草酸钾-过氧化氢加合物的合成及结构表征

采用溶液结晶法制备了草酸钾-过氧化氢（K2C2O4·H2O2）晶体,过氧化氢的含量接近于理论值．利用红外光谱和X-射线衍射对草酸钾-过氧化氢加合物的结构进行了表征,得到了其红外光谱和X-射线衍射谱图,并对谱图进行了简要分析．     

超强磁场中H2^＋能级的B样条计算与绝热近似结果的比较

用B-splines技术将波函数在径向和角向同时展开,考虑两核之间的相互作用,计算超强外磁场中,氢分子离子基态（m=0）和低激发态（m=-1,-2,-3,-4）的能级与两核间距离的关系,计算结果在2．35×10^6→2．35×10^8T整个区域比绝热近似结果的精度提高0．01到0．02．     

富氧浸出机理及其在氰化提金中的应用

本文简述了金氰化学反应和氧在金氰化浸出中的重要作用,论述了富氧浸金机理及其在氰化提金中的应用.从研究资料表明,利用富氧浸出,可提高金溶解速度和显著提高金浸出率,并能增加浸出设备的生产能力.由于缩短浸出时间,从而降低了氰化物单耗量.     

Differential generation of hydrogen peroxide upon exposure to zinc and cadmium in the hyperaccumulating plant specie （Sedum alfredii Hance）

Sedum alfredii Hance has been identified as zinc (Zn) and cadmium (Cd) co-hyperaccumulator. In this paper the relationships of Zn or Cd hyperaccumulation to the generation and the role of H2O2 in Sedum alfredii H. were examined, The results show that Zn and Cd contents in the shoots of Sedum alfredii H. treated with 1000 μmol/L Zn2 and/or 200 μmol/L Cd2 increased linearly within 15 d. Contents of total S, glutathione (GSH) and H2O2 in shoots also increased within 15 d, and then decreased. Total S and GSH contents in shoots were higher under Cd2 treatment than under Zn2 treatment. However, reverse trends of H2O2 content in shoots were obtained, in which much higher H2O2 content was observed in Zn2 -treated shoots than in Cd2 -treated shoots. Similarly, the microscopic imaging of H2O2 accumulation in leaves using H2O2 probe technique showed that much higher H2O2 accumulation was observed in the Zn2 -treated leaf than in the Cd2 -treated one. These results suggest that there are different responses in the generation of H2O2 upon exposure to Zn2 and Cd2 for the hyperaccumulator Sedum alfredii H. And this is the first report that the generation of H2O2 may play an important role in Zn hyperaccumulation in the leaves. Oar results also imply that GSH may play an important role in the detoxification of dissociated Zn/Cd and the generation of H2O2.     

利用手持技术探究过氧化氢的分解

利用手持技术仪器测量过氧化氢分解时所引起的压强变化.通过实验比较了二氧化锰、马铃薯或干酵母作催化剂的条件下对H2O2溶液分解的影响.结果表明,增加催化剂的用量能提高分解反应的速率,增大H2O2溶液的浓度也会加快分解反应速率.对反应速率进行了线性拟合,建立了过氧化氢催化分解反应的动力学方程.     

金属离子对过氧化氢的催化分解作用研究

在弱酸性条件下，采用碘量法研究了Cu^2＋、Zn^2＋、Mn^2＋、Ni^2＋等金属离子在不同浓度下对过氧化氢溶液分解速率的影响。     

水杨酸在果实成熟衰老中的作用

成熟和衰老是果实发育的最后阶段,直接影响到果实品质和贮藏保鲜.成熟和衰老的调控一直被研究者所关注.该过程是一个复杂的代谢过程,除受遗传因子决定外,很大程度上受控于信息物质和多种代谢物质.SA是植物体内普遍存在的一种酚类化合物,被认为是一种植物内源信号分子和新的激素,在植物体内发挥着多种生理功能.最近的研究发现SA是一种乙烯生物合成的有效抑制剂,而乙烯的大量生成是果实趋于成熟衰老的重要特征之一.因此,SA抑制乙烯合成的研究必将成为探索SA延缓果实衰老机理的重要内容.     

辛烯氢甲酰化反应基础研究

研究气、液、固三相体系中烯烃氢甲酰化反应固载催化剂的制备方法及影响因素。重点论述固载铑催化剂的制备,包括对不同催化剂载体的优选及不同催化剂制备条件的研究。用不同方法进行催化剂制备并考察其催化反应的性能,最终确定了合适的固载铑催化剂的制备方法。     

Oxidative stress and serum α<Subscript>1</Subscript> — Antitrypsin in smokers

The present study was undertaken to evaluate the levels of serum lipid peroxide, nitric oxide end poducts, erythrocytic superoxide dismutase activity and serum α ₁-antitrypsin in smokers. Total 90 active cigarette smokers were subdivided into Group I (subjects with smoking habit of less than 10 cigarettes per day) and Group II (with smoking habit of more than 10 cigarettes per day). In both groups lipid peroxide and nitric oxide end products were significantly increased with significantly decrease in erythrocytic superoxide dismutase activity and serum α ₁-antitrypsin as compared to controls. Our findings show enhanced oxidative stress and reduced α ₁-antitrypsin in cigarette smokers. Further increase in number of cigarettes per day exacerbates the oxidative stress with decrease in α ₁-antitrypsin.     

γ辐射对α-亚麻酸氧化反应的影响

对α-亚麻酸及其乙酯分别在氧气气氛和氮气气氛下进行一定剂量的γ辐射,每隔2d测定其过氧化值.研究结果表明,辐射剂量和时间对亚麻酸的过氧化值有较大影响;同时探讨了亚麻酸在γ辐射下过氧化值与反应机制之间的内在联系。