Diversified production of red figured pottery in Apulia (Southern Italy) in the late period

Late Apulian red figured pottery [1] from Egnatia (Fasano, Brindisi, Italy) was studied in order to widen the view on this ceramic class in Southern Italy. Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) provided the samples elemental composition that allowed to make provenance hypotheses. Optical Microscopy (OM) and Scanning Electron Microscopy (SEM) with Energy Dispersive Spectrometry (EDS), supplied information about the minero-petrographic features of the objects to better understand their production technology. The set of results highlighted the contemporary presence in the Apulian land in the late 4th century BC of both local and imported finds and showed the existence of two different kinds of local production, the “classic” Attic and a peculiar one, characterized by the application of an engobe layer before the black gloss. Our previous studies resulted in the discovery that an engobe layer, with similar chemical and minero-petrographic characteristics, was present in finds from another site in central Apulia (Monte Sannace). So the discovery of red engobe on fragments from Egnatia, proves that its use was not an isolated occurrence, but was quite common in the production of red figured in Apulia during the Late period, appearing as a peculiar technological mark of Apulian potters.     

Electricity (de)regulation and innovation

In this paper we study the effect of deregulation on innovation in the electricity sector using a sample of 31 OECD countries. Exploiting sharp reductions in the level of product market regulation, explicitly linked to changes in the legal framework, we perform a difference-in-difference analysis by matching data retrieved from the OECD International Regulation, OECD Patent Grants, and UN World Development Indicators databases. Our main findings suggest that a decrease in regulation intensity, following a significant reform, has a negative impact on patents (granted by the European Patent Office). This impact appears to be mainly due to the degree of market contestability. Finally, we find evidence of an inverted U-shaped relationship between regulation and innovation. This may imply that the effect of deregulation on innovation depends on the strength of the deregulatory process.     

Recent advances in swollen-state NMR spectroscopy for the study of drying oils

The cross-linking processes of three drying oils (poppy, linseed, walnut), a class of organic compounds very important in the field of artworks, were studied by means of ¹H-NMR spectroscopy, following the change of the protons signals when oils are heated at 60 °C in the presence of air or nitrogen gas. This preliminary information is particularly important to identify the presence of drying oils within a solid painting film. We demonstrated that it was possible to study these films by swollen-state NMR, an innovative spectroscopy method that can directly analyze very small semisolid samples instead of solutions. The main advantages of this method are the short time of analysis, the possibility to analyze samples without any preliminary treatment, and the small quantity of the sample required. Therefore, swollen-state NMR technique was used to characterize three real painting films: in this way, we succeeded in recognizing in real paintings specimens the presence of drying oils employed as binders, avoiding any interferences due to other organic compounds acting as binding agents, like waxes or egg-yolk media.     

Organizing the ‘productive transformation of knowledge’: linking university and industry in traditional manufacturing areas

The article aims at underlining the role played by extra-academic and autonomous organizations strongly connected with university institutions and researchers in producing, acquiring, transferring and transforming knowledge. The study examines a particular Italian case, the Politecnico Calzaturiero, a private institution providing technical training and research services operating in North-eastern Italy. The analysis of this experience suggests that, in traditional manufacturing areas, organizations playing a key role in managing the ‘productive transformation of knowledge’ may be neither universities nor firms. ‘Special organizations’, like the one discussed in this article, are deeply embedded in their economic and institutional environment, are closely interconnected within a dense and extended network of various actors, engage in complex and time-consuming processes, and can be understood as organizational relé, that is entities which are able to connect structures that are usually not connected. For these reasons, they represent an underestimated resource for universities’ third mission and its management.     

Viscoelastic and mechano-sorptive studies applied to the conservation of historical violins: A case study of the Guarneri “del Gesù” violin (1743) known as the “Cannone”

To assess the possible effects of mechanical loading on the conservation of historical wooden musical instruments, a research project was carried out on the violin Guarneri “del Gesù” (1743), known as the “Cannone”. This paper refers to the results obtained by studying the deformations to which a violin is subjected after being tuned, with special attention to the viscous and mechano-sorptive behaviour (as in a concert environment for example). The amount of viscoelastic creep was quantified under normal tuning conditions, and the mechano-sorptive creep was quantified using a dead mass resulting in 55% of the elastic deformation obtained after tuning. The viscoelastic and mechano-sorptive deformations were clearly observed. These deformations were completely recovered once the violin was unloaded, demonstrating that this violin structure is appropriately dimensioned for the applied stresses.     

Photoluminescence of the inorganic pigments Egyptian blue, Han blue and Han purple

The room-temperature photoluminescence spectra of various samples of Egyptian blue (CaCuSi₄O₁₀) are presented, discussed and compared with those of recently synthesized compounds corresponding to the ancient pigments Han blue (BaCuSi₄O₁₀) and Han purple (BaCuSi₂O₆). All the samples of Egyptian blue show identical spectra, in spite of their very different origin. The spectra of Han blue and Han purple are significantly different. Since the Cu²⁺ ion may be considered the only luminescent centre in the spectral range under investigation, the differences between the spectra of the various pigments are ascribed to a ligand-field change. This can be related to the larger size of the Ba²⁺ ion with respect to Ca²⁺. The use of PL spectra for the identification of these pigments in works of art is proposed.