Studying on the increasing temperature in IT-SOFC： Effect of heat sources

The dimensions and the materials type limit the performance of fuel cell. The increase of the temperature in electrodes and electrolyte of the cell,is due to the over potential of activation (transfer of load),the over potential Ohmic (resistance of polarization),the over potential of reaction (heat released by the chemical reaction) and the over potential of diffusion. In this paper,we studied the thermo-electrical performance of an intermediate temperature solid oxide fuel cell (IT-SOFC) with electrode supported. The aim of this work is to study this increasing temperature of a single cell of an IT-SOFC under the influence of the following parameters: heat sources,functioning temperature and voltages of the cell,geometric configuration and materials type. The equation of energy in one dimension is numerically resolved by using the method of finite volumes. A computing program (FORTRAN) is developed locally for this purpose in order to obtain fields of temperature in every element of the cell.     

碱金属氧化物稳定性的讨论

从热力学角度对碱金属的各类氧化物的稳定性进行了讨论。     

《硫的氢化物和氧化物》教案

[教学目的]1．使学生掌握硫化氢、二氧化硫的性质。2．了解二氧化硫的实验室制法和三氧化硫的性3．了解可逆反应概念。     

Preparation of Glutaraldehyde Cross-Linked Chitosan Beads Under Microwave Irradiation and Properties of Urease Immobilized onto the Beads

The glutaraldehyde cross-linked chitosan beads were prepared under microwave irradiation and urease was immobilized onto the beads. The activity and the yield of enzyme activity of the immobilized urease were 10.83 U/g carrier and 47.7%, respectively. The optimum conditions of immobilization were 1% of glutaraldehyde volume fraction, 10 mg/g of urease/beads weight ratio, 24 h of the processing time and pH 6.5 of the reaction medium for immobilization. The properties of the immobilized urease were investigated and compared with those of the free enzyme. The optimum pH values were 6.5 and 7.0 for the immobilized and free urease, respectively. The optimum temperature was 60℃ for the free urease, while it shifted to 65 ℃ for the immobilized enzyme. The Michaelis constant Kr, was 9.1 mmol/L for the immobilized and 12.5 mmol/L for the free urease. The immobilized urease retained 40% of its initial enzyme activity even after 10 repeated uses. The immobilized urease stored at 4 ℃ retained 46% of its initial activity even after 35 d.     

镁条在二氧化碳中燃烧实验成功技巧

镁条在CO2中燃烧实验是一个教师演示实验，它不仅说明了镁能跟某些氧化物起反应，同时还说明了镁燃烧时不能用CO2灭火的原因。实验过程中，如果按照现行高中化学第二册22面所述做实验，实验不容易成功。其主要原因是镁条的表面附着有一层致密的氧化物薄膜，阻止了镁条与CO2反应。如果实验中改用除去氧化物薄膜的镁条，镁条在空气中燃烧速率又太快，要用比较长的镁条才能使实验成功。我在实验过程中采取了以下方法，克服了以上方法的不足。     

非氧化物纳米材料的溶剂热合成

非氧化物如氮化物、碳化物纳米材料的通常制备方法 ,主要是高温反应。我们发展了溶剂热合成制备纳米材料的技术 ,在较低温度下制备了多种非氧化物纳米材料。     

铜-铬-钼-稀土/二氧化硅及铜-稀土/二氧化硅复合加氢催化剂的研究

在本研究中制备了一系列Ｃｕ－Ｃｒ－Ｍｏ－ＲＥ／ＳｉＯ２和Ｃｕ－ＲＥ／ＳｉＯ２催化剂。研究结果表明：在Ｃｕ／ＳｉＯ２催化剂中,引进Ｃｒ、Ｍｏ和稀土氧化物后能显著延长催化剂寿命。这一结果并用ＸＰＳ光谱对催化剂表面及用ＴＧ对催化剂抗结焦性能进行了分析研究结论为：Ｃｕ－Ｃｒ－Ｍｏ－ＲＥ／ＳｉＯ２和Ｃｕ－ＲＥ／ＳｉＯ２催化剂的负荷比Ｃｕ／ＳｉＯ２催化剂显著提高。     

Excimer紫外灯辐照法钽氧化物膜XPS分析

报道了利用新型紫外光源—Ｅｘｃｉｍｅｒ紫外灯辐照制备钽氧化物薄膜的新方法,并对所制备的薄膜进行了Ｘ光光电子能谱（ＸＰＳ）分析,分析结果表明：所制备的钽氧化物薄膜不含碳而且符合化学计量比,有望获得好的介电性能     

稀土氧化物负载CuO催化剂的CO氧化活性和还原性能

考察了稀土氧化物负载CuO催化剂的CO氧化活性和还原性能,发现CuO／CeO2催化剂具有很高的CO氧化活性,65℃时,CO转化率可达95％．