Cyclic-anion salt for high-voltage stable potassium-metal batteries

Electrolyte anions are critical for achieving high-voltage stable potassium-metal batteries (PMBs). However, the common anions cannot simultaneously prevent the formation of ‘dead K’ and the corrosion of Al current collector, resulting in poor cycling stability. Here, we demonstrate cyclic anion of hexafluoropropane-1,3-disulfonimide-based electrolytes that can mitigate the ‘dead K’ and remarkably enhance the high-voltage stability of PMBs. Particularly, even using low salt concentration (0.8 M) and additive-free carbonate-based electrolytes, the PMBs with a high-voltage polyanion cathode (4.4 V) also exhibit excellent cycling stability of 200 cycles with a good capacity retention of 83%. This noticeable electrochemical performance is due to the highly efficient passivation ability of the cyclic anions on both anode and cathode surfaces. This cyclic-anion-based electrolyte design strategy is also suitable for lithium and sodium-metal battery technologies.     

基于专利数据的技术融合研究综述

[目的/意义]基于专利数据开展技术融合研究是技术融合研究的主要方式和热点方向,面向为技术融合后续研究工作开展提供参考和启发的目标,对国内外基于专利数据的技术融合研究现状进行较为全面的综述.[方法/过程]将已有研究按研究内容划分为技术融合测度及预测方法研究、特定领域/多领域间/全领域的技术融合态势测度及趋势预测、技术融合...