Phase Transformations of Graphite and Carbon Black by Laser with Low Power Density

The structure phase transformations of graphite and carbon black induced by pulsed laser were studied in this paper.Under irradiation with laser beam of 1.06 μm wavelength and power density of 106 W·cm-2,both graphite structure and carbon black structure were changed obviously.The results of Raman analyses and Transmission Electron Microscopy(TEM)observations show that graphite transforms into nanodiamond about 5 nm and carbon black is graphitized.It is demonstrated that graphite is the intermediate phase in the transformation from carbon black to diamond,and graphite is easier to transform into diamond by laser irradiation than carbon black.     

加强过程管理提高硕博连读研究生创新能力的培养

硕博连读培养方式是研究生教育中一种较新的博士生培养方式,其培养过程和其他博士生培养方式有共同之处,但也有独特的特点。笔者通过分析硕博连读培养方式的特殊意义,探究目前我国硕博连读研究生培养管理过程中存在的问题,提出加强过程管理、提高硕博连读研究生创新能力培养的若干对策。     

医学院校教改课题成果推广应用的现状调查与管理对策研究

为了解教改课题成果推广的现状,对广西医科大学相关教学管理人员及教师进行访谈和问卷调查。结果显示教改课题研究内容脱离教学实际需要、不懂相关推广渠道、无相应经费支持等严重制约了成果的推广。为此,提出对教改立项课题研究进行全过程管理、加强成果推广应用的指导和宣传、健全完善教改课题相关管理制度等对策。     

本体性游戏与幼儿元认知发展的研究

元认知在个体的发展中起着重要的作用。在不同的个体身上,元认知有成熟与次成熟之别,整体与局部之分。幼儿具有局部的次成熟的元认知。在本体性游戏的影响下,幼儿的元认知将获得较快的发展。     

关于做好网络化教学准备工作的探索

本文就网络教学指导思想、教学内容组织原则、网络课件制作等教学准备过程中的问题提出了自己的意见和看法。     

动态膜压仪在有序分子薄膜体系研究中的应用

应用动态膜压仪测定单分子膜在亚相上的表面压π,表面张力γ以及膜的崩溃压。研究两亲分子在亚相上铺展成膜的状态及其规律,为有序单分子薄膜的制备及成膜过程的研究提供了依据。     

磺基水杨酸铜络离子稳定常数的测定

本文采用pH电位滴定法测定磺基水杨酸铜络离子的稳定常数,得到了比较准确的结果(与文献值比较)。该法适用于弱酸根离子或弱碱分子作配位体的单核络合物稳定常数的测定。     

Visual Foxpro6.0任意打印报表的实现

报表输出的灵活性是visual Foxpro的弱点,本文通过对报表格式文件的分析,用两个需要灵活报表输出的实例及最后的编译方式,提出了解决报表输出灵活性的一种方法.     

Tandem Biocatalysis by CotA-TJ102@UIO-66-NH2 and Novozym 435 for Highly Selective Transformation of HMF into FDCA

2,5-Furandicarboxylic acid(FDCA) is a potential biorenewable chemical for applications including plastics, polyamides, drugs, etc. The selective biosynthesis of FDCA from 5-hydroxymethylfurfural(HMF) by a specific enzyme poses a great challenge. In this study, we reported an efficient strategy to produce FDCA from HMF by the tandem biocatalysis of laccase(Cot A-TJ102@UIO-66-NH_2) and Novozym 435. For the first step, a nanoparticle metal–organic framework was synthesized as a carrier to immobilize Cot A-TJ102@UIO-66-NH_2, which was assigned for the production of 5-formyl-2-furancarboxylic acid(FFCA) and featured an enzyme loading of 255.54 mg/g, specific activity of 135.90 U/mg, and solid loading ratio of 99.65%. Under optimal conditions, an ideal FFCA yield of 98.5% was achieved, and the Cot A-TJ102@UIO-66-NH_2 presented a high recycling capacity after 10 cycles. For the second step, Novozym 435 was applied for the further conversion of FFCA into FDCA, presenting a high FDCA yield of 95.5% under the optimized conditions. Novozym 435 also exhibited a high recyclability after eight cycles. As a result, the tandem biocatalysis strategy provided a 94.2% FDCA yield from HMF, indicating its excellence as a method for FDCA production.