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21.
Laser cleaning has been used to restore the soiled terracotta statues and decorations of the tympanum of the portal of Palos of the Cathedral of Seville in Spain. A simultaneous laboratory study performed on a representative sample helped to identify the optimum laser conditions to remove the dark soiling layer produced by air pollution. It was found that irradiation at 1064 nm with a Q-switched Nd:YAG laser was more effective than the harmonic wavelengths of 532 or 266 nm. LIBS and Raman microscopy gave information on the composition of terracotta and identified the presence of a protective layer made of gypsum and calcite. As detected by Raman spectroscopy, laser irradiation caused the elimination of the carbon component of the soiling layer and the appearance of an anhydrite component in the laser irradiated gypsum layer applied over the terracotta substrate for protective purposes. Local heating of the surface caused by laser irradiation at 1064 nm, the laser wavelength used for restoration of the portal, might be responsible for a process of partial dehydration of gypsum into anhydrite.  相似文献   
22.
The objective assessment of the prestige of an academic institution is a difficult and hotly debated task. In the last few years, different types of university rankings have been proposed to quantify it, yet the debate on what rankings are exactly measuring is enduring.To address the issue we have measured a quantitative and reliable proxy of the academic reputation of a given institution and compared our findings with well-established impact indicators and academic rankings. Specifically, we study citation patterns among universities in five different Web of Science Subject Categories and use the PageRank algorithm on the five resulting citation networks. The rationale behind our work is that scientific citations are driven by the reputation of the reference so that the PageRank algorithm is expected to yield a rank which reflects the reputation of an academic institution in a specific field. Given the volume of the data analysed, our findings are statistically sound and less prone to bias, than, for instance, ad–hoc surveys often employed by ranking bodies in order to attain similar outcomes. The approach proposed in our paper may contribute to enhance ranking methodologies, by reconciling the qualitative evaluation of academic prestige with its quantitative measurements via publication impact.  相似文献   
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