>40 km depth), we suggest that this evident shift in TTG zircon O isotopic compositions records the onset of recycling of the mafic oceanic crust that underwent seawater hydrothermal alteration at low temperature. The onset of the enhanced recycling of supracrustal materials may also have developed elsewhere in other Archean cratons and reflects a significant change in the tectonic realm during craton formation and stabilization, which may be important processes for the operation of plate tectonics on early Earth.     

Water transport to the core–mantle boundary

Water is transported to Earth''s interior in lithospheric slabs at subduction zones. Shallow dehydration fuels hydrous island arc magmatism but some water is transported deeper in cool slab mantle. Further dehydration at ∼700 km may limit deeper transport but hydrated phases in slab crust have considerable capacity for transporting water to the core-mantle boundary. Quantifying how much remains the challenge.

Water can have remarkable effects when exposed to rocks at high pressures and temperatures. It can form new minerals with unique properties and often profoundly affects the physical, transport and rheological properties of nominally anhydrous mantle minerals. It has the ability to drastically reduce the melting point of mantle rocks to produce inviscid and reactive melts, often with extreme chemical flavors, and these melts can alter surrounding mantle with potential long-term geochemical consequences. At the base of the mantle, water can react with core iron to produce a super-oxidized and hydrated phase, FeO₂H_x, with the potential to profoundly alter the mantle and even the surface and atmosphere redox state, but only if enough water can reach such depths [1].Current estimates for bulk mantle water content based on the average H₂O/Ce ratio of oceanic basalts from melt inclusions and the most un-degassed basalts, coupled with mass balance constraints for Ce, indicate a fraction under one ocean mass [2], a robust estimate as long as the basalts sampled at the surface tap all mantle reservoirs. The mantle likely contains some primordial water but given that the post-accretion Earth was very hot, water has low solubility and readily degasses from magma at low pressures, and its solubility in crystallizing liquidus minerals is also very low, the mantle just after accretion may have been relatively dry. Thus, it is plausible that most or even all of the water in the current mantle is ‘recycled’, added primarily by subduction of hydrated lithospheric plates. If transport of water to the core–mantle boundary is an important geological process with planet-scale implications, then surface water incorporated into subducting slabs and transported to the core–mantle boundary may be a requirement.Water is added to the basaltic oceanic crust and peridotitic mantle in lithospheric plates (hereafter, slab crust and slab mantle, respectively) at mid-ocean ridges, at transform faults, and in bending faults formed at the outer rise prior to subduction [3]. Estimates vary but about 1 × 10¹² kg of water is currently subducted each year into the mantle [4], and at this rate roughly 2–3 ocean masses could have been added to the mantle since subduction began. However, much of this water is returned to the surface through hydrous magmatism at convergent margins, which itself is a response to slab dehydration in an initial, and large, release of water. Meta-basalt and meta-sediments comprising the slab crust lose their water very efficiently beneath the volcanic front because most slab crust geotherms cross mineral dehydration or melting reactions at depths of less than 150 km, and even if some water remains stored in minerals like lawsonite in cooler slabs, nearly complete dehydration is expected by ∼300 km [5].Peridotitic slab mantle may have much greater potential to deliver water deeper into the interior. As shown in Fig. 1a, an initial pulse of dehydration of slab mantle occurs at depths less than ∼200 km in warmer slabs, controlled primarily by breakdown of chlorite and antigorite when slab-therms cross a deep ‘trough’, sometimes referred to as a ‘choke point’, along the dehydration curve (Fig. 1a) [6]. But the slab mantle in cooler subduction zones can skirt beneath the dehydration reactions, and antigorite can transform directly to the hydrated alphabet silicate phases (Phases A, E, superhydrous B, D), delivering perhaps as much as 5 wt% water in locally hydrated regions (e.g. deep faults and fractures in the lithosphere) to transition zone depths [6]. Estimates based on mineral phase relations in the slab crust and the slab mantle coupled with subduction zone thermal models suggest that as much as 30% of subducted water may have been transported past the sub-volcanic dehydration front and into the deeper mantle [4], although this depends on the depth and extent of deep hydration of the slab mantle, which is poorly constrained. Coincidentally, this also amounts to about one ocean mass if water subduction rates have been roughly constant since subduction began, a figure tantalizingly close to the estimated mantle water content based on geochemical arguments [2]. But what is the likely fate of water in the slab mantle in the transition zone and beyond?Open in a separate windowFigure 1.(a) Schematic phase relations in meta-peridotite modified after [6,10,12]. Slab geotherms are after those in [4]. Cold slabs may transport as much as 5 wt% water past ‘choke point 1’ in locally hydrated regions of the slab mantle, whereas slab mantle is dehydrated in warmer slabs. Colder slab mantle that can transport water into the transition zone will undergo dehydration at ‘choke point 2’. How much water can be transported deeper into the mantle and potentially to the core depends on the dynamics of fluid/melt segregation in this region. (b) Schematic showing dehydration in the slab mantle at choke point 2. Migration of fluids within slab mantle will result in water dissolving into bridgmanite and other nominally anhydrous phases with a bulk storage capacity of ∼0.1 wt%, potentially accommodating much or all of the released water. Migration of fluids out of the slab into ambient mantle would also hydrate bridgmanite and other phases and result in net fluid loss from the slab. Conversely, migration of hydrous fluids into the crust could result in extensive hydration of meta-basalt with water accommodated first in nominally anhydrous phases like bridgmanite, Ca-perovskite and NAL phase, but especially in dense SiO₂ phases (stishovite and CaCl₂-type) that can host at least 3 wt% water (∼0.6 wt% in bulk crust).Lithospheric slabs are expected to slow down and deform in the transition zone due to the interplay among the many factors affecting buoyancy and plate rheology, potentially trapping slabs before they descend into the lower mantle [7]. If colder, water-bearing slabs heat up by as little as a few hundred degrees in the transition zone, hydrous phases in the slab mantle will break down to wadsleyite or ringwoodite-bearing assemblages, and a hydrous fluid (Fig. 1a). Wadselyite and ringwoodite can themselves accommodate significant amounts of water and so hydrated portions of the slab mantle would retain ∼1 wt% water. A hydrous ringwoodite inclusion in a sublithospheric diamond with ∼1.5 wt% H₂O may provide direct evidence for this process [8].But no matter if slabs heat up or not in the transition zone, as they penetrate into the lower mantle phase D, superhydrous phase B or ringwoodite in the slab mantle will dehydrate at ∼700–800 km due to another deep trough, or second ‘choke point’, transforming into an assemblage of nominally anhydrous minerals dominated by bridgmanite (∼75 wt%) with, relatively, a much lower bulk water storage capacity (< ∼0.1 wt%) [9] (Fig. 1a). Water released from the slab mantle should lead to melting at the top of the lower mantle [10], and indeed, low shear-wave velocity anomalies at ∼700–800 km below North America may be capturing such dehydration melting in real time [11].The fate of the hydrous fluids/melts released from the slab in the deep transition zone and shallow lower mantle determines how much water slabs can carry deeper into the lower mantle. Presumably water is released from regions of the slab mantle where it was originally deposited, like the fractures and faults that formed in the slab near the surface [3]. If hydrous melts can migrate into surrounding water-undersaturated peridotite within the slab, then water should dissolve into bridgmanite and coexisting nominally anhydrous phases (Ca-perovskite and ferropericlase) until they are saturated (Fig. 1b). And because bridgmanite (water capacity ∼0.1 wt%) dominates the phase assemblage, the slab mantle can potentially accommodate much or all of the released water depending on details of how the hydrous fluids migrate, react and disperse. If released water is simply re-dissolved into the slab mantle in this way then it could be transported deeper into the mantle mainly in bridgmanite, possibly to the core–mantle boundary. Water solubility in bridgmanite throughout the mantle pressure-temperature range is not known, so whether water would partially exsolve as the slab moves deeper stabilizing a melt or another hydrous phase, or remains stable in bridgmanite as a dispersed, minor component, remains to be discovered.Another possibility is that the hydrous fluids/melts produced at the second choke point in the slab mantle at ∼700 km migrate out of the slab mantle, perhaps along the pre-existing fractures and faults where bridgmanite-rich mantle should already be saturated, and into either oceanic crust or ambient mantle (Fig. 1b). If the hydrous melts move into ambient mantle, water would be consumed by water-undersaturated bridgmanite, leading to net loss of water from the slab to the upper part of the lower mantle, perhaps severely diminishing the slab’s capacity to transport water to the deeper mantle and core. But what if the water released from slab mantle migrates into the subducting, previously dehydrated, slab crust?Although slab crust is expected to be largely dehydrated in the upper mantle, changes in its mineralogy at higher pressures gives it the potential to host and carry significant quantities of water to the core–mantle boundary. Studies have identified a number of hydrous phases with CaCl₂-type structures, including δ-AlOOH, ϵ-FeOOH and MgSiO₂(OH)₂ (phase H), that can potentially stabilize in the slab crust in the transition zone or lower mantle. Indeed, these phases likely form extensive solid solutions such that an iron-bearing, alumina-rich, δ-H solid solution should stabilize at ∼50 GPa in the slab crust [12], but only after the nominally anhydrous phases in the crust, (aluminous bridgmanite, stishovite, Ca-perovskite and NAL phase) saturate in water. Once formed, the δ-H solid solution in the slab crust may remain stable all the way to the core mantle boundary if the slab temperature remains well below the mantle geotherm otherwise a hydrous melt may form instead [12] (Fig. 1a). But phase δ-H solid solution and the other potential hydrated oxide phases, intriguing as they are as potential hosts for water, may not be the likely primary host for water in slab crust. Recent studies suggest a new potential host for water—stishovite and post-stishovite dense SiO₂ phases [13,14].SiO₂ minerals make up about a fifth of the slab crust by weight in the transition zone and lower mantle [15] and recent experiments indicate that the dense SiO₂ phases, stishovite (rutile structure—very similar to CaCl₂ structure) and CaCl₂-type SiO₂, structures that are akin to phase H and other hydrated oxides, can host at least 3 wt% water, which is much more than previously considered. More importantly, these dense SiO₂ phases apparently remain stable and hydrated even at temperatures as high as the lower mantle geotherm, unlike other hydrous phases [13,14]. And as a major mineral in the slab crust, SiO₂ phases would have to saturate with water first before other hydrous phases, like δ-H solid solution, would stabilize. If the hydrous melts released from the slab mantle in the transition zone or lower mantle migrate into slab crust the water would dissolve into the undersaturated dense SiO₂ phase (Fig. 1b). Thus, hydrated dense SiO₂ phases are possibly the best candidate hosts for water transport in slab crust all the way to the core mantle boundary due to their high water storage capacity, high modal abundance and high-pressure-temperature stability.Once a slab makes it to the core–mantle boundary region, water held in the slab crust or the slab mantle may be released due to the high geothermal gradient. Heating of slabs at the core–mantle boundary, where temperatures may exceed 3000°C, may ultimately dehydrate SiO₂ phases in the slab crust or bridgmanite (or δ-H) in the slab mantle, with released water initiating melting in the mantle and/or reaction with the core to form hydrated iron metal and super oxides, phases that may potentially explain ultra-low seismic velocities in this region [1,10]. How much water can be released in this region from subducted lithosphere remains a question that is hard to quantify and depends on dynamic processes of dehydration and rehydration in the shallower mantle, specifically at the two ‘choke points’ in the slab mantle, processes that are as yet poorly understood. What is clear is that subducting slabs have the capacity to carry surface water all the way to the core in a number of phases, and possibly in a phase that has previously seemed quite unlikely, dense SiO₂.     

青海柴北缘红铁沟地区基性岩脉锆石U-Pb测年、地球化学特征及地质意义

柴北缘红铁沟地区发现的北西-南东向基性岩脉,侵入于南华一震旦纪全吉群中。对辉绿岩进行了LA-MC-ICP-MS锆石U-Pb测年,获得年龄为234±14Ma,时代中三叠世。岩石化学和地球化学表明,基性岩脉为上地幔部分熔融的产物,基性岩浆的分异演化未受陆壳物质混染。红铁沟地区基性辉绿岩脉的发现,进一步证明了在中三叠世该地区经历了多次强烈挤压碰撞及其之间的相对松弛伸展,为柴北缘红铁沟地区的构造岩浆旋回演化过程提供了重要的地质信息。     

Linking deep CO2 outgassing to cratonic destruction

Outgassing of carbon dioxide from the Earth''s interior regulates the surface climate through deep time. Here we examine the role of cratonic destruction in mantle CO₂ outgassing via collating and presenting new data for Paleozoic kimberlites, Mesozoic basaltic rocks and their mantle xenoliths from the eastern North China Craton (NCC), which underwent extensive destruction in the early Cretaceous. High Ca/Al and low Ti/Eu and δ²⁶Mg are widely observed in lamprophyres and mantle xenoliths, which demonstrates that the cratonic lithospheric mantle (CLM) was pervasively metasomatized by recycled carbonates. Raman analysis of bubble-bearing melt inclusions shows that redox melting of the C-rich CLM produced carbonated silicate melts with high CO₂ content. The enormous quantities of CO₂ in these magmas, together with substantial CO₂ degassing from the carbonated melt–CLM reaction and crustal heating, indicate that destruction of the eastern NCC resulted in rapid and extensive mantle CO₂ emission, which partly contributed to the early Cretaceous greenhouse climate episode.     

把握“马克思主义基本原理概论”课程的教学深度

以马克思主义的三个组成部分构成的马克思主义基本原理概论课,要求教师在有限的课时内突出教学深度。本文认为要确保教学内容上的深度,必须在讲课形式上有所突破,以教学形式上的深度来确保教学内容上的深度。     

黑龙江省辽东木资源的利用与保护

对黑龙江省野生辽东木资源的分布、经济价值、利用现状进行了评述 ,分析了浅山区辽东木资源濒危的直接原因和我国野生植物资源保护所存在的深层次问题 ,提出了野生植物资源的主动保护思想 ,勾画出地方重点保护野生植物的框架 ,并提出建立野生辽东木资源的保护管理费制度、资源调查监测系统和研究其合理利用与保护方法等对策     

Magnesium isotope geochemistry of the carbonate-silicate system in subduction zones

The lighter magnesium (Mg) isotopic signatures observed in intraplate basalts are commonly thought to result from deep carbonate recycling, provided that the sharp difference in Mg isotopic composition between surface carbonates and the normal mantle is preserved during plate subduction. However, deep subduction of carbonates and silicates could potentially fractionate Mg isotopes and change their chemical compositions. Subducting silicate rocks that experience metamorphic dehydration lose a small amount of Mg, and preserve the original Mg isotopic signature of their protoliths. When the dehydrated fluids dissolve carbonate minerals, they may evolve into lighter Mg isotopic compositions. The solubility of carbonate minerals in fluids decreases in the order of calcite, aragonite, dolomite, magnesite and siderite, leading to selective and partial dissolution of carbonate minerals along the subduction path. At the island arc depth (70–120 km), the metamorphic fluid dissolves mainly Mg-poor calcites, and thus the fluid has difficulty modifying the Mg isotopic system of the mantle wedge and associated arc basalts. At the greater depth of the back arc system or continental margin (>150 km), the supercritical fluid can dissolve Mg-rich carbonate minerals, and its interaction with the mantle wedge could significantly imprint the light Mg isotopic signature onto the mantle rocks and derivatives. Meanwhile, the carbonate and silicate remaining within the subducting slab could experience elemental and isotopic exchange, during which the silicate can obtain a light Mg isotopic signature and high CaO/Al₂O₃, whereas the carbonates, particularly the Ca-rich limestone, shift Mg isotopes and MgO contents towards higher values. If this isotopic and elemental exchange event occurs widely during crustal subduction, subducted Ca-rich carbonates can partially transform into being Mg-rich, and a portion of recycled silicates (e.g. carbonated eclogites) can have light Mg isotopic composition alongside carbonates. Both serve as the low-δ²⁶Mg endmember recycled back into the deep mantle, but the latter is not related to deep carbonate recycling. Therefore, it is important to determine whether the light Mg isotopic signatures observed in intraplate basalts are linked to deep carbonate recycling, or alternatively, recycling of carbonated eclogites.     

技术交易市场：科技成果产业化的主桥梁

我国科技对经济发展贡献率低的主要原因在于科技成果产业化程度低,科技成果产业化程度低的主要原因在于技术交易市场不够成熟,技术交易市场的发展趋势在于区域化、体制独立化、服务社会化、机构专业化和市场国际化。     

石灰、抗剥落剂对玄武岩沥青混合料水稳定性的影响

玄武岩呈弱碱性，一般认为与沥青有较好的粘附性。但是，现有用玄武岩沥青混合料铺筑的一些路面桥面仍出现了各种早期的水损坏现象。消石灰和抗剥落剂等添加剂可改善沥青混合料水稳定性。马歇尔试验残留稳定度（MS0）与冻融劈裂试验残留强度比（TSR）结果显示，无添加剂玄武岩沥青混合料的水稳定性不一定能够满足规范要求：所用各种添加剂均可以显著改善玄武岩沥青混合料的水稳定性，使MSO达到88％-98％、TSR达到77％-90‰，基本满足规范要求。