Organic-inorganic material for the consolidation of plaster

Organic-inorganic materials to be used as hydrophobic consolidants for plasters were synthesized starting from an inorganic precursor (Tetraethoxysilane [TEOS]), added to a polysiloxane epoxy formulation and thermally cured with Ytterbium as acid catalyst. The TEOS reduces the viscosity of the resin, contributing to the mechanical properties of the film, without causing cracking. Solvents, that are harmful for workers and environment and show some drawbacks in the practice of restoration, were not used. The film properties and the formation of silica clusters were investigated. The products were applied by brush on plaster's samples and their compatibility and effectiveness were verified. Thanks to the organic content, the products penetrate deeply, are more stable to photo-oxidative degradation, and the hydrophobicity of the resin, provided by the silicone component, is not altered.     

Noninvasive physicochemical characterization of two 19th century English ferrotypes

The present work was one of the first attempts to analyze the conservation status of two ferrotypes, ancient photographic plates realized on a support made of iron. The photographic material was constituted of collodion as binder for the photosensitive silver halides grains. The two ferrotypes studied belonged to a private collection of a family from Durham, UK, and were made at the end of the 19th century. The analytical techniques used for the morphological and physicochemical characterization were noninvasive. The surface morphology was studied by means of optical microscopy (OM) and environmental scanning electron microscopy (ESEM) coupled with an energy dispersive X-rays (EDX) system for the elemental analysis. These techniques, together with microreflectance Fourier transform infrared spectroscopy (μ-FTIR) and contact angle, allowed to obtain information on both the chemical – elemental – composition of the materials constituting the ferrotypes, and the conservation status of these photographic plates. The study showed that the physicochemical diagnostics allowed to characterize the two ferrotypes that, despite their similar age and provenance, showed different conservation status, surface properties, and elemental composition.     

Maturity status effects on torque and muscle architecture of young soccer players

ABSTRACT

This study investigated the effects of maturity status on knee extensor torque and vastus lateralis architecture of young soccer players. Thirty-four males aged 13–18 years were divided into two groups: pubescent (PUB, n = 15) and postpubescent (POSP, n = 19). Torque by angle interaction was established for absolute [F(2.649, 84.771) = 9.066, p < 0.05] and relative to body mass [F(2.704, 86.533) = 4.050, p < 0.05] isometric torque with the POSP group showing greater values. Muscle volume torque-angle relationship was similar between groups. Absolute, relative to body mass, and relative to muscle volume concentric and eccentric torque-velocity relationship showed a non-significant interaction but a significant group effect in favour the POSP group for absolute and concentric torque relative to body mass. Torque-angle and torque-velocity relationship normalized by body mass allometric exponents showed a non-significant interactions and group effects. Muscle thickness (3.6 ± 0.6 vs. 3.8 ± 0.6 cm), fascicle length (8.3 ± 1.4 vs. 8.9 ± 1.6 cm) and pennation angle (15.0 ± 2.3 vs. 14.3 ± 3.2 degrees) was similar between PUB and POSP groups, respectively. Maturity status did not show a significant effect on muscle architecture and on isometric and dynamic torques when allometrically normalized.     

One ultramarathon,two cities: differences in social impact perceptions

ABSTRACT

To ensure the positive sentiment of residents towards sporting events, it is important to understand and manage the social impact perceptions generated by such events at the host destinations. The Comrades ultramarathon is a unique event which affects the residents of two cities at the same time, meaning that diversified social impact management approaches may be needed. The research revealed apparent differences in social impact perceptions among the two cities. Despite the Comrades, as it is colloquially termed, being a single event, diversified management approaches are therefore needed. This study furthermore reveals that the size and diversity of communities’ economies might influence residents’ social impact perceptions.     

Indirect estimation of injected mortar volume in historical walls using the electrical resistivity tomography

The electrical resistivity tomography (ERT) represents one of the widely used geophysical techniques for the exploration of the subsurface. In the last few years, this method has been demonstrated to be an efficient reconnaissance tool not only for monitoring degradation status of walls and foundations of historical buildings, but also for imaging the spatial distribution of injected mortar, commonly employed for consolidation purposes. A 3D resistivity tomography survey was carried out on four selected wall portions of the historical church of Montepetriolo, Perugia, Central Italy. The obtained 3D resistivity distribution models before and after grouting provided suggestive images of the internal structure of the studied walls. Moreover, the spatial distribution of the zones being filled with mortar was determined quantitatively by scaling the post- to the preinjection resistivity values. Using a well known correlation between resistivity and porosity, established in the geophysical community, a further step towards a more quantitative assessment was attempted to indirectly determine the unit volumes of the injected mortar The obtained results were satisfactory and in some cases almost similar to the yard data. Furthermore, two flat-jack tests confirmed the local increment of the mechanical resistance of the studied left front (2) and right lateral (3) wall portions.     

An advanced church heating system favourable to artworks: A contribution to European standardisation

The European project Friendly-Heating (FH): comfortable to people and compatible with conservation of artworks preserved in churches addressed the problems caused by the continuous or intermittent heating of historic churches, which disturbs the microclimatic conditions to which the building and the artworks preserved inside have acclimatised. As thermal comfort and the preservation of artworks often conflict with each other, a balance between the two needs is necessary. The proposed heating strategy is to provide a small amount of heat directly to people in the pew area while leaving the conditions in the church, as a whole, undisturbed. This novel heating system is based on some low-temperature radiant emitters mounted in a pew to provide a desirable distribution of heat to the feet, legs and hands of people occupying it. Due to little heat dispersion, this novel system not only significantly reduces the risk of mechanical stress in wooden artworks and panel or canvas paintings, fresco soiling and cyclic dissolution-recrystallization of soluble salts in the masonry, but is energy-efficient. The detailed environmental monitoring was conducted in the church of Santa Maria Maddalena in Rocca Pietore, Italy over a 3-year period to verify the performance of the novel heating system in comparison to the warm-air system that was active earlier in the church. The methodology and results of this comprehensive and multidisciplinary study were included in three draft standards of the European Committee for Standardisation intended for use in the study and control of environments of cultural heritage objects.     

Mechanical properties of adobe walls in a Roman Republican domus at Suasa

Adobe is a construction technique that uses raw earth mixed and moulded to form sun-dried blocks to realize a bearing wall. The recent discovery of adobe walls belonging to a Republican domus sited in Suasa (Ancona, Italy) was the starting point of the present work. The research was developed through an experimental approach, in order to characterize the mechanical behavior of this type of walls: firstly some adobe blocks similar to the original ones were reproduced by using the soil directly came from the archaeological site near the adobe walls and adding straw to reduce hygrometric shrinkage and coarse sand, taken from a local quarry, as a stabilizer, as Romans were used to do. Then, after a seasoning period of 4 months, four adobe walls were produced to be tested by compression and shear. From compression tests, maximum strength, first cracking compression stress, Young modulus and breaking manner were evaluated. As well, compression results show a possible two-storey structure of the earthen Republican domus. In fact, it appears that the stress from the two-storey load analysis is lower than the first cracking compression stress. From the shear tests, a proportional law seems to regulate the relation between the maximum value of the mean tangential tensions and the vertical compression the sample is subjected to. This could be the starting point for a future seismic analysis.