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1.
This study shows that the sandstone used in the construction of the Church of San Mateo in Tarifa (Cádiz, Spain) is highly sensitive to processes of decay because of a combination of factors that are intrinsic and extrinsic to the material. The mineralogy, texture and porous system of the sandstone and the proximity of the church to the sea all play a part in these processes. X-ray diffraction reveals that there are interstratified chlorite/smectite clays among the minerals that make up the rock. These mixed layer clays have been shown to undergo hydric expansion. This phenomenon may be accompanied and augmented by the presence of NaCl which acts as an electrolyte in osmotic swelling processes. Two varieties of sandstone were used in the construction of the church, namely grey sandstone and brown sandstone. The latter is more porous and undergoes greater hydric expansion, showing a higher degree of deterioration. Ultrasound analysis has demonstrated that both varieties are anisotropic because they contain bedding planes and are affected by the preferred orientation of the phyllosilicates in the rock. The anisotropic nature of these stones was confirmed by capillary suction tests. The capillary front reaches a relatively low height which means that when water is absorbed, the anisotropic textural properties combined with the presence of chlorite–smectite mixed layers in the sandstone result in mechanical (shear) stress between the first few centimetres of the wet stone and the dry area behind. The latter effect favours the development of flakes, so causing the decay of the ornamental stone and the church façade.  相似文献   

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The sculptural polychromy in the Zhongshan Grottoes, sited in northwest China, has been investigated in terms of chemical composition of employed materials and pigments, state of conservation and painting technique. Raman analysis, Fourier-transform infrared analysis, analysis through energy-dispersive X-ray spectrometry coupled to scanning electron microscopy and pyrolysis coupled to gas chromatography and mass spectrometry were applied. Six analyzed samples showed silicates and kaolin as main components of the ground layers. Also lead white has been found in these layers. Minium, red-earth and mercury sulfide are the red pigments detected in the polychromy. A mixed use of malachite and atacamite has been detected in three green samples. Optical characteristics of atacamite and malachite found in the samples indicate a synthetic origin. The presence of a synthetic organic pigment such as phthalocyanine chlorinated pigment was also revealed. Ultramarine blue pigment, obtained by purification of lapis lazuli, has been detected in the blue sample. As for the binders used, fatty materials and siccative oil were found.  相似文献   

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Restoring cultural heritage is an extremely important job due to its immeasurable value. However, it also requires even greater attention in the case of a building. The actions taken on these constructions not only guarantee their preservation from the point of view of their historical value, but they also guarantee their stability as structures. The need to control historic buildings, analyzing their defects and their possible consequences, is decisive in preventing significant damage. This work demonstrates calculating the thickness of vaults in a church. It is easy to determine the interior and exterior 3D geometry of the church using scanner laser techniques. By combining both geometries, it is easy to determine the difference between the interior vaults and the roof of the church. However, the interior of both geometries is completely unknown, and it is not possible to act on their condition for structural consolidation purposes. This work shows the methods used to determine the interior sections of the vault thicknesses by referencing the internal geometry of both models with the interior of the church, using plumb line system scanning. The results obtained show accuracy better than 6 millimeters.  相似文献   

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Lava columns from the cathedral St Maria of Randazzo (Catania, Italy), were studied in order to establish the classification of these rocks and to investigate their origin. At the beginning of the XIX century, some columns of the old frame of the nave were removed to build the dome and stored in a fornix beneath the cathedral. Samples were taken directly from these columns. The specimens underwent petrographic investigation through optical microscopy, X-ray diffraction analysis (XRD) and Fourier transform infrared spectroscopy (FTIR) and chemical analyses of major and trace elements through X-ray fluorescence (XRF). Some trace element (Sr, Rb, Y, Zr and Nb) concentrations were assessed through non-destructive analyses, performed with a portable X-ray device which can detect homogeneous concentrations of such elements on the columns of the cathedral. According to chemical data, these rocks can be classified as mugeariites whose mineral assemblage is given by plagioclase (mostly andesinic), augitic pyroxene, olivine, magnetite and, occasionally, apatite. In order to investigate the origin of the material used for the columns, a comparative examination was conducted between the column samples and specimens collected from quarries in the surrounding area of the town of Randazzo (Randazzo and Maniace quarries and the 1536 lava flow). The correlation with the Randazzo quarry proved to be excellent.  相似文献   

6.
The focus of this work is the wood polychrome model of the church of S. Maria della Consolazione in Todi, an artefact whose author and historical events are not completely known except a general reference to the construction period of the church (1508–1607 AD). In this study, original and additional materials were examined in order to provide a deeper understanding of the painting and assembly techniques, and a greater awareness of how well preserved the object is, as well as an analysis of previous preservation and conservation interventions. The samples from the painted surfaces were examined by means of micro-Raman spectroscopy, fourier transform infrared (FTIR) spectrometry and internal microstratigraphic analysis. Thin sections of the wood samples were examined under an optical transmission light microscope in order to identify the botanical species. The results shown in this paper suggest the possibility that the original painted layers are made of calcium carbonate white, red ochre and indigo and they were applied by protein binder without any ground layer. Some non-original pigments were found on the model surface like Prussian blue and chrome yellow. Concerning wood components, poplar was characterized both in the original and non-original parts of the model whereas pine species were detected only in the restoration elements.  相似文献   

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In May–June 2012, several seismic events took place in the Po River Plane in northern Italy, with a maximum magnitude of MW 5.86 (ML 5.9)] and the epicentre located about 32 km from the centre of Ferrara. Many historical buildings were seriously damaged and others showed marked deformations or differential settlements. Therefore, it was necessary to place many of them under monitoring, using fast and safe measurement techniques to quickly obtain accurate information on ongoing structural deformation. This paper presents the case study of the bell tower of San Benedetto Church in Ferrara (17th century), which was already under monitoring at the time of the earthquake because of its remarkable leaning angle. Immediately after the seismic events, monitoring of the bell tower was repeated. Digital levelling indicated a marked differential settlement of the foundations with regard to the trend of secular movement, while terrestrial laser scanning (TLS) revealed a significant increase of the inclination of the tower's axis, confirming the results from levelling and showing good integration of both monitoring techniques.  相似文献   

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《高僧传》序录卷十四云:“沙门法济,偏叙高逸一迹。沙门法安,但列志节一行。沙门僧宝,止命游方一科。沙门法进,乃通撰传论。”该文对四人及其书进行了考论。  相似文献   

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Academic studies concerning how climate influences Asian heritage are rare. The object of this study was to utilize the concept of heritage climatology together with a spatial analysis approach that includes respective climate parameter risks to cultural heritage sites. The study area, Tainan City, Taiwan, is in a subtropical zone south of the Tropic of Cancer. Tainan has nearly 300 hundred years of rich history and a multicultural background. This study used maps to gain information about potential climactic threats to Tainan's cultural-historical legacy. There are four kinds of map that use ArcGIS to analyse and demarcate regions not only by climate parameters but also by risk to heritage. These four types of map are climate maps, heritage climate maps, heritage maps and heritage risk maps. Climate maps give the short- to medium-term general status of the climate in Tainan City and thus served as the foundation of the other maps used in this study. Heritage climate maps give data concerning index factors that influence wood and stone materials. Heritage maps show locations of cultural heritage sites on an administrative map and categorize them according to their historic value. Heritage risk maps use accumulated calculations to superimpose the heritage climate map onto the heritage map in order to evaluate the risks to heritage sites in certain areas and categorize the levels of risk. Heritage sites in mountainous areas generally need to be protected from heavy rain, whereas downtown city environments, due to the urban heat island effect, require better protection against heat and cracking. By comparison of our field study results and climate risk maps, we found that in urban areas wooden materials have a higher risk of structural cracking, colour fading and bio-degradation, while coastal areas have a higher risk of weathering of stone materials.  相似文献   

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Over the last years, there was an increasing interest in keeping suitable microclimatic conditions for the preservation of artefacts: the artefacts preservation requirements may diverge from those of the museums visitors, willing to enjoy the works of art in a situation of psycho-physical wellness. The HVAC designers and engineers will have then to cooperate closely with the curator, in order to define a compromise between conflicting environmental performance requirements. In particular at the stage of air-conditioning system design or retrofit, it is extremely important to carry out a series of preliminary analysis to evaluate and monitor the existing environmental conditions and to anticipatory simulate and predict the post-intervention conditions. To this aim, advanced fluid-dynamic investigation tools (Computational Fluid Dynamic [CFD] techniques) enable to deal with the specificity of such topics and provide a useful decision-making support.  相似文献   

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Piperno, a Late Quaternary magmatic rock cropping out on the eastern side of the Campi Flegrei (Italy), is probably the most important building stone of Naples, used over a time-span from at least the Roman age until the beginning of the 20th century. Despite its wide diffusion in the monumental architecture of Naples, very little is known about this rock, as regards its technical features, as well as the geological aspects. This paper aims at providing a first overall contribution towards a rediscovery of this long-time-used material, in view of careful restoration works, which nowadays at Naples only take into account the proper geological features of the stone in a few peculiar cases. Thus, it seems of extreme importance to understand the basic parameters of Piperno and, above all, its response to weathering agents. Main mineralogical, petrographical and engineering–geological properties are presented here for the first time, with specific reference to two sampling areas, located at Pianura and Soccavo, in the western sector of the Neapolitan urban area. As far as many of its physico–mechanical features are concerned, Piperno extends over a wide range of values, which allow different varieties of the rock to be identified. This preliminary result is seemingly in accordance with data from old historical literature, which stated the existence of six horizons in the Piperno formation.  相似文献   

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Bab Agnaou is one of the most beautiful gates of the 12th century town walls of Marrakech (Morocco). It is faced with poorly preserved stone, which has recently been subjected to preliminary laboratory studies for the purpose of collecting data useful for its restoration. The results of such studies indicate the presence of two macroscopically similar grey stones, classified as slates, which were probably sourced from quarries situated not far from the city of Marrakech. The schistosity of such stones, namely their laminated fabric, has much influenced the morphology of deterioration. The causes and mechanisms of decay have been investigated and connected to the presence of soluble salts, mainly chlorides and sulphates deriving from the mortar used to fix the stone blocks to the wall, and to local air pollution. Their concentration in the bottom 3 m of the gate due to rising damp has produced strong exfoliation and flaking phenomena through rapidly repeating crystallization/dissolution cycles. A minor contribution to the overall deterioration is due to hydrolytic phenomena partly responsible for the formation of natural brown patinas on the stone surface. Another brown patina formed of Ca-oxalates and with residual proteinaceous matter was also detected and is probably due to partly mineralized protection-treatments made with natural products such as animal glue. General indications for the restoration of the gate, based on these results, are proposed.  相似文献   

16.
The possible pre-consolidation of the stones used to repair the Roman wall of Tarragona was studied, on the premise that this had been carried out prior to placement in the wall. A detailed study of the stones was conducted in order to determine whether they had been treated, and if so, how this had been done. A semi-quantitative X-ray mineralogical analysis using the Rietveld method was performed, together with porosity and textural analyses. This paper concludes with a discussion of how the stones studied here were pre-consolidated using lime slurry.  相似文献   

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