Validating chemical and structural changes in painting materials by principal component analysis of spectroscopic data using internal mineral standards

This work shows the capability of principal component analysis (PCA) to detect molecular, chemical and mineralogical changes in historic painting materials subjected to a thermal ageing test (< 250 °C). To simulate the heat-induced alterations an ageing accelerated process was performed on two sets of samples containing two mineral phases (hydroxyapatite and quartz) and two organic compounds (collagen and albumin). The chosen minerals behaved as internal standards during the tests since they are stable and chemically inert at the tested temperatures. Raman microscopy (RM) was applied to characterise one set of samples made of bone, containing ca. 70% hydroxyapatite and 30% collagen. Attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy was used to study the other set of samples made of four different quartz/albumin mixtures with quartz contents of 30%, 50%, 70% and 90% (w/w). The aim was to identify the ideal proportion of internal standard to be validated by ATR-FTIR and PCA, determined to be 70%. PCA analyses detected changes in the molecular structures of the organic components while the internal mineral standard remained stable. Moreover, the internal standard IR/Raman bands were constant during the tests and confirmed that the results of PCA analyses were independent of instrumental and technical factors, as well as sample collecting and handling. This demonstrates the potential benefits of our approach to study historical painting materials, which have suffered any type of heat-induced alteration.     

Toward a Longitudinal Model of e-Commerce: Environmental,Technological, and Organizational Drivers of B2C Adoption

Despite the important benefits for firms of commercial initiatives on the Internet, e-commerce is still an emerging distribution channel, even in developed countries. Thus, more needs to be known about the mechanisms affecting its development. A large number of works have studied firms' e-commerce adoption from technological, intraorganizational, institutional, or other specific perspectives, but there is a need for adequately tested integrative frameworks. Hence, this work proposes and tests a model of firms' business-to-consumer (called B2C) e-commerce adoption that is founded on a holistic vision of the phenomenon. With this integrative approach, the authors analyze the joint influence of environmental, technological, and organizational factors; moreover, they evaluate this effect over time. Using various representative Spanish data sets covering the period 1996–2005, the findings demonstrate the suitability of the holistic framework. Likewise, some lessons are learned from the analysis of the key building blocks. In particular, the current study provides evidence for the debate about the effect of competitive pressure, since the findings show that competitive pressure disincentivizes e-commerce adoption in the long term. The results also show that the development or enrichment of the consumers' consumption patterns, the technological readiness of the market forces, the firm's global scope, and its competences in innovation continuously favor e-commerce adoption.     

不同生态效度的呈现方式对专业乒乓球运动员知觉预测的影响

生态学效度是运动领域研究需要考虑的重要因素,实验旨在探讨虚拟全景呈现方式和单一屏幕呈现方式下乒乓球运动员对发球旋转的判断是否存在差异。研究选取9名上海体育学院乒乓球专项二级运动员为被试,在运动员判断发球旋转时记录下他们的反应时、正确率和事件相关联电位数据。结果表明,运动员的决策过程在不同呈现条件下存在差异,更具生态效度的呈现方式下反应时更长,且完成认知加工过程所需的潜伏期及振幅也存在差异。     

Spatial-temporal constraints on decision-making during shooting performance in the team sport of futsal

Abstract

In this paper we examined the influence of opposing players constraining the decision-making of an attacker during shooting performance in futsal. Performance during 10 competitive matches was recorded and examined from the moment a shot was taken until the ball was intercepted or entered the goal in sequences of play: ending in a goal, a goalkeeper's save, or an interception by the nearest defender. The variables under scrutiny in this study were (i) the distance of each player to the ball's trajectory, (ii) the time for the ball to arrive at that same point (i.e. the interception point), and (iii), the required movement velocity of the nearest defender and the goalkeeper to intercept the ball. Results showed that values of distance from a defender and goalkeeper to the interception points were significantly lower when they intercepted the ball. The time of ball arrival at the interception point of the defender was also lower when the ball was intercepted. The required velocities of the nearest outfield defender and the goalkeeper to intercept the ball were significantly lower during plays in which they intercepted the ball, than in plays in which the ball was not intercepted. Our results suggest that researchers and practitioners should consider simultaneously both space and time in analysis of interceptive actions in team sports. The required movement velocities of the opponents to intercept the ball are reliable spatial-temporal variables constraining decision-making during shooting performance in team sports like futsal.     

The effects of verbal encouragement and conscientiousness on maximal voluntary contraction of the triceps surae muscle in elite athletes

Abstract

We investigated the effect of verbal encouragement on maximal voluntary contraction (MVC) level of the triceps surae muscle group. Our secondary focus was to examine whether the effect of verbal encouragement on MVC level varies as a result of conscientiousness. While the participants performed plantar flexion, MVCs of the triceps surae muscle group were measured using rectified and smoothed surface electromyography (rsEMG) during the absence and presence of verbal encouragement. Participants completed questions from the Five Factor Personality Inventory concerning conscientiousness and were divided into high- and low-conscientiousness groups according to a median split. The sample included 30 female and 53 male elite athletes. In the entire cohort, there was no significant difference in MVCs with and without verbal encouragement. When the sample was partitioned by conscientiousness scores, verbal encouragement led to a significant increase in MVC in the low-conscientiousness group, whereas verbal encouragement led to a non-significant decrease in MVC in the high-conscientiousness group. Percentage change in MVC across experimental conditions was significantly different between the groups, with a 9.72% increase during verbal encouragement of the low-conscientiousness group, and a 2.47% decrease during verbal encouragement of the high-conscientiousness group.     

Ground Reaction Force Differences in the Countermovement Jump in Girls With Different Levels of Performance

Purpose: The aim of this study was to ascertain the biomechanical differences between better and poorer performers of the vertical jump in a homogeneous group of children. Method: Twenty-four girls were divided into low-scoring (LOW; M _age = 6.3 ± 0.8 years) and high-scoring (HIGH; M _age = 6.6 ± 0.8 years) groups based on their performance on the vertical jump. The force-, velocity-, displacement-, and rate of force development (RFD)-time curves of vertical jumps were analyzed to determine the differences between groups. Results: The analysis of the data showed differences in the pattern of the ensemble mean curves of the HIGH and LOW groups, although the majority of the differences occurred during the eccentric contraction phase of the jump. The differences in the HIGH group with respect to the LOW group were: lower force at the beginning of the movement, higher speed and RFD during the eccentric phase, high force at the beginning of the concentric phase, higher velocity during the concentric phase, and a higher position at takeoff. Conclusion: The results showed that the HIGH group achieved a higher jump height than did the LOW group by increasing the effectiveness of the countermovement and achieving a more advantageous position at takeoff.