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Throughout his distinguished career of over 40 years, Robin Hochstrasser has made significant contributions to several areas of science in the fields of chemical and biochemical physics. He has been at the forefront and made fundamental contributions to the fields of photochemistry, solid-state chemistry, ultra-fast laser spectroscopies, and protein dynamics. He has been a prolific researcher, producing over 560 publications. His work has been characterized by experts in the fields as “a constant stream of experiments of lasting significance” (J. Phys. Chem. 100 (1996) 11791).Robin began his career in the 1960s using a variety of magnetic and electric field measurements to study crystals at low temperatures to understand spin quantization in solids and electron exchanged-mediated energy transfer. This work, described as a “classic contribution” (J. Phys. Chem. 100 (1996) 11791) was the basis for much of the subsequent experimental and theoretical work on the effect of magnetic fields on molecular spectra and on the measurements of dipole moments.In the late 1970s, Robin recognized the power of laser technology for the study of molecules and soon became a leader in the field investigating solid, gas phase, and condensed phase systems. He developed and applied various ultra-fast laser techniques to study the structure and dynamics of complex molecules in liquid phase, chemical, and biochemical reactions. He made seminal contributions to the development of two-dimensional infrared spectroscopy (2D IR) on a time scale of a picosecond or less. This 2D IR spectroscopy measures coupling between two functional groups in a large molecule and can thus be used to measure distances, as for example, two amide carbonyl groups in a peptide molecule. On the ultra-fast timescale, one application of 2D IR is to gain information on the rate of protein folding and unfolding in solution. Some of Robin's greatest contributions to understanding biomolecules are said to be in the experimental studies on the picosecond and femtosecond dynamics of heme proteins. Using techniques he developed he was able to observe the interactions of oxygen, carbon monoxide, and nitric oxide with hemoglobin inside the protein.  相似文献   
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Children's lie-telling is surprisingly understudied among children with significant behavioral problems. In the present study, experimental paradigms were used to examine antisocial lie-telling among ethnically diverse 5- to 10-year-old children with disruptive behavior disorders (DBD;= 71) and a typically developing (TD) comparison sample (= 50) recruited from a southeastern state from 2013 to 2014. Children completed two games that measured the prevalence and skill of their lies: (a) for personal gain and (b) to conceal wrongdoing. Children with DBD were more likely to lie for personal gain than TD children. With age, children were more likely to lie to conceal wrongdoing, but the reverse was true regarding lies for personal gain. Results advance knowledge concerning individual differences in children's lie-telling.  相似文献   
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A stochastic actor‐based model was used to investigate the origins of sex segregation by examining how similarity in sex of peers and time spent in gender‐typed activities affected affiliation network selection and how peers influenced children's (= 292; Mage = 4.3 years) activity involvement. Gender had powerful effects on interactions through direct and indirect pathways. Children selected playmates of the same sex and with similar levels of gender‐typed activities. Selection based on gender‐typed activities partially mediated selection based on sex of peers. Children influenced one another's engagement in gender‐typed activities. When mechanisms producing sex segregation were compared, the largest contributor was selection based on sex of peers; less was due to activity‐based selection and peer influence. Implications for sex segregation and gender development are discussed.  相似文献   
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The funding environment has a profound impact on researchers’ behavior. In particular, it influences their freedom and readiness to conduct research ventures with highly uncertain outcomes. In this conceptual paper, we propose a concise new methodology to evaluate researchers’ risk aversion based on citation statistics. The derived single-number criterion PR is sensitive to the ratio of high impact versus average impact work, based on citation counts. We demonstrate the usefulness of PR on a micro and meso level in the field of chemistry. PR is a potentially valuable tool for managers in higher education, to control for the impact of their funding instruments. The conducted testing may, in addition, contribute to the literature stream dealing with the effects of peer review in the allocation of research funding. Our results support the view that peer review fosters mainstream research. However, faculties with the highest percentages of third-party funding may find ways to avoid the restrictive effects. We also find evidence that permanent positions back risky research endeavors.  相似文献   
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Conclusion Dance has made major incursions into the area of computer technology over the past 10 years. In this respect, it has more than rivalled the other arts and, in addition, has an even greater potential for reaching beyond current constraints and into the realm of vanishing horizons. Through computer and video technologies, dance has gained a potential and accelerated access to home audiences. Computer technology has also provided the art of dance with increased opportunities for creativity and experimentation, for literacy and for learning. In sum, and as a result, dance exemplifies the integration of artistic concerns and technological advances in today's world.  相似文献   
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Three experiments investigated the effects of magnitude and schedule of reinforcement and level of training in instrumental escape learning at a 24-h intertriai interval. In Experiment I, two magnitudes of reinforcement were factorially combined with two schedules of reinforcement (CRF and PRF). Under PRF, large reward produced greater resistance to extinction than did small reward, while the reverse was true under CRF. In Experiment II, two levels of acquisition training were factorially combined with three schedules of reinforcement (CRF, single-alternation, and nonalternated PRF). Patterned running was observed late in acquisition in the single-alternation extended-training condition. Resistance to extinction was greater for the nonalternated PRF condition than for the single-alternation condition following extended acquisition, and the reverse was true following limited acquisition. Experiment III confirmed the extinction findings of Experiment II. The results of all three experiments supported an analysis of escape learning at spaced trials in terms of Capaldi’s (1967) sequential theory.  相似文献   
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Although the relationship between relational victimization and psychosocial adjustment in adolescence has been established, it is unknown whether it extends into early adulthood. The current retrospective study investigated the relationship between recall of adolescent relational victimization and symptoms of depression, social anxiety, and loneliness in 205 undergraduate students. The effects of gender and perceived social support on these relationships were assessed, as were the psychometric qualities of the Relational Victimization Questionnaire (RVQ). Recalled adolescent relational victimization was related to increased symptoms of depression and social anxiety; neither gender nor perceived social support affected the strength of these relationships. Results indicated that the RVQ has adequate internal consistency and a single factor structure. Implications for psychologists working with adolescents are highlighted. © 2008 Wiley Periodicals, Inc.  相似文献   
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