碳纳米管在药物载体领域的应用

医学中开发新型药物载体对研究药物具有重要作用,作为一种具有独特纳米管径与中空结构的碳纳米管,可将其纳入药物载体范畴,以核酸、蛋白、药物分子以及肽所修饰的新型碳纳米管为载体,将生物活性分子运载至细胞中,而且不会产生毒性。本研究主要对碳纳米管在药物载体领域的应用进行分析与探讨。     

催化剂种类对PECVD制备碳纳米管的影响

采用PEVCD技术,分别用Fe、Ni、Co作为催化剂,在Si基底上沉积出了不同形貌的碳纳米管．并用扫描电镜对碳纳米管的形貌进行了表征．而且深入研究了不同催化剂种类对碳纳米管生长的影响机理．结果表明：Ni是这3种催化剂中最适合沉积碳纳米管的催化剂．     

氮化钼/碳纳米管催化剂上氨分解活性的研究

采用MoO_3/碳纳米管和NH_3程序升温反应的方法合成了一系列不同Mo含量的Mo_2N/碳纳米管催化剂,利用XRD、BET、TG-DSC、TPR等手段对其物化性能进行了表征,同时以氨分解为探针反应考察了它们的催化活性。结果表明,MoN_x/CNTs催化剂对氨分解反应具有良好的催化活性,当Mo负载量为15%,反应温度650℃时,氨转化率为66.59%;由TG-DSC结果可以看出,焙烧温度对催化剂活性有较大影响,500℃焙烧制得的催化剂中活性组分分散性最好,其氨分解活性最高。     

负载型双组分催化剂的研究Ⅳ Pt-Sn/P催化剂中金属与载体以及金属与金属之间的相互作用

本文研究了负载型双组分催化剂Pt—Sn/P中金属与载体以及金属与金属之间的相互作用,并从理论上作了较为详细的讨论。     

镍基催化剂载体对催化苯加氢反应性能的影响

利用不同载体采用共沉淀法制备了负载型镍催化剂,用于苯完全加氢反应,研究了载体对催化剂活性的影响,并采用粒度分析、XRD等手段对催化剂进行了表征。结果表明,在140℃～190℃和4MPa氢压下,载体不同,催化剂活性相差很大,由高到低顺序依次为：SiO2〉硅藻土〉ZrO2〉TiO2〉γ—Al2O3。研究表明,这种差异来源于载体的比表面积,活性组分的分散程度以及活性组分与载体的相互作用。具有较大的比表面积,活性组分分散均匀,活性组分与载体具有适宜相互作用的SiO2作载体,催化剂具有最好的加氢活性。     

碳纳米管的研究进展及应用

阐述了碳纳米管的结构，并对碳纳米管合成方法及其应用进行了简单的分析，同时指出了碳纳米管的研究进展。其合成方法主要有电弧法、激光蒸发法、催化剂气相分解法。其应用领域主要在力学、催化剂及储能方面。     

碳纳米管负载CuO催化剂的制备及性能

用自行制备的碳纳米管(CNTs)作为载体。研制出一种高活性的催化剂CuO／CNTs通过对物理特性分析、SEM图对比以及催化活性的测定。证明小粒径的CuO粒子均匀地分布在碳纳米管表面，对CO氧化反应有良好的催化活性、     

碳纳米管负载CuO催化剂的制备及性能

用自行制备的碳纳米管 (CNTs)作为载体 ,研制出一种高活性的催化剂CuO/CNTs .通过对物理特性分析、SEM图对比以及催化活性的测定 ,证明小粒径的CuO粒子均匀地分布在碳纳米管表面 ,对CO氧化反应有良好的催化活性 .     

均相催化剂的固载化研究

介绍了均相催化剂的固载化研究进展.可以通过离子交换、密封和接枝等方法将均相催化剂固载于载体之上,而载体和接枝过渡物质的接枝长度也会影响固载化催化剂的活性.     

电化学双层电容器中碳纳米管电极的化学法处理

Multi-walled carbon nanombes with homogeneous diameters （40 - 60 nm）, produced by chemical vapor deposition of hydrocarbon gas, are purified by nitric acids. Infrared and Raman studies indicate that oxygen containing surface groups, which are predominately carboxylic, phenolic and lactonic groups, are introduced into purified carbon nanotubes. Then three kinds of block-form porous tablets of carbon nanotubes are fabricated as electrodes in electrochemical double-layer capacitors. Using mounded mixture comprising carbon nanotubes and binder powders provides these tablets. Comparison of the effect of different processing on the structural performance of the capacitors is specifically investigated. Using chemically treated electrodes, electrochemical double-layer capacitors with a specific capacitance of about 33 F/g are obtained with 38 wt % H2SO4 as the electrolyte.     

激光轰击制备碳纳米管及其相关纳米材料

采用Nd：YAG脉冲激光在常温常压下轰击浸于乙醇流动相中的铁／石墨混合靶进行制备碳纳米管的研究。用傅立叶红外光谱、X射线衍射和透射电镜等现代分析技术分别对激光轰击所得产物进行表征。结果表明，以铁为催化剂，激光波长为1064nm，激光功率密度为4．5x10^9W/cm^2的条件下可成功制备碳纳米管，并且，透射电镜观察到所得的碳纳米管管径约为20～50nm，长度约几百nm，最长可达1μm以上。     

Electrical properties of carbon nanotubes in flowing vapor

1 Introduction a Among the numerous sensitive materials, carbon nanotubes (CNTs), both single and multiwalled, have been the focus of many studies recently [1,2]. In addition to high gas detection capability, it is established that CNT-based sensors opera…     

Injection of stored nucleotides from single-walled carbon nanotubes

We investigate the possibility of injection of a nucleotide via single-walled carbon nanotubes （SWNTs）. The collapse process of an SWNT with a large radius may proceed like falling dominoes. The characteristics of a large radius SWNT are utilized to drive the nucleotide movement in the SWNT, or even to inject the stored nucleotide out of the SWNT. In this process, the lateral section of the collapsed SWNT resembles a dumbbell. Occasionally, the nucleotide in the SWNT will be inbreathed into one of the two dumbbell ends, leading to interference with the injection process. To investigate the random nature of the injection process, a series of simulations on SWNT with different lengths were carried out. It was found that the injection probability was not influenced by the tube length. Freezing the nucleotide at the beginning, or modifying the SWNT at the outlet, may serve to facilitate the injection process, as indicated by the rise in the injection probability.     

纳米碳管的几何构型与模型制作

介绍了纳米碳管的几何构型．给出了一种纳米碳管模型的制作方法。     

碳纳米管与石墨烯作为润滑油添加剂对界面摩擦磨损性能的影响

纳米碳材料因可能具有优异的摩擦磨损性能受到了研究者的广泛关注,但其作为润滑添加剂时,摩擦磨损性能的差异尚未得到充分研究。针对此问题,采用四球机研究了碳纳米管与石墨烯作为润滑油添加剂时对摩擦和磨损性能的影响。结果表明:微量碳纳米管与石墨烯作为添加剂能够减小摩擦、降低磨损,酸化后碳纳米管的减摩降磨作用更为显著;采用碳纳米管作为添加剂时,添加剂的最佳质量分数与载荷相关,石墨烯作为添加剂时添加的质量分数受载荷变化的影响较小。对钢球磨斑表面形貌的观察表明,碳纳米管与石墨烯在摩擦副之间能够起到润滑和填充作用,从而减小了摩擦、降低了磨损,在高载荷下,添加过量碳纳米管和石墨烯时,由于其团聚性反而使磨损急剧增加。     

碳纳米管/活性炭复合载体承载硫化镉的光催化性能

利用原位反应过程分别制备碳纳米管、活性炭和碳纳米管/活性炭复合体负载硫化镉的复合材料, 进行光催化降解甲基橙的研究.结果显示, 在碳纳米管和活性炭作载体时, 光催化降解反应速率常数为没有载体条件下的3. 6倍和8. 8倍.按质量比为20∶80的碳纳米管/活性炭复合载体承载硫化镉的光催化性能又显著高于分别以碳纳米管和活性...     

Physical properties of the junction of scandium and carbon nanotubes

Using first-principles calculations, the contact between the scandium (Sc) and semiconducting carbon nanotube (CNT) is investigated. This is one of the best quality of n-type contacts. Two junction models with (8,0) CNT on low-index Sc surfaces are constructed to elucidate the structural and electronic properties of Sc/CNT junctions. Analyses based on density of states and charge difference reveal that strong chemical bonds are formed between Sc and C atoms due to hybrid states of Sc 3d state and C 2π state. With respect to Ti(0001)/CNT junction, we find the dipole layer formed at the interface of Sc(0001)/CNT is comparable with that of Ti(0001)/CNT but gives a negative barrier at the interface. This indicates that the excellent contact properties of Sc metal electrode are caused by its low work function and excellent binding with CNT.