What do plastics emit? HS-SPME-GC/MS analyses of new standard plastics and plastic objects in museum collections

In recent years, plastics are designated as a source of indoor pollution and particular attention has thus been devoted to the identification of emitting low molecular weight compounds. Headspace-solid phase microextraction-gas chromatography coupled with mass spectrometry (HS-SPME-GC/MS) has been already successfully applied for screening emissions from synthetic materials. This analytical tool being also non-invasive, it has been already successfully applied in the field of cultural heritage science for the identification of volatile organic compounds (VOCs) emitted from various museum objects made of natural materials. In this research, we aimed at assessing the use of HS-SPME-GC/MS as an in situ non-invasive analytical tool for a better knowledge of the volatile organic compounds emitted by plastics in collections. The possibility of characterizing plastics based on their emission signatures was also evaluated. Twelve new standard plastic samples, belonging to seven main polymer families widely present in museum collections as well as three naturally aged museum objects, were investigated. In this paper, we provide a survey of the VOCs emitted, and the use of HS-SPME-GC/MS for identifying volatile marker compounds, degradation products, additives, and monomer residues of the plastic synthesis is evaluated. More than 200 different VOCs were identified from the new standard samples. Two categories of VOCs were distinguished: “non-specific” and “specific” ones. We showed that based on the “specific” VOCs, it was possible to identify the nature of the polymeric matrix itself or at least to unambiguously distinguish a plastic by family. Emissions from the museum objects were then characterised, and main volatile degradation compounds considered as degradation markers of the natural deterioration of polymeric matrices, were identified. This identification procedure could be further exploited for the characterization of VOCs emitted by objects made of multiple synthetic polymers. Complementary to other techniques, this analytical tool is an interesting way to assess the risk for the objects stored in the vicinity of emitting plastics.     

Porosity and surface hardness as indicators of the state of conservation of Mudéjar plasterwork in the Real Alcázar in Seville

Plasterwork, a very typical element of Islamic art, comprises highly artistic decorative elements on wall, arches, and vaults. Due to their gypsum composition, such elements are easily weathered, primarily because of low mechanical strength and slight solubility in water. This work has studied the traditional Islamic plasterwork in the halls and patios of the Mudéjar Palace (13–16th centuries) in the Real Alcázar of Seville. This palace complex was declared a World Heritage Site by UNESCO in 1987. The analysis of its porosity and shore C surface hardness has allowed determination of the mathematical correlation between them. Consequently, future evaluations can merely measure the hardness (a non-destructive test) to estimate the plasterwork's porosity (which reveals its mechanical strength and its degree of weathering). These elements must be maintained in order to prevent the spread of pathologies. In addition to requiring an in-depth knowledge of its materials, application techniques, and properties, to do so also demands simple techniques for regular assessments and criteria to prioritize interventions if they become necessary.     

Traffic modeling for communications networks: A multifractal approach based on few parameters

In this work, in order to model network traffic processes, an efficient multifractal model is proposed based on fewer parameters than other models present in the literature, called 2PEMV. The 2PEMV model (2-Parameter Exponential Modeling for Multipliers’ Variance) is based on a multiplicative cascade in the wavelet domain capable of synthesizing communication network traffic traces which present characteristics such as self-similarity and wide Multifractal Spectrum Width (MSW). For such a purpose, in the 2PEMV model, the energy decay of the wavelet coefficients is captured by means of an exponential modeling for the multipliers’ variance along the cascade scales. The performance of the 2PEMV model to represent the network traffic characteristics is evaluated in comparison to other models present in the literature through simulations that are carried out using real communication network traffic traces.     

Monarchy,Socialism and Modern Capitalism: Hungary's Participation in Three London Olympic Games

Olympic sport is a double-edged sword. It has the potential to bring nations together and to transmit values, but it can also demonstrate international political tensions and conflicting national structural characteristics. As part of the International Olympic Movement from the very beginning, Hungary is one of the few nations to have taken part in the (Summer) Olympic Games in London for the third time. The Olympic presence of Hungary has been almost continuous in spite of the significant transformations of its state ideology, sport structures and political background. In 1908, within the framework of the Austro-Hungarian Monarchy, the Hungarian Kingdom endeavoured to demonstrate its autonomy and courage with its memorable Olympic successes in London. A People's Republic was being formed in Hungary at the time of the second London Olympic Games in 1948. The socialist ideology and the self-display of socialist–communist ambitions characterised the preparation and the participation of the Hungarian athletes. Hungary is celebrating the year of its third London Games with a democratic system in the background, built up from 1989, and a new Constitution adopted in 2011. Furthermore, the Hungarian Sport Act was renewed in 2012, due to which the Hungarian Olympic Committee has gained increased power, which might provide new ways of solving the financial problems within Hungarian elite sport.     

Spatial-temporal constraints on decision-making during shooting performance in the team sport of futsal

Abstract

In this paper we examined the influence of opposing players constraining the decision-making of an attacker during shooting performance in futsal. Performance during 10 competitive matches was recorded and examined from the moment a shot was taken until the ball was intercepted or entered the goal in sequences of play: ending in a goal, a goalkeeper's save, or an interception by the nearest defender. The variables under scrutiny in this study were (i) the distance of each player to the ball's trajectory, (ii) the time for the ball to arrive at that same point (i.e. the interception point), and (iii), the required movement velocity of the nearest defender and the goalkeeper to intercept the ball. Results showed that values of distance from a defender and goalkeeper to the interception points were significantly lower when they intercepted the ball. The time of ball arrival at the interception point of the defender was also lower when the ball was intercepted. The required velocities of the nearest outfield defender and the goalkeeper to intercept the ball were significantly lower during plays in which they intercepted the ball, than in plays in which the ball was not intercepted. Our results suggest that researchers and practitioners should consider simultaneously both space and time in analysis of interceptive actions in team sports. The required movement velocities of the opponents to intercept the ball are reliable spatial-temporal variables constraining decision-making during shooting performance in team sports like futsal.     

Modelling training response in elite female gymnasts and optimal strategies of overload training and taper

Abstract

The aim of the study is the modelling of training responses with a variable dose-response model in a sport discipline that requires highly complex coordination. We propose a method to optimise the training programme plan using the potential maximal performance gain associated with overload and tapering periods. Data from five female elite gymnasts were collected over a 3-month training period. The relationship between training amounts and performance was then assessed with a non-linear model. The optimal magnitude of training load reduction and its duration were investigated with and without an overload period using simulation procedures based on individual responses to training. The correlation between actual and modelled performances was significant (R ² = 0.81 ± 0.02, P < 0.01). The standard error was 2.7%. Simulations revealed that taper preceded by an overload period allows a higher performance to be achieved compared to an absence of overload period (106.3 ± 0.3% vs. 105.1 ± 0.3%). With respect to the pre-taper load, the model predicts that optimal load reductions during taper were 48.4 ± 0.7% and 42.5 ± 1.0% for overloading and non-overloading strategies, respectively. Moreover, optimal durations of the taper period were 34 ± 0.5 days and 22 ± 0.5 days for overloading and non-overloading strategies, respectively. In conclusion, the study showed that the variable dose-response model describes precisely the training response in gymnasts.     

Enzyme activity and myoglobin concentration in rat myocardium and skeletal muscles after passive intermittent simulated altitude exposure

Abstract

We studied the effect of intermittent hypobaric hypoxia exposure on lactate dehydrogenase and citrate synthase activities, together with myoglobin content, of rat myocardium, tibialis anterior, and diaphragm muscles. The intermittent hypoxia exposure programme consisted of daily 4-h sessions in a hypobaric chamber (5000 m) over a period of 22 days. Samples were taken at the end of the programme, and 20 and 40 days later, and compared with those of control animals. In myocardium, lactate dehydrogenase activity was significantly depressed in animals 20 days post-exposure (314.6 ± 15.3 IU · g^?1) compared with control animals (400 ± 14.3 IU · g^?1), while citrate synthase activity and myoglobin concentration showed a significant stepwise increase from control animals (88.2 ± 3.6 IU · g^?1 and 4.38 ± 0.13 μm · mg^?1) to animals 20 days (104.7 ± 3.7 IU · g^?1 and 5.01 ± 0.17 μm · mg^?1) and 40 days post-exposure (108.8 ± 6.5 IU · g^?1 and 5.11 ± 0.22 μm · mg^?1). In contrast, no differences were found in diaphragm and tibialis anterior muscles. Our results show that intermittent hypobaric hypoxia exposure increased the oxidative character of myocardium even 20 days after the hypoxic stimulus has ceased, and that this effect lasts for more than 40 days for citrate synthase activity and myoglobin concentration. These findings support our previous results on skeletal and cardiac muscle capillarization after passive intermittent simulated altitude exposure, thus providing morphofunctional and biochemical evidence for increased cardiac aerobic efficiency.     

Characteristics of extracurricular physical activity and cognitive performance in adolescents. The AVENA study

Abstract

The aim of this report was to examine the associations between some characteristics (i.e., structure and number) of extracurricular physical activity (EPA) and cognitive performance in adolescents. A total of 1662 adolescents (880 girls; 13.0–18.5 years) from 5 Spanish cities (Granada, Madrid, Murcia, Santander and Zaragoza) were included in this study. Structure (organised and non-organised) and number of EPAs, and participation at vigorous intensity during EPA were self-reported. Cognitive performance (verbal, numeric and reasoning abilities, and an overall score) was measured with the “SRA-Test of Educational Ability”. Results showed that vigorous EPA was positively associated with all cognitive variables. Adolescents who practiced an organised EPA had higher scores in 3 of the 4 cognitive variables than those who practiced a non-organised EPA (all P < 0.05). Likewise, the group who participated in more than one EPA had higher cognitive performance in all variables than the group who participated in only one EPA (all P < 0.05). Regardless of potential confounder variables, including vigorous EPA, both structure and number of EPAs were each other independently associated with cognitive performance. Therefore, structure and number of EPAs may positively influence cognitive performance in adolescents. Participating in multiple, organised EPA may have benefits for cognitive performance.