Fact and fantasy in chemical analysis

Chemical analysis is now so precise and sophisticated a science that it is difficult to appreciate that scarcely a century ago its deficiencies were a cause for public scandal. This article reviews some of the main causes for complaint and how they were remedied.     

The graph-theoretic field model—I. Modelling and formulations

The Graph-Theoretical Field Model provides a unifying approach for developing numerical models of field and continuum problems. The methodology examines the field problem from the first stages of conceptualization without recourse to the governing differential equations of the field problem; this is accomplished by deriving discrete statements of the physical laws which govern the field behaviour. There are generally three laws, and these are modelled by the “cutset equations”, the “circuit equations”, and the “terminal equations”. In order to establish these three sets of equations it is expedient first to spatially discretize the field in a manner similar to the finite difference method and then to associate a linear graph (denoted as the field graph) with the spatial discretization. The concept of “through” and “across” variables, which underlies the cutset and circuit equations respectively, enables one to define the graph in an unambiguous manner such that each “edge” of the graph identifies a pair of complementary variables. From a knowledge of the constitutive properties and the boundary conditions of the field it is possible to associate terminal equations with sets of edges. Since the resulting sets of equations represent the field equations, these equations provide the basis for a complete (but approximate) solution to the field or continuum problem. In fact, this system approach uses a two part model: one for the components and another for the interconnection pattern of the components which renders the formulation procedures totally independent of the solution procedure.This paper presents the theoretical basis of the model and several graph-theoretic formulations for steady-state problems. Examples from heat conduction and small- deformation elasticity are included.     

Infant visual acuity as a function of viewing distance.

Dynamic retinoscopy has suggested that near vision may be more acute than far vision during early infancy. To test this, acuity thresholds were determined by presenting square wave gratings in a preference paradigm to 1- and 2-month-old human infants at 4 viewing distances. Gratings were paired with unpatterned fields; direction of first fixation was the dependent measure. Infants exhibited the same acuity at each of the distances at which gratings were presented. The results were interpreted as compatible with the fact that considerable optical defocusing does not seriously affect a visual system, such as the infant's, that is sensitive only to low spatial frequencies.     

Research findings and administrative implications for off-campus higher education

While off-campus educational programs grow in number and in importance in American higher education, little systematic research has been conducted concerning their effectiveness and intellectual and developmental impact. The project described here compared students in three categories: those studying abroad; those studying off-campus in this country; and those who remained on their home campus. The implications of the findings of the research suggest that a rethinking of existing programs is appropriate, if off-campus educational programs are to realize their full potential. The authors offer concrete suggestions toward restructuring these programs.

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Zusammenfassung Obwohl Bildungsprogramme ausserhalb der Universität in der amerikanischen Hochschulbildung an Anzahl und Bedeutung zunehmen, wurde deren Fruchtbarkeit und geistige und entwicklungsmässige Auswirkung kaum systematisch untersucht. Das hier geschilderte Projekt vergleicht Studenten dreier Kategorien: im Ausland studierende, im Lande ausserhalb der Universität studierende und solche, die in ihrem heimischen Universitätsbetrieb geblieben sind. Die Ergebnisse der Untersuchung legen die Folgerung nahe, es sei angebracht, bei eingeführten Programmen zu überdenken, ob die Bildungsprogramme ausserhalb der Universität ihre Möglichkeiten voll ausschöpfen sollen. Die Verfasser machen konkrete Vorschläge für eine Neugestaltung dieser Programme.

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Résumé Tandis que l'importance et le nombre des programmes d'éducation en dehors des universités s'accroît dans l'enseignement supérieur aux Etats-Unis, peu de recherche systématique a été effetué en ce qui concerne leur efficacité et leur impact intellectuel et de développement. Le projet décrit ici a comparé des étudiants de trois catégories: ceux qui étudient à l'étranger, ceux qui étudient hors des universités à l'intérieur du pays et ceux qui sont restés dans leurs universités d'origine. Les implications des conclusions de la recherche suggèrent qu'il convient de repenser les programmes existants, si les programmes d'éducation hors des universités doivent réaliser tout leur potentiel. Les auteurs présentent des suggestions concrètes quant à la restructuration de ces programmes.

     

The DT-Polynomial Approach to Discrete Time-Varying Network Flow Problems

This paper introduces a polynomial operator called the DT-polynomial as a novel approach to network flow problems. The class of networks dealt with is time-varying in the sense that the capacity, cost, and travel-time of each edge may vary in discrete time. The Dt-polynomial is a polynomial in two operators, D (delay) and T (time), which is used for describing the time-varying transmission characteristics. The paper starts with the mathematics involving the DT-polynomials. A new shortest arrival route algorithm is presented, and its computational complexity is found to be favorable in comparison with others such as Dijkstra's method and the potential method derived from Ford-Fulkerson's technique. Furthermore, a dynamic flow problem is formulated and analyzed in terms of DT-polynomials, and a latest-departure earliest-arrival schedule is given. Finally, a modified DT-polynomial is applied to digital filter networks.