Enrichment of semi-volatile organic acids from aqueous solutions by multiple-effect membrane distillation

Multiple-effect membrane distillation(MEMD) process for enriching semi-volatile organic acids from their individual aqueous solutions was performed by using a hollow fiber-based air gap membrane distillation(AGMD)module with the function of internal heat recovery.Aqueous solutions of glyoxylic acid,glycolic acid,lactic acid,pyruvic acid,malonic acid and glutaric acid were used as model feed.For a feed of 1%(mass fraction),each acid could be enriched for 8-20 times,which depended on the surface tension of the concentrate.The operation performance of MEMD process was characterized by permeation flux J,performance ratio PR and acid rejection rate R.The effects of cold feed-in temperature,heated feed-in temperature,feed-in volumetric flow rate and feed-in concentration on MEMD performance were experimentally evaluated.Maximum values of J,PR and R were 4.8 L/(h·m 2),9.84 and 99.93%,respectively.Moreover,MEMD process demonstrated a fairly good stability in a long-term experiment lasting for 30 d when aqueous solution of 4%(mass fraction) lactic acid was used as a feed.     

常减压蒸馏装置的腐蚀与防护

茂石化炼油厂第一套常减压蒸馏装置近年来设备腐蚀情况日益严重,对装置的安全生产构成严重威胁,设备腐蚀一直是影响装置安全生产的隐患,该文通过对装置腐蚀原因的分析提出一些防腐措施,以供工程参考。     

现有蒸馏装置改炼国外轻质原油的方案探讨

该文介绍了现有常减压蒸馏装置改炼国外轻质原油过程中遇到的问题,并分析了解决问题的方法。     

低品位热能与潮汐能驱动的多效蒸馏海水淡化装置

提出了一种利用低品位热能和潮汐能驱动的多效蒸馏海水淡化技术,其特点是利用潮汐能代替传统电泵为系统运行提供动力,从而减少了系统运行对稳定电力供应的依赖,降低造水成本.根据该技术的原理,设计搭建了一套试验系统,测试并分析了给海水温度和加热水温度对该系统运行性能的影响.试验结果表明,当加热水温度为65℃,系统绝对压力为25kPa时,系统的淡水产量为27kg/h.通过试验和理论分析发现,选择合适的加热水温度是维持系统稳定运行的关键因素.     

民爆企业生产废水污染控制现状研究

通过对辽宁某民营爆破企业废水排放情况的分析,该企业的废水主要来源为DDNP废水,具有强酸性和强碱性、COD浓度高、某些污染物的毒性大等特点。现在采用减压蒸馏处理方法处理后,个别指标不能达到排放标准,为了进一步改善废水处理效果,拟采用双模工艺对该企业DDNP废水进行处理。     

Comparison of volatile and semivolatile compounds fromcommercial cigarette by supercritical fluid extractionand simultaneous distillation extraction

Supercritical carbon dioxide fluid extraction (SFE) was studied as a rapid method for extraction of volatile and semivolatile compounds of Chinese commercial cigarettes. The method was compared with simultaneous distillation and extraction (SDE). Temperature and pressure for the SFE were optimized. The extracts obtained by the two methods showed different characters in composition and represented differently the flavor characteristics of tobacco; compared to SDE, SFE can extract compounds within a shorter time and avoid the thermal degradation and solvent contamination of samples. The extracts by the two extraction methods are complementary for investigating the flavor characteristic of tobacco products.     

利用造纸厂废水污泥制备活性炭

以造纸废水处理厂污泥为主要原料,采用化学活化法制备活性炭,考查了活化剂的浓度、活化温度、活化时间、固液比等方面对污泥吸附性能的影响.结果表明:在氯化锌溶液为40%、活化温度为600℃、活化时间为15 min、固液比为1∶3的最佳条件下制备的污泥活性炭碘值达到320 mg·g-1,而加入10%的茶梗添加剂制备的活性炭碘值可达503 mg·g-1,因此引入添加剂可以改善污泥活性炭的吸附性能.利用该污泥活性炭处理含苯酚废水,具有较好的处理效果,因此加强开发并推广污泥制备活性炭新技术,实现废水污泥的资源化利用,成为处理剩余污泥的一种有效途径.     

Comparison of volatile and semivolatile compounds from commercial cigarette by supercritical fluid extraction and simultaneous distillation extraction

Supercritical carbon dioxide fluid extraction (SFE) was studied as a rapid method for extraction of volatile and semivolatile compounds of Chinese commercial cigarettes. The method was compared with simultaneous distillation and extraction (SDE). Temperature and pressure for the SFE were optimized. The extracts obtained by the two methods showed different characters in composition and represented differently the flavor characteristics of tobacco; compared to SDE, SFE can extract compounds within a shorter time and avoid the thermal degradation and solvent contamination of samples. The extracts by the two extraction methods are complementary for investigating the flavor characteristic of tobacco products.     

Removal of copper ions from electroplating rinse water using electrodeionization

An improved configuration of the membrane stack was adopted in the electrodeionization （EDI） cell to prevent precipitation of bivalent metal hydroxide during the running. The operational parameters that influenced the removal of copper ions from the dilute solution were optimized. The result showed that a moderate decrease in the inlet pH value and a moderate increase in the applied voltage could achieve a better removal effect. The steady process of electroplating wastewater treatment could be achieved with a removal efficiency of more than 99.5% and an enrichment factor of 5-14. The concentration of copper in purified water was less than 0.23 mg/L. This demonstrated the applicability of recovering heavy metal ions and purified water from electroplating effluent for industrial reuse.     

Effects of operative conditions on membrane fouling of jet loop membrane bioreactor

The orthogonal experiments, which involves three factors： aeration intensity, suction time and suction suspended time, were designed to research membrane fouling of jet loop membrane bioreactor （JLMBR）. Experimental results indicate that increasing aeration intensity, reducing suction time and increasing suction suspended time all could mitigate membrane fouling effectively. However excessive aeration intensity, too short suction time and excessive suction suspended time were bad for bioreactor running. The optimal aeration intensity, suction time and suction suspended time were 0.75 1.00 m3/（m2.h）, 8 -10 min and 4 -5 min, respectively. The three factors all had effect on membrane pollution rate, while the suction time was the most important one and followed by aeration intensity and suction suspended time. It also indicates that, comparing with traditional submerged membrane bioreactors, JLMBR had lower membrane pollution rate.     

Studies of the Extraction of Phenol by N-Octanoylpyrrolidine

1 IntroductionWasteWater containing phenol is a kind of industrialwaStowater that has eXtensive resources, and it isseriously hannful to our environxnent. Treatment ofwaSte water containing phenol by solvent extractionmethod generally selects extraCtants such as butylacetate, isopropyl ether, tributyl Phosphate (TBP) and N,N-di (l-methyl-heptyl) acetamide (N503) .to.['"]. Anew type of extractant, N-octanoylprplidine (OPOD),was synthesized in our laboratory for the first time.The experim…     

Interactions between mycoplasma lipid-associated membrane proteins and the host cells

Mycoplamas are a group of wall-less prokaryotes widely distributed in nature, some of which are pathogenic for humans and animals. There are many lipoproteins anchored on the outer face of the plasma membrane, called lipid-associated membrane proteins （LAMPs）. LAMPs are highly antigenic and could undergo phase and size variation, and are recognized by the innate immune system through Toll-like receptors （TLR） 2 and 6, LAMPs can modulate the immune system, and could induce immune cells apoptosis or death. In addition, they may associate with malignant transformation of host cells and are also considered to be cofactors in the progression of AIDS.     

紧扣要点正确掌握减压蒸馏操作技术

减压蒸馏是物质分离的重要技术 ,部分学生不能很好地掌握这项技术 ,原因在于对真空状态等概念的认识模糊。就正确掌握减压蒸馏操作技术的几个问题加以分析和讨论 ,以期对学生相关技术的训练起指导作用。     

除砷技术研究现状

介绍含砷废水对人类的危害，阐述除砷材料和含砷废水的处理方法的发展情况，以及各种除砷技术的优缺点．总结出在各种除砷方法中生物除砷将是最有发展前景的方法。     

质子交换膜燃料电池水管理的建模和分析

质子交换膜燃料电池的水管理是影响其性能的重要因素之一。电池水管理的目的就是要实现尽可能高的膜的水合程度,降低膜的阻抗。为了更好实现以上目标,文中建立了电池水传输模型,基于模型利用工程逼近分析方法,分析了阴阳极湿度、反应气体流量对膜的水含量和阴阳极水分压的影响。仿真结果通过与其他模型相比较,取得了一致的结果,因此也证明了该模型的有效和实用性。基于以上的分析结果为建立简化的膜水含量控制模型和实现水管理的控制目标奠定基础。     

New hybrid model of proton exchange membrane fuel cell

Model and simulation are good tools for design optimization of fuel cell systems. This paper proposes a new hybrid model of proton exchange membrane fuel cell (PEMFC). The hybrid model includes physical component and black-box com-ponent. The physical component represents the well-known part of PEMFC, while artificial neural network (ANN) component estimates the poorly known part of PEMFC. The ANN model can compensate the performance of the physical model. This hybrid model is implemented on Matlab/Simulink software. The hybrid model shows better accuracy than that of the physical model and ANN model. Simulation results suggest that the hybrid model can be used as a suitable and accurate model for PEMFC.     

Fenton氧化工艺在处理炼化废水中苯酚的应用研究

通过正交实验和单因素实验探索了Fenton氧化炼化废水中苯酚的最佳工艺条件。实验结果表明,Fenton试剂处理苯酚废水时,各影响因素的作用大小顺序是:p H反应温度H2O2投加量反应时间Fe SO4·7H2O投加量;最佳氧化反应条件为:p H=3.5,反应温度为20℃,H2O2投加量为12 m L·L-1,反应时间为30min,Fe SO4·7H2O投加量为450 mg·L-1,此时废水中苯酚的去除率为89.26%,残余苯酚含量为11.76 mg·L-1。因此,用Fenton氧化法处理含苯酚废水是一种非常有效的方法。     

真空预压技术加固海堤深厚软基原型试验研究

真空荷载提供了一种减少堤坝软土地基固结时间的选择. 本文开展了一个海堤全断面的试验及原型观测研究. 试验堤高5. 5 m, 22 m深且三角形布置的塑料排水板作为竖向排水通道, 现场布置了水平测斜和沉降仪等观测仪器, 埋设在不同地基深度的孔隙水压力计用来量测真空-堆载联合荷载下的地基中超静孔隙水压力的变化. 通过场地条件分析、高真空度维持和真空卸载, 得到了系统的沉降变形和孔隙水压力资料, 试验结果验证了真空-堆载联合预压加固海堤软土地基的效果.     

Phenol Tert-Butylation Catalyzed by Zeolite H-Mordenite

Para-tert-butyl phenol (p-TBP) and 2,4-di-tert-butyl phenol ( 2,4-DTBP) are wi.dely used for the preparation of antioxidants. Zeolite catalysts showed good performance for the synthesis of p-TBP and 2,4-DTBP. In this work, zeolite H-mordenite (HM) catalyst was prepared and the alkylation of phenol with tert-butyl alcohol over zeolite HM catalyst was investigated at different reaction conditions. It is found that increasing temperature enhances the selectivity to p-TBP and the optimum reaction temperature for phenol conversion is 438 K. Increasing flow rate decreases phenol conversion apparently while the selectivity to p-TBP has a little increase. The suitable tert-butyl alcohol/phenol molar ratio is 2. Lower alcohol/phenol molar ratios are beneficial to p-TBP while higher ones are helpful for producing 2,4-DTBP.     

Removal of hexavalent chromium from aqueous solution by iron nanoparticles

Groundwater remediation by nanoparticles has收稿日期increasing interest in recent years. This report presents a thorough evaluation of hexavalent chromium removal in aqueous solutions using iron (Fe0) nanoparticles. Cr(Ⅵ) is a major pollutant of groundwater. Zero-valent iron, an important natural reductant of Cr(Ⅵ), is an option in the remediation of contaminated sites, transforming Cr(Ⅵ) to essentially nontoxic Cr(Ⅲ). At a dose of 0.4 g/L, 100% of Cr(Ⅵ) (20 mg/L) was degraded. The Cr(Ⅵ) removal efficiency decreased significantly with increasing initial pH. Different Fe0 type was compared in the same conditions. The reactivity was in the order starch-stabilized Fe0 nanoparticles＞Fe0 nanoparticles＞Fe0 powder＞Fe0 filings. Electrochemical analysis of the reaction process led to the conclusion that Cr(OH)3 should be the final product of Cr(Ⅵ). Iron nanoparticles are good choice for the remediation of heavy metals in groundwater.