Effect of the addition of hydroxyl-terminated polydimethylsiloxane to TEOS-based stone consolidants

Hybrid stone consolidants prepared from tetraethoxysilane (TEOS) and α,ω-hydroxyl-terminated polydimethylsiloxane (PDMS-OH) have been considered as one of the most promising approaches to improve the effectiveness of traditional alkoxysilane-based formulations. They have emerged as response to the negative reports commonly found in the literature: the resulting silica gel phase (SiO₂) tends to develop fractures and fissures inside the stone as the gel shrinks during the drying stage. In this work, we employed SEM, solid-state ²⁹Si NMR spectroscopy and compressive tests to characterize SiO₂-PDMS hybrid gels. We report the morphological characteristics exhibited by gels prepared in vitro and in situ. It was found an appreciable reduction of gel fracture for hybrids prepared from 5% w/w of PDMS. As TEOS polycondenses, PDMS-OH is chemically incorporated into the gel matrix via Si-O-Si bonds. The inclusion of these elastic chains provides the necessary flexibility to resist the stress imposed by capillary pressure. Additionally, an important hydrophobic character is imparted to the stone.     

Tunable visual color filter using microfluidic grating

This paper reports a tunable visual color filter based on a microfluidic transmission grating. The grating lines are formed by the microflows in an array of evenly spaced straight microchannels. In experimental study, the transmission of white light measures a shift of visual color from red to blue in the zeroth order diffraction in response to a change of the refractive index from 1.3290 to 1.3782 in the microflows. The merit of large tunability of transmission peak (Δλ=408 nm) makes this grating potential for various applications in biological and chemical measurements, such as space- and time-resolving micropattern spectrophotometers and separation of the fluorescence from the excitation.     

The hybrid librarian: the affinity of collection management with technical services and the organizational benefits of an individualized assignment

Collection management and technical services have a natural affinity that is not reflected in the organization of many academic libraries, where subject librarians are often aligned with reference. This article examines organizational and individual approaches to librarian assignment, along with the place of collection management in the organization.     

Les six étapes de l'apprentissage des structures

Sans résuméPublié, avec illustrations, sous forme d'un petit livre, par O.C.D.L., Paris.