煤田钻探用冲洗液类型的探讨

冲洗液对煤田钻探来说,是很重要的。从国内煤田钻探情况看,推广使用"双聚泥浆"等虽有较大进展,解决了不少问题,一些钻孔中水敏层超径及煤层中结核掉块卡钻等仍然严重;有些造浆地层使泥浆比重上升(至1.4以上),大大减低机械钻速等等问题,未能很好解决。从今后在煤田钻探中推广应用金刚石(绳索取芯)及其他新钻进方法看,也要求冲洗液具有更完善的性能。煤田钻探中常见的钻穿漏失问题,也值得进一步研究解决。     

Edaravone protects PC12 cells from ischemic-like injury via attenuating the damage to mitochondria

Background： Edaravone had been validated to effectively protect against ischemic injuries. In this study, we investigated the protective effect of edaravone by observing the effects on anti-apoptosis, regulation of Bcl-2/Bax protein expression and recovering from damage to mitochondria after OGD （oxygen-glucose deprivation）-reperfusion. Methods： Viability of PC 12 cells which were injured at different time of OGD injury, was quantified by measuring MTT （2-（4,5-dimethylthia-zol-2-yl）-2,5-diphenyltetrazolium bromide） staining. In addition, PC 12 cells＇ viability was also quantified after their preincubation in different concentration of edaravone for 30 min followed by （OGD）. Furthermore, apoptotic population of PC 12 cells that reinsulted from OGD-reperfusion with or without preincubation with edaravone was determined by flow cytometer analysis, electron microscope and Hoechst/Pl staining. Finally, change of Bcl-2/Bax protein expression was detected by Western blot. Results： （1） The viability of PC12 cells decreased with time （1-12 h） after OGD. We regarded the model of OGD 2 h, then replacing DMEM （Dulbecco＇s Modified Eagle＇s Medium） for another 24 h as an OGD-reperfusion in this research. Furthermore, most PC 12 cells were in the state of apoptosis after OGD-reperfusion. （2） The viability of PC 12 cells preincubated with edaravone at high concentrations （1, 0.1, 0.01 μmol/L） increased significantly with edaravone protecting PC 12 cells from apoptosis after OGD-reperfusion injury. （3） Furthermore, edaravone attenuates the damage of OGD-reperfusion on mitochondria and regulated Bcl-2/Bax protein imbalance expression after OGD-reperfusion. Conclusion： Neuroprotective effects of edaravone on ischemic or other brain injuries may be partly mediated through inhibition of Bcl-2/Bax apoptotic pathways by recovering from the damage of mitochondria.     

六（硫氰酸根-N）合铬（Ⅲ）酸钾的合成及电子光谱

合成标题配合物K3[Cr（NCS）6].4H2O并测定其在水溶液中的电子光谱。用RHF-SCF-PM3方法进行了几何优化,研究了配合物基态和激发态组态的电子结构。由ZINDO/S方法的组态相互作用（CI）计算给出了理论光谱,计算结果与实测谱吻合较好。     

若干因素对铬天青-S显色的影响

研究了室温、缓冲液两种pH值、显色时间、显色剂量对食品中铝测定的铬天青-S显色的影响;铝含量和吸光度之间的线性关系.结果显示：室温从21℃升高到33℃,吸光度相应增加;pH5.7缓冲液较pH5.5的吸光度轻微增加;加入铬天青-S20分钟后至45分钟内显色稳定;将显色剂量减半后吸光度稍微降低,显色效果改善;铝含量在0.5-6μg/ml范围内与吸光度之间线性关系良好;铝含量增至8μg/ml时失去线性关系;方法的重复性较好.     

铜铬钼／=二氧化硅三元复合加氢催化剂中铜,铬,钼的分析

本文报导了Ｃｕ＝ｅｒ－Ｍｏ／ｓｉｏ２三元复合催化剂中Ｃｕ，Ｃｒ，Ｍｏ的测定方法，此法简便，快速，获得令人满意结果。