Secondary electron emission from oxide-coated cathodes

The secondary electron emission from alkaline-earth oxide-coated cathodes has been investigated under both continuous and pulsed bombardment. Various factors affecting the yield, such as dependence upon primary voltage, collecting voltage, temperature, time, and angle of incidence, are noted, and the present state of the theory is discussed.Experiments have been performed with three types of apparatus. Yield vs. Energy data reveal values of δ of 4–7 at room temperature, with a more or less flat maximum at approximately 1,000 volts primary energy.The yield increases with temperature in an exponential manner, and plots of log Δδ (i.e. δ_K° ? δ_300°K) vs. 1/T give straight lines. Values of Q₁ between 0.9 – 1.5 eV. are generally indicated, and from extrapolation of these curves, yields exceeding 100 at 850° C. are deduced. The secondary emission depends upon the degree of activation, and increases with enhancement of the thermionic emission characteristics. Short-time effects such as growth or decay of secondary current after the onset of primary bombardment or persistence after the cessation of bombardment have not been observed, and values of yield obtained by pulsed methods are in accord with those obtained under D.C. conditions. Tail phenomena reported by J. B. Johnson and interpreted as “enhanced thermionic emission” from oxidecoated cathodes become manifest only under experimental conditions characterized by certain space-charge effects, and have been effectively simulated by bombarding a tantalum target adjacent to an electron-emitting tungsten filament. Various measurements of the energy distribution of secondary electrons as a function of primary voltage and temperature have been obtained. It was observed that the average energy of the secondary electrons decreases with temperature at a rate which more than compensates for the increase in the number of secondaries emitted per incident primary. The mechanism of the observed dependence of yield upon temperature is not well understood. Various alternative explanations are discussed and, in the light of the present state of our knowledge, regarded as untenable.     

The relay oscillator and related devices

Several arrangements of relay, condenser, and battery can be made to oscillate dependably. The electrical properties of these oscillators, as well as of a number of derivative devices, are here outlined.     

The elimination of hypo from photographic images

It is very difficult, if not impossible, to remove the last traces of hypo from photographic papers by any known procedure of washing. The sulfur in the residual hypo ultimately, and especially under abnormal conditions of temperature and humidity, combines with the silver image to form yellowish brown silver sulfide. This phenomenon is known as sulfiding or “fading” of the image. The various factors which affect the rate of fading of images and the washing out of hypo from films and papers are outlined.Chemical methods of hypo elimination have been proposed from time to time but the majority of these have not been satisfactory because they tend to leave substances such as thionates in the photographic material, which are equally as difficult to wash out as hypo and which also tend to sulfide or fade the silver image. A new hypo eliminator is recommended consisting of two volatile chemicals, hydrogen peroxide and ammonia. This eliminator oxidizes the hypo to sodium sulfate, which is inert and soluble in water, while any excess eliminator evaporates on drying.Two formulas and treatments are proposed: (1) Complete elimination of hypo for use by the professional, advanced amateur, and photofinisher who demand the highest standard of photographic quality in their prints.(2) Almost complete elimination of hypo (less than o.oi milligram per square inch).Since the conditions to which prints will be subjected are rarely known in advance, use of the “complete elimination treatment” is advised in all cases.