Non-structural injection grouts with reduced water content: Changes induced by the partial substitution of water with alcohol

Conventional grouting – used to stabilise delaminated plaster – typically involves the use of water as suspension medium. Water can be dangerous when water-sensitive original materials are present and can cause the solubilisation of salts, leading to their re-crystallisation on drying. Ethyl alcohol is a less effective solvent for soluble salts and generally does not affect the original materials. This is the reason why it was used as a partial substitute for water in grout preparations in the present research. Three water–ethyl alcohol-based grouts were compared with the correspondent water-based grout. The working properties and performance characteristics of the injection grouts with reduced water content were measured to assess their suitability for use on historic plasters.     

Individual differences in memory updating in relation to arithmetic problem solving

The study investigates the relationship between memory updating and arithmetic word problem solving. Two groups of 35 fourth graders with high and low memory-updating abilities were selected from a sample of 89 children on the basis of an updating task used by Palladino et al. [Memory & Cognition 29 (2002) 344]. The two groups were required to solve a set of arithmetic word problems and to recall relevant information from another set of problems. Several span tasks, a computation test, and the PMA verbal subtest were also administered. The group with a high memory-updating ability performed better in problem solving, recalling text problems, and in the computation test. The two groups did not differ in the PMA verbal subtest or in the digit and word spans. Results were interpreted as supporting the importance of updating ability in problem solving and of the substantial independence between memory updating and problem solving on one hand and verbal intelligence on the other.     

Development and validation of the Dynamic Career Scale (DCS): a psychodynamic conceptualization of career adjustment

International Journal for Educational and Vocational Guidance - The purpose of this research was to develop and validate a new instrument, the Dynamic Career Scale (DCS), which measures four...     

Risk Assessment and Preservative Measures for Volatile Organic Compounds in Museum Showcases

ABSTRACT

The first step in preservative measures for artworks in airtight showcases is the exclusion of outgassing from construction materials or, at least, limitation of the emissions to a minimum acceptable level if the volatile organic compounds (VOCs) generated may be qualified as harmless. Once it is ascertained that the objects in the showcases are responsible for VOC emissions, a step forward becomes necessary, implying showcase ventilation with air flowing through active sorbent materials. Solid phase micro-extraction (SPME) followed by GC separation and MS identification has been applied for checking the outgassing characteristics of different types of materials used for the construction of airtight showcases, and the method was found particularly attractive in terms of speed and sensitivity, suitable for measurements in presence of low-emitting materials. Sampling could also be done in the case interiors, thus making possible detection and recognition of emissions from art objects within a case. A comprehensive preventive conservation scheme has been further devised by means of active air circulation within the showcase and functional sorbent materials along the flow, for complete suppression of gaseous compounds. Control of the compounds in the air flow and of their filtration efficacy was achieved by direct sampling, also using SPME fibers. Continuous monitoring of the air quality in the showcases has been developed with insertion of a photoionization detector capable of detecting the VOCs in the air by inducing molecular ionization, and measuring the generated photocurrent. The system is not selective, but gives the total concentration, reaching ppb sensitivity with high-quality data. In addition it includes temperature and humidity sensors, making the whole a useful instrument for environment control.     

Biomechanical determinants of cross-country skiing performance: A systematic review

ABSTRACT

Cross-country skiing is a complex endurance sport requiring technical skills, in addition to considerable physiological and tactical abilities. This review aims to identify biomechanical factors that influence the performance of cross-country skiers. Four electronic databases were searched systematically for original articles in peer-reviewed journals addressing the relationship between biomechanical factors (including kinematics, kinetics, and muscle activation) and performance while skiing on snow or roller skiing. Of the 46 articles included, 22 focused exclusively on the classical technique, 18 on the skating technique, and six on both. The indicators of performance were: results from actual or simulated races (9 articles); speed on specific tracts (6 articles); maximal or peak speed (11 articles); skiing economy or efficiency (11 articles); and grouping on the basis of performance or level of skill (12 articles). The main findings were that i) cycle length, most often considered as a major determinant of skiing speed, is also related to skiing economy and level of performance; ii) higher cycle rate related with maximal speed capacity, while self-selected cycle rate improves skiing economy at sub-maximal speeds; iii) cross-country skiing performance appears to be improved by joint, whole-body, ski, and pole kinematics that promote forward propulsion while minimizing unnecessary movement.     

Selective spatial working memory impairment in a group of children with mathematics learning disabilities and poor problem-solving skills

This study examines visual and spatial working memory skills in 35 third to fifth graders with both mathematics learning disabilities (MLD) and poor problem-solving skills and 35 of their peers with typical development (TD) on tasks involving both low and high attentional control. Results revealed that children with MLD, relative to TD children, failed spatial working memory tasks that had either low or high attentional demands but did not fail the visual tasks. In addition, children with MLD made more intrusion errors in the spatial working memory tasks requiring high attentional control than did their TD peers. Finally, as a post hoc analysis the sample of MLD was divided in two: children with severe MLD and children with low mathematical achievement. Results showed that only children with severe MLD failed in spatial working memory (WM) tasks if compared with children with low mathematical achievement and TD. The findings are discussed on the basis of their theoretical and clinical implications, in particular considering that children with MLD can benefit from spatial WM processes to solve arithmetic word problems, which involves the ability to both maintain and manipulate relevant information.