HFC125跨临界热泵热水器性能实验研究

为深入了解HFC125跨临界循环热泵热水器的运行特性,设计和建造了一个直流变频热泵热水器实验装置,对HFC125跨临界循环热泵热水器性能进行了实验研究,发现压缩机运行在95Hz时系统存在一个COP峰值.然后以95Hz为例,研究了系统COP与压缩机频率、冷凝压力、蒸发压力、冷却水温升、压缩机排气温度等参数的关系,并与R410A亚临界循环系统性能进行了比较.结果表明：系统存在一最优频率,此时系统有较好的COP值,系统COP随冷凝压力和压比的降低呈上升趋势,而蒸发压力基本恒定;当冷却水温升超过47.5℃时,COP迅速下降.相对R410A亚临界循环,HFC125跨临界循环系统COP显著提升,提高幅度平均在12%以上.     

Experimental investigation on system with combination of ground-source heat pump and solar collector

This paper presents the heating performance and energy distribution of a system with the combination of ground-source heat pump and solar collector or a solar-assisted ground-source heat pump system (SAGSHPS) by calculation and experiment.The results show that the average absolute error is less than 0.6 ℃ and the relative error is less than 5% under the pulse load when the analytical solution to the 2-D solid cylindrical source model is used for the SAGSHPS.The coefficient of performance (COP) of the SAGSHPS is 2.95-4.70.The average fluid temperature in the borehole heat exchanger can increase by 3 ℃ with the assistance of solar collector,which will improve the COP of the heat pump by approximately 10% from the experimental data.The energy contributions to the total heating load of soil,electricity and solar are 56.30%,36.87% and 6.83%,respectively.     

Experimental performance of moderate and high temperature heat pump charged with refrigerant mixture BY-3

Theoretical and experimental analysis of a new refrigerant mixture BY-3 was conducted based on a single-stage vapor compression refrigeration system. The water-water heat pump system used BY-3 to produce hot water when the low temperature was 20 ℃. The following results were obtained: the highest temperature at the condenser outlet reached about 85 ℃; when the difference between the water temperatures at the condenser outlet and the evaporator inlet was less than 40 ℃, the coefficient of performance (COP) was larger than 4; when the difference reached 55 ℃, the COP still kept 3; the discharge temperature of BY-3 was lower than 100 ℃, and the refrigerant vapor pressure kept lower than 1.8 MPa. When the water temperature at the condenser outlet reached over 85 ℃, nearly a 5 ℃ superheating temperature was maintained.     

福州市闽江水源热泵技术应用基础数据库建设

对福州市境内闽江水的水温、水质和水位等重要参数开展测试工作,建立了福州市闽江水源热泵技术应用基础数据库。测试数据显示闽江水温在纵向断面上基本保持一致,相对气温变化稳定,适合作为冷热源。多项水质测试结果显示,主要水质指标均满足水源热泵机组的要求,闽江水存在浊度大和铁离子含量偏高的问题。闽江水位每日变化幅度受潮汐的影响较大,潮差自闽江口向闽江上游逐渐减少,其中马尾段每日最大水位差在2.58~5.34 m之间波动,水位年变化幅度为5.51 m。本研究旨在为福州市闽江水源热泵技术推广应用提供数据支撑。     

Parallel operation characteristics analysis of sewage source heat pump units in winter

Sewage source heat pump unit operates under partial load most of the time, and study on the law of coefficient of performance (COP) of the unit varying with load ratio can provide basis for the heat pump units running in high efficiency. A mathematical model determining COP, evaporation temperature and condensation temperature of a single unit was proposed. Under the condition of uniform load distribution, the model was established according to different ways of bearing partial load with the same type multiple units but different parallel operation models, and the operation characteristics of units were analyzed as well. Results show that the single screw water-source heat pump can maintain high COP only at 60%—100% load ratio, COP decreases sharply with the decrease of load ratio, and the units with parallel operation are controlled by the load ratio of a single unit according to the reduction of total load which can keep the average COP at high level within a wide load range.     

A novel application of the SAWD-Sabatier-SPE integrated system for CO2 removal and O2 regeneration in submarine cabins during prolonged voyages

To improve the working and living environment of submarine crews, an integrated system of CO2 removal and O2 regeneration was designed to work under experimental conditions for 50 people in a submarine cabin during prolonged voyages. The integrated system comprises a solid amine water desorption （SAWD） unit for CO2 collection and concentration, a Sabatier reactor for CO2 reduction and a solid polymer electrolyte （SPE） unit for O2 regeneration by electrolysis. The performances of the SAWD-Sabatier-SPE integrated system were investigated. The experimental results from the SAWD unit showed that the average CO2 concentration in the CO2 storage tank was more than 96% and the outlet CO2 concentration was nearly zero in the first 45 min, and less than 1/10 of inlet CO2 after 60 min when input CO2 was 0.5% （1000 L）. About 950 L of CO2 was recovered with a recovery rate of 92%-97%. The output CO2 concentration was less than 0.2%, which showed that the adsorption-desorption performance of this unit was excellent. In the CO2 reduction unit we investigated mainly the start-up and reaction performance of the Sabatier reactor. The start-up time of the Sabatier reactor was 6, 8 and 10 rain when the start-up temperature was 187.3, 179.5 and 168 ℃, respectively. The product water was colorless, transparent, and had a pH of 6.9-7.5, and an electrical conductivity of 80μs/cm. The sum of the concentration of metal ions （Ru^3＋, Al^3＋, Pb^2＋） was 0.028% and that of nonmetal ions （Cl^-, SO4^2-） was 0.05%. In the O2 regeneration unit, the O2 generation rate was 0.48 m^3/d and the quantity was 2400 L, sufficient to meet the submariners＇ basic oxygen demands. These results may be useful as a basis for establishing CO2-1evel limits and O2 regeneration systems in submarines or similar enclosed compartments during prolonged voyages.     

Experimental and model comparisons of H2O2 assisted UV photodegradation of Microcystin-LR in simulated drinking water

The degradation of Microcystin-LR （MC-LR） in water by hydrogen peroxide assisted ultraviolet （UV/H2O2） process was investigated in this paper. The UV/H2O2 process appeared to be effective in removal of the MC-LR. MC-LR decomposition was primarily ascribed to production of strong and nonselective oxidant-hydroxyl radicals within the system. The intensity of UV radiation, initial concentration of MC-LR, MC-LR purity, dosages of H2O2, the initial solution pH, and anions present in water, to some extent, influenced the degradation rate of MC-LR. A modified pseudo-first-order kinetic model was developed to predict the removal efficiency under different experimental conditions.     

微分求积法求解不可压二阶粘弹性流体和热迁移模型中的稳态流动

1IntroductionAlthoughthe computation of the fluid mechanics hasgreat development during the last decades,due to themodel in nonlinear fluid mechanics is very complicat-ed,the more efficient techniques for solvingthis prob-lemstill attract the interest of many researchers.Thedifferential quadrature method(DQM)introduced byBell man,et al.[1,2]is an efficient numerical methodfor solving partial differential equations.In recentyears,the DQMhas been widely used for solving theproblems of enginee…     

Effect of CO2 enrichment on the glucosinolate contents under different nitrogen levels in bolting stem of Chinese kale (Brassica alboglabra L.)

The effects of CO2 enrichment on the growth and glucosinolate (GS) concentrations in the bolting stem of Chinese kale (Brassioa alboglabra L.) treated with three nitrogen (N) concentrations (5, 10, and 20 mmol/L) were investigated. Height,stem thickness, and dry weights of the total aerial parts, bolting stems, and roots, as well as the root to shoot ratio, significantly increased as CO2 concentration was elevated from 350 to 800 μl/L at each N concentration. In the edible part of the bolting stem,11 individual GSs were identified, including 7 aliphatic and 4 indolyl GSs. GS concentration was affected by the elevated CO2 concentration, N concentration, and CO2×N interaction. At 5 and 10 mmol N/L, the concentrations of aliphatic GSs and total GSs significantly increased, whereas those of indolyl GSs were not affected, by elevated atmospheric CO2. However, at 20 mmol N/L,elevated CO2 had no significant effects on the concentrations of total GSs and total indolyl GSs, but the concentrations of total aliphatic GSs significantly increased. Moreover, the bolting stem carbon (C) content increased, whereas the N and sulfur (S) contents decreased under elevated CO2 concentration in the three N treatments, resulting in changes in the C/N and N/S ratios.Also the C/N ratio is not a reliable predictor of change of GS concentration, while the changes in N and S contents and the N/S ratio at the elevated CO2 concentration may influence the GS concentration in Chinese kale bolting stems. The results demonstrate that high nitrogen supply is beneficial for the growth of Chinese kale, but not for the GS concentration in bolting stems, under elevated CO2 condition.     

Effect of CO2 enrichment on the glucosinolate contents under different nitrogen levels in bolting stem of Chinese kale (Brassica alboglabra L.)

The effects of CO₂ enrichment on the growth and glucosinolate (GS) concentrations in the bolting stem of Chinese kale (Brassica alboglabra L.) treated with three nitrogen (N) concentrations (5, 10, and 20 mmol/L) were investigated. Height, stem thickness, and dry weights of the total aerial parts, bolting stems, and roots, as well as the root to shoot ratio, significantly increased as CO₂ concentration was elevated from 350 to 800 μl/L at each N concentration. In the edible part of the bolting stem, 11 individual GSs were identified, including 7 aliphatic and 4 indolyl GSs. GS concentration was affected by the elevated CO₂ concentration, N concentration, and CO₂×N interaction. At 5 and 10 mmol N/L, the concentrations of aliphatic GSs and total GSs significantly increased, whereas those of indolyl GSs were not affected, by elevated atmospheric CO₂. However, at 20 mmol N/L, elevated CO₂ had no significant effects on the concentrations of total GSs and total indolyl GSs, but the concentrations of total aliphatic GSs significantly increased. Moreover, the bolting stem carbon (C) content increased, whereas the N and sulfur (S) contents decreased under elevated CO₂ concentration in the three N treatments, resulting in changes in the C/N and N/S ratios. Also the C/N ratio is not a reliable predictor of change of GS concentration, while the changes in N and S contents and the N/S ratio at the elevated CO₂ concentration may influence the GS concentration in Chinese kale bolting stems. The results demonstrate that high nitrogen supply is beneficial for the growth of Chinese kale, but not for the GS concentration in bolting stems, under elevated CO₂ condition. Project (No. 2007CB109305) supported by the National Basic Research Program (973) of China     

Development and validation of an individualized nomogram for early prediction of the duration of SARS-CoV-2 shedding in COVID-19 patients with non-severe disease

With the number of cases of coronavirus disease-2019(COVID-19) increasing rapidly, the World Health Organization(WHO) has recommended that patients with mild or moderate symptoms could be released from quarantine without nucleic acid retesting, and self-isolate in the community. This may pose a potential virus transmission risk. We aimed to develop a nomogram to predict the duration of viral shedding for individual COVID-19 patients. This retrospective multicentric study enrolled 135 patients as a training cohort and 102 patients as a validation cohort. Significant factors associated with the duration of viral shedding were identified by multivariate Cox modeling in the training cohort and combined to develop a nomogram to predict the probability of viral shedding at 9, 13, 17, and 21 d after admission. The nomogram was validated in the validation cohort and evaluated by concordance index(C-index), area under the curve(AUC), and calibration curve. A higher absolute lymphocyte count(P=0.001) and lymphocyte-to-monocyte ratio(P=0.013) were correlated with a shorter duration of viral shedding, while a longer activated partial thromboplastin time(P=0.007) prolonged the viral shedding duration. The C-indices of the nomogram were 0.732(95% confidence interval(CI): 0.685-0.777) in the training cohort and 0.703(95% CI: 0.642-0.764) in the validation cohort. The AUC showed a good discriminative ability(training cohort: 0.879, 0.762, 0.738, and 0.715 for 9, 13, 17, and 21 d; validation cohort: 0.855, 0.758, 0.728, and 0.706 for 9, 13, 17, and 21 d), and calibration curves were consistent between outcomes and predictions in both cohorts. A predictive nomogram for viral shedding duration based on three easily accessible factors was developed to help estimate appropriate self-isolation time for patients with mild or moderate symptoms, and to control virus transmission.