Fact and fantasy in chemical analysis

Chemical analysis is now so precise and sophisticated a science that it is difficult to appreciate that scarcely a century ago its deficiencies were a cause for public scandal. This article reviews some of the main causes for complaint and how they were remedied.     

Structural aspects of controllability and observability—I. tensorial aggregation

The classical criteria for controllability and observability are given a tensorial formulation which is then extended into Boolean form directly related to a digraph interpretation of system structure. This is examined in detail with particular reference to group theoretic aspects, invariant properties under transformation, the term rank test and the existence of zero eigenvalues.Within this framework the structural design concepts of potential controllability and observability are presented in generalised terms.     

Structural aspects of controllability and Sobservability—II. digraph decomposition

The graph theoretic aspects of controllability and observability are examined and related to the tensorial formulation of Part I of the paper. Particular emphasis is given to the significance of the system digraph decomposition and the relevance of this to certain system algebraic properties of interest in control theory.     

Essential gyrators and reciprocity in junction structures

This paper proposes an extended definition of reciprocity for a multiport junction structure based on the concept of essential gyrator coupling. Two theorems are given for junction structures containing gyrators and an algorithm is presented for identifying essential gyrators. The results are useful both theoretically and for designing efficient computation procedures for junction structures.     

Three-axis platform simulation: Bond graph and Lagrangian approach

A bond graph model is derived for the geometric constraints of a three-axis flight table. Gimbal dynamics are easily added even in asymmetrical and unbalanced cases. A method is introduced to make the local dependent inertias computable. The bond graph compares favourably to the Lagrangian approach as to modelling effort and accessibility of intermediate variables as well as having computational advantages.     

The graph-theoretic field model—I. Modelling and formulations

The Graph-Theoretical Field Model provides a unifying approach for developing numerical models of field and continuum problems. The methodology examines the field problem from the first stages of conceptualization without recourse to the governing differential equations of the field problem; this is accomplished by deriving discrete statements of the physical laws which govern the field behaviour. There are generally three laws, and these are modelled by the “cutset equations”, the “circuit equations”, and the “terminal equations”. In order to establish these three sets of equations it is expedient first to spatially discretize the field in a manner similar to the finite difference method and then to associate a linear graph (denoted as the field graph) with the spatial discretization. The concept of “through” and “across” variables, which underlies the cutset and circuit equations respectively, enables one to define the graph in an unambiguous manner such that each “edge” of the graph identifies a pair of complementary variables. From a knowledge of the constitutive properties and the boundary conditions of the field it is possible to associate terminal equations with sets of edges. Since the resulting sets of equations represent the field equations, these equations provide the basis for a complete (but approximate) solution to the field or continuum problem. In fact, this system approach uses a two part model: one for the components and another for the interconnection pattern of the components which renders the formulation procedures totally independent of the solution procedure.This paper presents the theoretical basis of the model and several graph-theoretic formulations for steady-state problems. Examples from heat conduction and small- deformation elasticity are included.     

Ladder realizations of multivariable positive real functions

Necessary and sufficient conditions are obtained for the realization of an m-variable positive real function (PRF) as the impedence function of a resistively-terminated ladder network of m lossless two-ports connected in cascade. Each two-port is a single-variable lossless ladder with all of its transmission zeros either at the origin or at finity. Conditions are also obtained when each of the two-ports is a Fujisawa-type lowpass ladder.     

An analysis of the role of users in the total r&d portfolios of scientific instrument firms

This paper describes a real-time investigation of the total new product portfolios of nine product departments in the scientific instrument industry. It was found that within these portfolios only a few new products represented a major advance in functional performance. Most new products offered only incremental performance improvement, and many ‘new’ products were direct copies of competitors ' offerings.The scientific instrument innovation process is described in seven stages: recognition of need, invention of solution, prototype development, use in application, precommercial information dissemination, product engineering, and commercialization. In those cases where users were involved in the majority of the first five stages of the innovation process, the innovation was either a major functional improvement or a minor improvement that had not been initiated as a direct response to a competitor's product introduction. Direct copies and minor improvements that were competitive responses are notable for the absence of user involvement in the innovation process.Finally, the decision of a manufacturer to commercialize an innovation was unrelated to the level of user activity in the prior stages of the innovation process.     

Polynomial Root Clustering

A sequence of tests on derived polynomials to be strictly Hurwitz polynomials is shown to be equivalent to a given (typically real) polynomial having all its zeros in an open sector, symmetric with respect to the real axis, in the left half-plane. The number of tests needed is at most 1 + ?(ln k)/(ln 3)?, where k is the integer associated with the central angle π/k of the sector. An extension of this result on the sector as a region of root clustering is given which shows that only a limited number of tests are needed to verify that the roots are clustered in a region composed as the intersection of a set of primative (sector-like) regions. The results reported evolve from application of a collection of mappings on the complex plane defined by a particular collection of Schwarz-Christoffel transformations.