两种Co(Ⅲ)配合物键合异构体的制备及结构分析

本文通过条件选择合成两种Co(Ⅲ)配合物键合异构体[Co(NH3)5NO2]Cl2(配合物1)与[Co(NH3)5ONO]Cl2(配合物2),通过红外光谱、紫外光谱对配合物进行表征。确立两种键合异构体可能的结构。     

From aniline to phenol: carbon-nitrogen bond activation via uranyl photoredox catalysis

Carbon-nitrogen bond activation, via uranyl photoredox catalysis with water, enabled the conversion of 40 protogenetic anilines, 8 N-substituted anilines and 9 aniline-containing natural products/pharmaceuticals to the corresponding phenols in an ambient environment. A single-electron transfer process between a protonated aniline and uranyl catalyst, which was disclosed by radical quenching experiments and Stern-Volmer analysis, facilitated the following oxygen atom transfer process between the radical cation of protonated anilines and uranyl peroxide originating from water-splitting. ¹⁸O labeling and ¹⁵N tracking unambiguously depicted that the oxygen came from water and amino group left as ammonium salt. The 100-fold efficiency of the flow operation demonstrated the great potential of the conversion process for industrial synthetic application.