In-situ production of ozone and ultraviolet light using a barrier discharge reactor for wastewater treatment

A dielectric barrier discharge （DBD） reactor consisting of water-filled dielectric tube electrodes was used for the treatment ofwastewater. The inner dielectric tube, which acted as the discharging electrode, was filled with an aqueous electrolyte solution. The outer dielectric tube, which served as the other electrode, was in contact with the wastewater, which was grounded. The present reactor system was energy-efficient for the production of ozone, not only because the perfect contact between the aqueous electrode and the dielectric surface minimized the loss of the electrical energy, but also because the DBD reactor was cooled by the wastewater. In addition, the ultraviolet （UV） light produced in the DBD reactor was able to assist in the wastewater treatment since the quartz tube used as the dielectric material was UV-transparent. The performance of the present DBD system was evaluated using a synthetic wastewater formed from distilled water and an azo dye, amaranth. The experimental parameters were the concentration of the electrolyte in the aqueous electrode, the discharge power, the initial pH of the wastewater and the concentration of hydrogen peroxide added to the wastewater. The wastewater treatment system was found to be effective for achieving decomposition of the dye.     

基于电火花线切割机床脉冲电源的主控电路改进研究

传统的电火花线切割机床脉冲电源主控电路采用51系列单片来设计和控制脉冲信号,其输出电流波形存在前后沿不陡峭、脉宽脉间数字调节范围较小且数字调节不方便等缺点。针对这些缺点,本文着力选用PIC单片机来设计脉冲发生器,以此对其主控电路进行改进。这样的改进,对减少加工电极丝的非正常损耗和提高整个机床高效低耗的加工性能,起到了至关重要的作用。     

Electrochemical behaviors of lomefloxacin at a single-wall carbon nanotube-modified electrode and its interaction with bovine serum albumin

The electrochemical behaviors of lomefloxacin at a single-wall carbon nanotube-modified glassy carbon electrode have been investigated by cyclic voltammetry. In a Britton-Robinson buffer (pH 4. 5 ), lomefioxacin yields a sensitive and well-defined oxidation peak at ca. 1.24 V (vs. SCE) on the modified electrode. Compared with the bare glassy carbon electrode, the oxidation peak current of lomefloxacin significantly increases and the oxidation peak potential positively shifts. Under the optimal conditions, the interaction of lomefloxacin with bovine serum albumin is also investigated. The results indicate that an electrochemically inactive supramolecular complex is formed and the formation of complex between lomefloxacin and bovine serum albumin is an intercalation mechanism. The proposed methods offer a reference for the studies on the biological effects and action mechanism of lomefioxacin with albumins in vivo.     

特殊电容器场强及电容计算的探讨

对特殊电容器一极板不平行的电容器进行了研究,主要采用数学物理方法中的复变函数及保角变换理论,结合电磁学和电动力学中的一些基本理论,对其进行了分析和研究,推导出了该类电容器特性参数一电场分布函数以及电容的计算公式,以及电场分布函数和电容值在具体条件下的计算方法．     

Electrochemical characteristics and applications of boron-doped polycrystalline diamond film electrodes

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用离子选择性电极在含钙溶液中测定氟

研究了在高含量钙溶液中用氟离子选择性电极标准曲线法测定氟的条件．实验表明,以大于0.01mo·L-1 EDTA为掩蔽剂可以有效排除Ca2 离子的干扰．在F-浓度为10-2 ～10-6 mol·L-1浓度范围,可得到EF-～logCF-直线关系．该法可用于含钙溶液中氟的准确测定．     

Intrinsically flexible displays: key materials and devices

Continuous progress in flexible electronics is bringing more convenience and comfort to human lives. In this field, interconnection and novel display applications are acknowledged as important future directions. However, it is a huge scientific and technical challenge to develop intrinsically flexible displays due to the limited size and shape of the display panel. To address this conundrum, it is crucial to develop intrinsically flexible electrode materials, semiconductor materials and dielectric materials, as well as the relevant flexible transistor drivers and display panels. In this review, we focus on the recent progress in this field from seven aspects: background and concept, intrinsically flexible electrode materials, intrinsically flexible organic semiconductors and dielectric materials for organic thin film transistors (OTFTs), intrinsically flexible organic emissive semiconductors for electroluminescent devices, and OTFT-driven electroluminescent devices for intrinsically flexible displays. Finally, some suggestions and prospects for the future development of intrinsically flexible displays are proposed.     

Integrated ‘all-in-one’ strategy to stabilize zinc anodes for high-performance zinc-ion batteries

Many optimization strategies have been employed to stabilize zinc anodes of zinc-ion batteries (ZIBs). Although these commonly used strategies can improve anode performance, they simultaneously induce specific issues. In this study, through the combination of structural design, interface modification, and electrolyte optimization, an ‘all-in-one’ (AIO) electrode was developed. Compared to the three-dimensional (3D) anode in routine liquid electrolytes, the new AIO electrode can greatly suppress gas evolution and the occurrence of side reactions induced by active water molecules, while retaining the merits of a 3D anode. Moreover, the integrated AIO strategy achieves a sufficient electrode/electrolyte interface contact area, so that the electrode can promote electron/ion transfer, and ensure a fast and complete redox reaction. As a result, it achieves excellent shelving-restoring ability (60 hours, four times) and 1200 cycles of long-term stability without apparent polarization. When paired with two common cathode materials used in ZIBs (α-MnO₂ and NH₄V₄O₁₀), full batteries with the AIO electrode demonstrate high capacity and good stability. The strategy of the ‘all-in-one’ architectural design is enlightened to solve the issues of zinc anodes in advanced Zn-based batteries.     

Nafion/MWCNT复合修饰电极测定痕量锡的伏安法

研究了利用Nafion/多壁碳纳米管(MWCNT)复合修饰玻碳电极测定痕量锡的阳极溶出伏安法。结果表明,在pH值为1.2的NH4Cl—HCl电解液中,当Sn(Ⅳ)在Nafion/MWCNT复合修饰电极表面富集时间为3min,电位扫描速度为200mV/s时,该修饰电极在伏安图上能出现一灵敏的氧化峰,峰电位约为-570mV,利用该峰可以进行痕量锡的检测;峰电流与Sn(Ⅳ)浓度在4.0×10-8~1.0×10-6mol/L的范围内呈良好线性关系,相关系数为0.997,检出限为1.0×10-8mol/L;该修饰电极稳定性较好,用于实际水样中锡含量的测定,平均回收率为97.48%,所得结果令人满意。     

新型场发射器件中栅极的化学刻蚀制备

为了得到碳纳米管场发射器件的三极结构,设计了一种新型栅极.在电极的制作过程中使用普通的丝网印刷方法,然后运用化学刻蚀的手段进行双面刻蚀制备出带有小孔阵列的栅极.在栅极制作过程中通过改变酸液刻蚀的时间和浓度,可以腐蚀出不同形状的小孔.运用扫描电镜(SEM)和红外光谱(IR)分析,得到小孔的尺寸、形貌和刻蚀液的成份,然后在三极结构上加电压显示出孔的亮度图像,最后对器件结构进行模拟,算出在电场条件下的电子从阴极拉到阳极基板的轨迹.模拟结果和实验结果一致,从而实现了对场发射三极器件的优化.