偶氮胂Ⅲ光度法测定微量稀土的实验教学改革

对偶氮胂Ⅲ分光光度法测定稀土元素钆进行了条件优化实验,其中控制显色剂用量是提高测定准确度的关键.在显色溶液中加入无水乙醇以及采用双波长光度法可有效提高测定灵敏度.该实验项目已取代传统的光度分析实验,成为实验教学与实际应用相结合的典范.     

Infrared Absorption Spectra of Serpentine Cat＇s Eye from Sichuan Province of China

Infrared （IR） absorption spectra and X-ray powder diffraction （XRD） patterrns of sexpenfine cat＇s eye from Sichuan Province have been investigated, and infrared absorption bands of the serpentine have been assigned in this paper. The results indicate that the bands near 3 600 - 3 700 cm^-1 belong to the stretching absorption band VOH, the bands in 948 - 1 100 cm^-1 axe assigned to the stretching vibraling band Usvo, and the bands at 600 570 and 440 cm^-1 respectively belong to the bending vibration band VOH, δMg-O and δSi-O. The serpentine cat＇ s eye includes two types： chrysotile and antigorite. Chrysotile has a sharp and intensive band at 3 688 cm^-1 and a weak band at 3 643 cm^-1 , while antigorite has only one intensive band in the region. At vibration band VSi-O, chrysotile and antigorite have a similar feature at 1 071 cm^-1, but the band at 980 cm^-1 in anfigorite has been split into two bands in chrysotile - a strong one at 1 027 cm^-1 and a weak one at 949 cm^-1. In addition, antigorite has a characteristic bending vibrating band δMg-O at 570 cm^-1. Based on the analysis of the feature of crystal structure, their IR differences axe well explained.     

等吸光点若干特性的证明

本文对等吸光点的重特性:吸光度只与总浓度有关,与各组分浓度无关;各组分摩尔吸光系数之间存在着一定关系。给出了证明。     

红外光谱法确认辽宁三地区苹果中黄烷醇类化合物

黄烷醇基本结构为C6·C3·C6型化合物 ,具有一定的抗癌活性 .其衍生形成的多酚类化合物对人体具有较强的抗衰老作用 ,它广泛存在于各种水果及一些植物中 .本文利用红外光谱法对辽宁三地区不同种类苹果的提取物进行了分析、比较 ,结果是辽南地区的苹果黄烷醇类化合物的含量少于辽西地区的苹果黄烷醇类化合物的含量 ,富士苹果的黄烷醇类化合物的含量高于国光苹果的黄烷醇类化合物的含量 ,为进一步研究开发提供了依据     

Er:LN晶体的生长和激光性能研究

在LiNbO5中掺进(0、0．5、1．0、1．5mol％)Er2O5，以Czochrals技术生长LiNbO5、Er(1mol％)：LiNbO3、Er(2mol％)：LiNbO3、Er(3mol％)：LiNbO3晶体。测试Er：LiNbO3晶体的吸收光谱，确定晶体的泵浦波长，Er：LiNbO3晶体的吸收变相对LiNbO3晶体发生红移，红移的程度随Er^3 浓度的增加而增大。测试Er：LiNbO3晶体的荧光光谱，Er：LiNbO3晶体易实现激光震荡的波长4115／2→4115／2(～1．5μm)，是制作波导激光器的最合适的波长。测试Er：LiNbO3晶体的光损伤阅值，其结果高于LiNbO3晶体。Er(3mol％)：LiNbO3晶体的光损伤阀值比LiNbO3晶体高一个数量级。     

企业技术引进复杂系统分析方法探讨

技术引进在很多企业中成效不大的原因之一,是没有把技术引进作为一个复杂系统并进行分析研究。为了实现技术引进的复杂系统进入良性循环,本文借鉴IDEF方法,从层次理论角度来分解技术引进的复杂系统,并着重对国内外研究较少的消化吸收进行了分析,阐明这一方法的应用过程。     

The Russian avant-garde painting palette: Documentary and physicochemical codification of organic colorants

In the present article an attempt is made to elucidate the organic colorants commonly encountered in the Russian avant-garde painting palette by a combined art historical, documentary and physicochemical investigation, and to examine the influence of environmental factors on the chromatic profile originally sought by the artist. The overall approach based on written sources is confirmed by measurements on relevant paintings. The documentary research deals with the influences of Orthodox iconography, folkloric art, and occidental modernist tendencies on the Russian avant-garde palette, and studies the effects of contradictory historical processes in the chromatic profile of individual paintings. In the experimental section a series of colorants are investigated concerning the effects of accelerated ageing on experimental painting tables, prepared as watercolor and gouache layers on paper ground. The resulting samples are subjected to colorimetric and spectroscopic measurements, and analogous analytical procedures are applied on samples taken from selected paintings. A systematic comparative study of all data permits evaluation of the materials used in terms of their stability towards extrinsic factors, and proposal of degradation routes in order to assist museum curators and conservators in every concrete case related to the broad spectrum of pigments examined.     

学术会议论文新颖性测度研究——以计算机学科人工智能领域为例

【目的/意义】研究学术会议论文新颖性测度方法,为会议论文的新颖性评价提供新的视角。【方法/过程】本 文设计吸收新颖性指标和产出新颖性指标测度方法,选择“人工智能”领域的会议论文进行实证研究。【结果/结论】 具有高吸收新颖性水平和高产出新颖性水平的论文成为A类会议论文的几率最高,结果表明新颖性测度方法的有 效性,对于会议论文的自动评审有一定的参考意义。【创新/局限】设计会议论文新颖性测度方法,促进会议论文评 价的发展;只针对计算机的人工智能领域进行实证,具有一定的领域局限性。     

不同质子酸掺杂聚苯胺的吸波性能研究

采用3厘米波导式测量线在8—14GHz频率范围内，用多点拟合的实验和计算方法对掺杂聚苯胺的微波吸收特性及参量进行了研究．发现：浓H2SO4掺杂本征态聚苯胺(PAn)所合成材料的电损耗很小、磁损耗较大(相对于盐酸聚苯胺而言)，且不利于对微波的吸收：FeCl3掺杂浓H2SO4-PAn材料可合成磁损耗较高、基本上有利于吸收微波的材料；更令人注意的是，利用HCl-PAn具有较大的电损耗，浓H2SO4-PAn—FeCl3材料具有较大的磁损耗这一特点，我们将它们按一定的比例混合，可以合成出平均衰减为13．37dB，最大衰减为26．7dB，密度为0．7g／cm^3、频宽为10．34—14GHz的很有利于吸收微波的材料．     

FAAS法测定凯里商陆不同部位的微量元素

采用火焰原子吸收光谱法测定凯里产商陆根、茎和叶中锌、铁、锰和铜的含量,为其开发和利用提供参考．结果表明,zn、Fe、Mn在商陆根中分别为60．64,528．17,105．63mg／kg;在商陆茎中分别为52．91,92．10,88．18mg／kg;在商陆叶中分别为133．10,726．37,589．47mg／kg．Cu未检出．Zn、Fe、Mn主要在商陆的叶中富集．