Mobilities of gaseous ions in CH3NO2H2 and CH3CNH2 mixtures

Extending previous investigations by Loeb of mobilities in gaseous mixtures using his procedure except that the auxiliary field in these measurements was made equal to the advancing field thus giving absolute values of the mobilities, measurements of mobilities were made in mixtures of CH₃NO₂H2 and CH₃CNH₂. The mobilities in H₂ were 7.12 for the positive ions and 10.46 for the negative ions in cm./sec. per volt/cm. Those in CH₃NO₂ were 0.221 cm./sec. per volt/cm. for both ions and in CH₃CN they were 0.234 cm./sec. per volt/cm. for both ions. Both ion mobilities deviated from Blanc's law in CH₃NO₂ indicating the formation of complexes with the CH₃NO₂ ions somewhat greater in size than the normal ions in H₂. The molecules attached to negative ions somewhat less readily than to the positive ions but both final ions were of the same size. In CH₃CN mixtures both positive and negative ions deviated from Blanc's law, the positive ion showing more ready attachment of CH₃CN. The negative ion had consistently a higher mobility than the positive ion, a circumstance indicating a smaller ion and suggesting that the attaching molecule might not be CH₃CN but some impurity. Both ion addition products in CH₃CN are larger than the normal ion in H₂ but smaller than those in CH₃NO₂ as was to be expected.     

新疆森林游憩区空气负离子浓度时空分布特征及其影响因素

以新疆阿尔泰山、天山、准格尔盆地西部山地等新疆主要林区的7个森林游憩区及其周边的8个城市为对象,对空气负离子浓度进行动态监测和时空分布特征分析,进而对各地空气质量等级进行对比分析,并初步探讨导致各观测点空气负离子浓度差异的影响因素。结果表明:1森林游憩区的空气负离子浓度日动态在早(7∶00)和晚(18∶00)较高,午间(13∶00)较低;2森林游憩区内不同生态功能区的平均空气负离子浓度有差异,水体、林地两个生态功能区显著高于游客聚集区、停车场两个生态功能区(p0.05);3以空气负离子角度开展森林游憩区空气质量评价是合理可行的,7个森林游憩区空气负离子浓度显著高于对应的8个城市(p0.05),70%以上的森林游憩区空气质量等级为A级,8个城市空气质量等级均在C级以下;4不同的森林游憩区,空气质量也有一定差异,7个森林游憩区空气质量等级顺序为:青河哈纳斯那拉提天池水西沟哈密林场巴尔鲁克山;5森林游憩区各生态功能区的空气负离子浓度与气温均呈显著的负相关关系(p0.001),与空气相对湿度均呈显著的正相关关系(p0.001),且林区的空气负离子浓度与温度和湿度的相关系数均高于水体、游客聚集区、停车场等其他生态功能区。     

远红外线与空气负离子生物学效应及其临床应用

文章从远红外线和空气负离子的基本概念和特征入手,分析了远红外线和空气负离子的生物学效应,并对国内外的相关临床应用做了一定的蔬理,认为远红外线主要的功效是消炎止痛、促进组织再生与修复、消毒灭菌和抑制肿瘤等;而空气负离子对呼吸系统、循环系统和神经系统疾病均有明显的疗效。     

Light-driven directional ion transport for enhanced osmotic energy harvesting

Light-driven ion (proton) transport is a crucial process both for photosynthesis of green plants and solar energy harvesting of some archaea. Here, we describe use of a TiO₂/C₃N₄ semiconductor heterojunction nanotube membrane to realize similar light-driven directional ion transport performance to that of biological systems. This heterojunction system can be fabricated by two simple deposition steps. Under unilateral illumination, the TiO₂/C₃N₄ heterojunction nanotube membrane can generate a photocurrent of about 9 μA/cm², corresponding to a pumping stream of ∼5500 ions per second per nanotube. By changing the position of TiO₂ and C₃N₄, a reverse equivalent ionic current can also be realized. Directional transport of photogenerated electrons and holes results in a transmembrane potential, which is the basis of the light-driven ion transport phenomenon. As a proof of concept, we also show that this system can be used for enhanced osmotic energy generation. The artificial light-driven ion transport system proposed here offers a further step forward on the roadmap for development of ionic photoelectric conversion and integration into other applications, for example water desalination.     

The conductance of aqueous solutions of electrolytes

Since the Debye-Hückel theory clearly indicates, from thermodynamic considerations, that strong electrolytes are substantially completely dissociated in aqueous solutions, it has been necessary to replace, in the explanation of the conductances of such electrolytes, the Arrhenius theory, which assumes partial dissociation and constant ion mobilities, with a theory which provides for changing mobilities with increasing ion concentrations. To this end Debye and Hückel, and Onsager, suggest two mechanisms: the “electrophoretic effect” and “the time of relaxation effect,” both dependent upon interionic electrostatic attractions and repulsions. Experimental tests of Onsager's relations show that his equations account accurately, at least for very dilute solutions, for the changes with concentration of the conductances of solutions of electrolytes containing ions of widely differing mobilities and valencies. For higher concentrations semi-empirical equations are available. In contrast to the Arrhenius theory, the newer ideas call for changes in the transference numbers with the concentration, which have been found experimentally. Precision transference measurements have also furnished an experimental test of Kohlrausch's law of independent mobilities of ions. The theory of interionic attractions and repulsions is, in addition, of utility in dealing with the ionic part of solutions of weak electrolytes. By computing degrees of dissociation in a manner which allows for changing ion mobilities a test is obtained of the Debye-Hückel limiting relation connecting activity coefficients with ion concentrations.     

Nest without birds: Inventor mobility and the left-behind patents

The mobility of inventors leaves behind their patented inventions at sourcing firms, yet there is little scholarly insight into how firms handle those intellectual properties. We investigate this important issue by developing a framework of tacit-codified knowledge interdependence. We theorize that tacit and codified knowledge offer the intellectual and legal pillars of corporate inventions, which complement each other in value creation. Inventor mobility decouples the two pillars and reduces the maintenance likelihood of the left-behind patents. The negative impact is greater for inventions that are complex or rely less on internal prior art because the tacit knowledge loss is more destructive and unrecoverable. However, when inventors move to competing or litigious target firms, the relationship between mobility and patent maintenance becomes less negative or even turns positive because the left-behind patents can be leveraged to hedge against the risk of knowledge leakage. Applying a two-stage Coarsened Exact Matching approach to construct a sample of 36,204 U.S. patents with comparable leaving and staying inventors from public firms between 1983 and 2010, we find strong evidence supporting our framework. Our findings highlight the intricate interdependence of tacit and codified knowledge in corporate inventions and add to the literatures on inventor mobility and intellectual property management.     

Destination unknown: Pursuing sustainable mobility in the face of rival societal aspirations

A growing volume of scholarship and policy practice focuses on developing societal capacity to guide transitions of socio-technical systems toward more sustainable alternatives. Because several prominent modes of transportation are widely regarded as systemically problematic, the notion of sustainable mobility has received considerable attention from the standpoint of system innovation. Sustainability though constitutes only one of many contemporary political objectives and public commitment to goals consistent with such a future is highly equivocal. A related challenge arises from the ambivalence that sustainability champions often harbor on an individual level. It is probable that efforts to facilitate sustainable mobility will need to be reconciled with rival societal aspirations such as the pursuit of faster and more convenient forms of travel. Drawing on insights from the multi-level perspective, this article contrasts the relatively static automobility system with its more dynamic aeromobility counterpart and explores why evidence of an incipient transition is more apparent within the realm of aviation. In particular, the diffusion of “personal aeromobility” involving the use of small airplanes for on-demand, point-to-point air travel raises perplexing questions for the governance of sustainable mobility.     

Hydrodynamic resistance and mobility of deformable objects in microfluidic channels

This work reports experimental and theoretical studies of hydrodynamic behaviour of deformable objects such as droplets and cells in a microchannel. Effects of mechanical properties including size and viscosity of these objects on their deformability, mobility, and induced hydrodynamic resistance are investigated. The experimental results revealed that the deformability of droplets, which is quantified in terms of deformability index (D.I.), depends on the droplet-to-channel size ratio ρ and droplet-to-medium viscosity ratio λ. Using a large set of experimental data, for the first time, we provide a mathematical formula that correlates induced hydrodynamic resistance of a single droplet ΔR_d with the droplet size ρ and viscosity λ. A simple theoretical model is developed to obtain closed form expressions for droplet mobility ? and ΔR_d. The predictions of the theoretical model successfully confront the experimental results in terms of the droplet mobility ? and induced hydrodynamic resistance ΔR_d. Numerical simulations are carried out using volume-of-fluid model to predict droplet generation and deformation of droplets of different size ratio ρ and viscosity ratio λ, which compare well with that obtained from the experiments. In a novel effort, we performed experiments to measure the bulk induced hydrodynamic resistance ΔR of different biological cells (yeast, L6, and HEK 293). The results reveal that the bulk induced hydrodynamic resistance ΔR is related to the cell concentration and apparent viscosity of the cells.     

科研人员省际流动网络分析及演化过程研究

   本文基于“科学家在线”平台数据,运用复杂网络分析方法,按照年份分别构建2010—2017年间全国34个省份之间科研人员流动网络模型,测度并分析8年间科研人员流动的复杂性网络整体特征和随时间变化的趋势。研究发现：（1）8年间科研人员流动呈现整体较为明显的“无标度”特性,即北京、上海、江苏等经济科技发达地区不仅流入科研人员的规模较大,流出科研人员的规模也不小,但是全国大部分省份流动科研人员规模较为有限;（2）除了小部分省份之外其余省份的人员流入流出相对较为均衡,一些经济科技发达省份在一定程度上也是全国或本区域科研人员流动的中心节点;（3）从发展态势来看,8年间全国省级科技人员流动态势相对平稳,但是省份之间科研人员流动规模差距越来越明显,经济科技发达省份与其他省份科研人员流动的规模相比差距越来越大;（4）最为突出的变化是流动人员规模显著增加,人员流动更加便利。     

Polyphosphonium-based ion bipolar junction transistors

Advancements in the field of electronics during the past few decades have inspired the use of transistors in a diversity of research fields, including biology and medicine. However, signals in living organisms are not only carried by electrons but also through fluxes of ions and biomolecules. Thus, in order to implement the transistor functionality to control biological signals, devices that can modulate currents of ions and biomolecules, i.e., ionic transistors and diodes, are needed. One successful approach for modulation of ionic currents is to use oppositely charged ion-selective membranes to form so called ion bipolar junction transistors (IBJTs). Unfortunately, overall IBJT device performance has been hindered due to the typical low mobility of ions, large geometries of the ion bipolar junction materials, and the possibility of electric field enhanced (EFE) water dissociation in the junction. Here, we introduce a novel polyphosphonium-based anion-selective material into npn-type IBJTs. The new material does not show EFE water dissociation and therefore allows for a reduction of junction length down to 2 μm, which significantly improves the switching performance of the ion transistor to 2 s. The presented improvement in speed as well the simplified design will be useful for future development of advanced iontronic circuits employing IBJTs, for example, addressable drug-delivery devices.There has been a recent interest in developing diodes^1–4 and transistors^4–8 that conduct and modulate ion currents. Such non-linear iontronic components are, for example, interesting as they allow further control of ions in, for instance, electrophoretic drug delivery devices. A range of microfabricated diodes,^9–11 transistors,^12,13 and circuits^9,14 has been constructed using ion-selective membranes. These membranes contain fixed charges of either polarity, compensated by mobile ions of opposite charge (counter-ions). When immersed in an electrolyte, counter-ions can move through the membrane, while ions with the same charge as the fixed charges (co-ions) are repelled. This renders the membrane selective for the counter-ion and can therefore be considered as p- or n-type ion conductors. By combining two membranes of opposite polarity, a bipolar membrane (BM) configuration is obtained¹⁵ (Figure 1(a)). The BM junction can be biased by an ion current in the reverse and forward directions, respectively.^16,17 This modulates the ion concentration inside the BM, and thus the ionic conductivity, which then results in an current rectification.^2,18 In the three-terminal ion bipolar junction transistor¹² (IBJT), an ion-selective base (B) is connected to oppositely selective emitter (E) and collector (C), forming two BM configurations (EB and BC) (Figure 1(b)). pnp- and npn-IBJTs have been constructed¹⁴ from photolithography patterned poly(styrene sulfonate) (PSS, p-selective) and quaternized poly(vinylbenzyl chloride) (n-selective) as emitter, collector, and base. In these devices, a neutral poly(ethylene glycol) (PEG) electrolyte is typically inserted into the junction to separate the base from the emitter and collector,¹² in order to avoid¹⁹ electric field enhanced (EFE) water dissociation¹⁶ (Figure 1(a)). EFE water dissociation is typically observed in BMs²⁰ and produces water ions inside the BM under reverse bias, which prevents proper IBJT operation. In PEG-IBJTs, the current between the emitter and collector (I_C) is thus modulated by controlling the ion concentration inside the PEG-junction.²¹ Ions are injected or extracted into the junction depending on the bias of the base (V_EB). In a npn-IBJT, a positive bias is typically applied between emitter and collector (V_EC), thus allowing anions to migrate from the emitter to the collector. In the cut-off mode (Figure 1(c)), a negative bias V_EB is applied, resulting in reverse bias of both EB and BC. Cations in the junction will migrate into the base, while anions will primarily migrate into the collector, due to the higher collector bias. This base current (I_B) will extract ions from the junction, which decreases the ionic conductivity in the junction resulting in a low I_C. Eventually, the resistive characteristics for ion charge transport, between the emitter and collector, will be entirely dominated by the junction. This gives that most of the applied V_EC is consumed across the junction with only a minimal voltage potential drop across the emitter and base terminals.Open in a separate windowFIG. 1.(a) The modes of operation for a BM; forward bias (high conduction and ion accumulation), reverse bias (low conduction and ion depletion), and EFE water dissociation (high conduction, formation of ions). (b) Illustrations of an npn-IBJT, with anion-selective emitter (E) and collector (C) forming a junction with a cation-selective base (B). (c) In cut-off mode, the base and collector extract ions from the junction, prohibiting co-ion migration through the base. (d) In active mode, the forward biased EB injects ions into the base, thus allowing anions from the emitter to migrate as co-ions through the base into the collector.In the active-mode of the npn-IBJT (Figure 1(d)), the V_EB bias at the base is reversed (i.e., now positive). This causes injection of cations, from the base, and anions, from the emitter, into the junction. As the ion concentration increases, anions from the emitter can start to drift across the junction to the collector, thus a high I_C is obtained. The high concentration of ions inside the junction is reflected in a low resistive value for ion transport. This now causes the voltage to drop over the emitter and collector terminals, thus lowering the EB forward bias and the injection of ions from the base. At the collector-junction interface, the extraction of anions produces an ion depletion zone and a corresponding voltage drop. Thus, in the active-mode, the applied V_EC is primarily consumed across the emitter and collector terminals and also at the collector-junction interface.The switching speed of an IBJT should be strongly correlated to the distance separating the emitter and collector,¹⁴ as this length determines the volume that needs to be filled or emptied with ions causing modulation of ions in the junction. To achieve a fast-switching IBJT, the junction volume, i.e., the collector-emitter separation, should be as small as possible. However, EFE water dissociation must be avoided since this process ruin the IBJT operation. EFE water dissociation is, in part, driven by the appearance of a large potential drop across a small distance, as occurring at the interface of a BM under reverse bias, producing a high electric field that accelerates the forward reaction rate of water auto-dissociation.¹⁶ Miniaturization of the collector-emitter distance is therefore problematic, as the separation inside the EB and BC BMs evidently also mush shrink, resulting in higher reverse bias electric fields across the BMs and thus promoting EFE water dissociation. The problem of EFE water dissociation in an IBJT primarily manifests itself in the cut-off mode, as water ions are generated in the reversed biased EB and BC BMs. These ions produce an elevated cut-off I_C, and hence deteriorate the IBJTs on–off performance. Here, we report an IBJT, in which the EFE water dissociation is avoided by the use of a novel polyphosphonium-based anion-selective material, which previously has been shown to prevent EFE water dissociation in BM diodes.¹¹ This allows the collector and emitter to directly contact the base without an intermediate PEG-layer. Without the need for a PEG-separator inside the BMs, the collector-emitter distance is reduced to only 2 μm.Polyphosphonium-based npn-IBJTs were produced following the same manufacturing protocol as was reported for polyphosphonium-based ion diodes.¹¹ Conjugated polymer electrodes and cation-selective base was patterned from ∼200 nm thick poly(3,4-ethylenedioxythiophene):polystyrene sulfonate film on polyethylene terephthalate-sheets using photolithography and dry-etching. The base was rendered electronically insulating by chemical overoxidation via exposure to sodium hypochlorite through a mask. A 2 μm thick SU8-layer was patterned on-top of this configuration, with an opening defining the actual junction. 1 μm thick polyphosphonium-based anion-selective emitter and collector were deposited and patterned using photolithography and dry-etching, to overlap with the base at the opening of the SU8. Finally, a second 10 μm thick layer of SU8 was used to seal the junction. The membranes were hydrated by incubation in dH2O for 24 h before any measurements were carried out. Aqueous 0.1M NaCl electrolytes were used during the measurement. All electrical measurements were performed using a Keithley 2602 source meter.The switching characteristics of the npn-IBJT were obtained by applying V_EC of 10 V and alternating V_EB at ±3 V for various duration of time, see Figure ​Figure2.2. A periodic 5 s switching with 8 Hz measurement rate was used to record the dynamics of the turn-on/off characteristics of the device. When V_EB switches from −3 to +3 V, there is a quick increase in the I_B, as ions from the base and emitter migrate into the emitter/base junction. After a delay of ∼0.25 s, I_C starts to increase due to the increased ion concentration in the emitter/base junction and the subsequent diffusion of anions into the base. As the I_C increases, the I_B decreases as the voltage drop between the emitter and base decreases, and after ∼2 s I_C reaches 90% of the steady state on-current level. For longer on-switching times, the I_B and I_C stay stable over 30 s, after which a small increase is observed. This current-drift in both I_B and I_C is likely due to the contribution of co-ion migration. As cations from the base migrate into the emitter as co-ions, the conductivity in the emitter increases, leading to an increased I_C value. This increases the ion concentration at the base, which gives less selective ion injection and thus more cation injection from the base, i.e., a higher I_B.Open in a separate windowFIG. 2.Emitter-collector current response as the IBJT is switched between cut-off (V_EB = −3 V) and active mode (V_EB = 3 V) for V_EC = 10 V, at 5 s and 120 s periods.As V_EB is switched back to −3 V, there is a sharp negative peak in I_E as ions are extracted from the junction, which occur mainly through the base (cations) and collector (anions) terminals. As the ion concentration in the base drops, I_C decreases. The transistor turns off to 10% of the value of the steady state on-current within ∼2 s, regardless of the duration of the on-state. The constant turn-off time indicates that ions are not accumulating to a significant extent inside the junction during the on-steady state but are instead constantly transported out of the junction. When all co-ions have been extracted from the junction, the Donnan exclusion prevents subsequent injection of anions into the base, and I_C is therefore low. The on/off ratio of I_C reaches above 100.A transfer curve was obtained by scanning V_EB between −3 and +3 V while keeping V_EC at 10 V (Figure 3(a)). As expected, both I_C and I_B remain low for negative V_EB. In this range, both EB and BC are biased in reverse direction. As V_EB turns positive, the EB configuration is switched into forward bias and ions are injected into the junction. This leads to a linear increase in I_C vs. V_EB. For the reverse scan, a minor hysteresis is observed for both the I_C and I_B scans, again probably due to the contribution of co-ion migration due to long time operation of the device.Open in a separate windowFIG. 3.Transfer and output curves. (a) The transfer curve is low for negative V_EB and increases linearly for positive V_EB with approximately zero threshold. (b) The output curves show I_C saturating with respect of V_EC for positive V_EB.The transistor output characteristics were obtained by scanning V_EC at different V_EB values (Figure 3(b)). The saturation regime, i.e., the bias mode was both EB and BC are in forward bias, was avoided as this has negative impact on the stability of the device. As reported for previous IBJT devices, the output characteristics show a clear saturation behaviour of I_C across the entire range of V_EC. Further, the I_C increases linearly with V_EB. The increase of both I_C and I_B when operating for extended periods of time in the active mode is again attributed to the addition and inclusion of co-ions in the junction. The current gain (I_C/I_B) at V_EC = 10 V decreases with V_EB and reaches 43.9, 17.9, and 10.7 for V_EB = 1 V, 2 V, and 3 V, respectively. For higher base bias voltages, the ion concentration increases in the junction and thus the injection selectivity decreases.In comparison with previously reported IBJTs,^12,14,21 the lack of a neutral electrolyte layer in the junction has an overall positive effect on the device characteristics. Main performance improvements are found in a decrease in the turn-on time from 9 s (for npn-IBJT²¹) to 2 s, for devices with comparable junction widths and heights. The main contribution to the improved switching speed is likely the decreased length between the emitter and collector. Interestingly, simulations have shown that an extended space charge region (ESCR), for a PEG-IBJT in cut-off mode, can extend several micrometers away from the collector.²² Thus, a PEG-IBJT with an emitter-collector separation of single micrometers should show an increased cut-off current due to the ESCR overlapping in the junction. However, by omitting the PEG in the junction, the ESCR is reduced due to screening from the fixed charges in the BM layers. This enables the IBJT, reported here, to operate with retained low cut-off currents. On-off ratios and ion current gains are approximately equal to previous IBJTs,^12,14,21 at above 100 and 10, respectively. The on–off ratio and ion current gain are more dependent on the selectivity of the membranes and the charge of the junction.Further, the need to separate the layers in a PEG-IBJT puts high demands on the patterning resolution and alignment accuracy to reduce the separation between emitter/collector and base. As polyphosphonium allows the IBJT to be built without separation of layers, miniaturization of the junction is relatively easier to obtain. The switching speed can potentially be further improved by retaining the base material between the emitter and collector (see Figure 1(b)), thus allowing for a more direct pathway for I_C. This design would, however, require a much more accurate layer alignment or that the base patterned on top of the emitter and collector layers. In general, such modifications of device geometry are simpler to accomplish with the non-EFE water dissociating polyphosphonium as fewer active layers are used, suggesting a further use of polyphosphonium to improve switching speed and miniaturization of IBJTs. Such further advancement in IBJT performance would be welcomed, for example, in the continued work towards complex ionic circuits¹⁴ to regulate signalling in bioelectronics and in drug delivery applications, in which generation of dynamic and complex gradients, at high spatial resolution, is of generic interest.     

Untangling the contributions of meteorological conditions and human mobility to tropospheric NO2 in Chinese mainland during the COVID-19 pandemic in early 2020

In early 2020, unprecedented lockdowns and travel bans were implemented in Chinese mainland to fight COVID-19, which led to a large reduction in anthropogenic emissions. This provided a unique opportunity to isolate the effects from emission and meteorology on tropospheric nitrogen dioxide (NO₂). Comparing the atmospheric NO₂ in 2020 with that in 2017, we found the changes of emission have led to a 49.3 ± 23.5% reduction, which was ∼12% more than satellite-observed reduction of 37.8 ± 16.3%. The discrepancy was mainly a result of changes of meteorology, which have contributed to an 8.1 ± 14.2% increase of NO₂. We also revealed that the emission-induced reduction of NO₂ has significantly negative correlations to human mobility, particularly that inside the city. The intra-city migration index derived from Baidu Location-Based-Service can explain 40.4% ± 17.7% variance of the emission-induced reduction of NO₂ in 29 megacities, each of which has a population of over 8 million in Chinese mainland.     

Electron diffusion,electron attachment,and the aging of negative ions in commercial nitrogen at atmospheric pressure

A criticism by Loeb and Bradbury of my interpretation of the experimental results of that part of a previous paper which dealt with the aging of negative ions in commercial nitrogen is shown to be invalidated by a mistake in their analysis and by assumptions which do not represent facts with sufficient accuracy. A more extended analysis of the previous work and new evidence which is given confirm the correctness of the former contention that the negative ions in question changed in size with age. The lateral spread, owing to diffusion, of a stream of electrons in this nitrogen at atmospheric pressure, when moving in an electric field of about 100 volts/cm., was found to be very nearly the same as that for positive ions under like conditions. The average energy losses of the electrons at collision with the molecules must therefore have nearly balanced the gains from the electric field and hence were greater than would result from purely elastic collisions. The experimental results indicate that in fields down to at least 20 volts/cm. nearly all of the attachment of electrons to molecules in the gas used occurred close to the place of their liberation.     

Dissociative attachment

The reaction of an electron with a molecule AB which leads to dissociation of the molecule into a neutral component and a negative ion, is known as dissociative attachment. Such reactions are important sources of negative ions and may be used for the design of very sensitive detectors for certain compounds. They are of basic importance in determining the high dielectric strength of certain gases and vapours as well as in the design of gaseous lasers. The detailed study of the reactions leads to insight into reaction mechanisms and provides new information about molecular parameters. This article reviews the application of modern experimental and theoretical techniques to the subject.     

Electro-osmotic mobility of non-Newtonian fluids

Electrokinetically driven microfluidic devices are usually used to analyze and process biofluids which can be classified as non-Newtonian fluids. Conventional electrokinetic theories resulting from Newtonian hydrodynamics then fail to describe the behaviors of these fluids. In this study, a theoretical analysis of electro-osmotic mobility of non-Newtonian fluids is reported. The general Cauchy momentum equation is simplified by incorporation of the Gouy–Chapman solution to the Poisson–Boltzmann equation and the Carreau fluid constitutive model. Then a nonlinear ordinary differential equation governing the electro-osmotic velocity of Carreau fluids is obtained and solved numerically. The effects of the Weissenberg number (Wi), the surface zeta potential (ψ¯s), the power-law exponent(n), and the transitional parameter (β) on electro-osmotic mobility are examined. It is shown that the results presented in this study for the electro-osmotic mobility of Carreau fluids are quite general so that the electro-osmotic mobility for the Newtonian fluids and the power-law fluids can be obtained as two limiting cases.     

A different glimpse into mobilities: On the interrelations between daily spatial mobility and social mobility

We explore the link between daily spatial mobility and social mobility, taking changes in the contemporary labor market and family as examples. We propose a new theoretical approach to mobility that is defined as a productive force of social labor. Analyzing the relationship between daily spatial mobility and social mobility, we show that spatial mobility has become a strategy of compensation for the lack of social mobility. Explanations for the increase in daily spatial mobility are also provided. Lastly, we reveal how spatial mobility has the capacity to produce major social change, taking the family as an example.     

基于LMDI模型的中国主要大气污染物的空间差异及其影响因素分析

为挖掘大气污染物排放量和污染治理效果的主要影响因素,本文运用LMDI分解模型,对全国和30个省份2000-2010年间的主要大气污染物排放量的变化进行因素分解,并通过构建四象限法评价地区差异。在此基础上,从技术效应、结构效应和规模效应三方面分析治理投资等因素对SO2去除量的贡献。研究结果显示:在影响大气污染物排放量变化的五个因素中,大气污染物末端治理措施、能源结构和能源强度对SO2、烟尘的排放量变化率呈现负向效应,尤其是末端治理措施负向效应最大,"十五"时期和"十一五"时期,其对SO2排放量变化的贡献度均值由-10.4%变为-49.9%、对烟尘的贡献度由-60.7%变为-73.7%,而经济规模和煤炭污染强度呈现正向效应,经济规模贡献度高达50%以上,但呈下降趋势。针对SO2去除量变化率的分解结果显示中国大气污染治理由规模和结构拉动型转为技术和规模拉动型,各省间技术效应和结构效应差别较大、规模效应差异小。     

The role of surface instability in electrical discharges from drops of alcohol and water in air at atmospheric pressure

A study of previous work on discharges from charged attached drops and from uncharged drops falling in electric fields shows that the surface electric intensities at these drops, when the discharges begin, satisfy the theoretical relations for surface instability. Glow discharges, if initially present, are conditioned by the surface deformation arising from instability. Experiments are described that indicate that the highly charged droplets ejected by an alcohol surface may have mobilities not much below those of normal air ions while such droplets coming from a water surface may have mobilities even greater than those of air ions. Calculations, by Stokes' Law, show such large mobilities for both kinds of drops to be possible. Further experiments show that under certain conditions the whole discharge current from an alcohol drop is carried solely by droplets of the liquid, resulting from surface instability, and under more restricted conditions the same may be true for a water drop.     

大学教师校际流动性的实证分析—基于Web内容分析数据与国际调查结果的比较

作者对我国大学教师进行分层整群抽样得到一个大样本(27所高校的4890名教师),从各校的师资网页上收集了每个教师的简历资料并用内容分析法分析得到了我国大学教师流动数据(有效个案数2354人);对该数据及卡内基国际调查数据采用"人均校际流动期望值"等指标进行了统计分析和中国外比较。分析结果表明:我国大学教师的校际流动性在所有国家中最低,美英德等欧美国家大学教师的流动性高于亚洲各国而居于中等程度;要使我国大学教师的流动性适度提高,必须强化大学教师的学术职业身份属性、完善职称制度和聘任制度,以优良的学术条件吸引教师人才。     

澜沧江流域潜在蒸散发敏感性分析

蒸散发对气候变量的敏感性研究是近年来水文学的热点之一,对探讨水循环对气候变化的响应具有重要意义。本文利用1960年-2005年澜沧江流域及其周边35个气象站的逐日常规气象观测数据,基于Penman-Monteith公式,计算了1月、7月及年3个不同时间尺度下潜在蒸散发对平均气温、相对湿度、风速及日照时数的敏感系数,分析了澜沧江流域潜在蒸散发对各气候变量的敏感性及其时空变化规律。结果表明各站潜在蒸散发对各变量的敏感系数空间分异明显,流域整体上对日照时数最为敏感。几十年来对日照时数的敏感性在1月主要为增加趋势,7月则为减小趋势。     

Learning-by-hiring: How do rival firms learn from focal firm's hiring

Previous studies provide evidence of learning from the mobility of scientists for the source and the hiring firms. However, we have a limited understanding of the competitive implications of such inter-firm mobility and associated learnings. Using a difference–in–difference approach on matched patents in the semiconductor industry in 1981–2010, we find that mobile scientists' patents receive more citations from rival firms after the mobility vis-à-vis before the mobility and vis-à-vis other similar patents. We conclude that rival firms respond to mobilities across other firms by attributing more attention to mobile scientists. Furthermore, the context of the mobility can determine the extent of response from rival firms. Rival firms are more likely to build on a mobile scientist's patents after mobility when the mobility occurs between technologically distant firms, the source firm or the hiring firm has low research experience, or the mobile scientist has considerable experience.