马来酸酐接枝改性石油树脂及其在热熔胶中的应用

以马来酸酐（MAH）为接枝单体和过氧化二异丙苯（DCP）为引发剂制备了石油树脂接枝马来酸酐（PR-g-MAH）,研究了DCP和MAH用量以及反应时间对石油树脂接枝率的影响,并将PR-g-MAH产物应用于LDPE/POE/LLDPE复合物中,制备了热熔胶,研究了PR-g-MAH用量对热熔胶粘结性能的影响。结果表明,MAH成功接枝到石油树脂上;当MAH用量为8%,DCP用量为2%,反应时间为2 h时,PR-g-MAH的接枝率最大,颜色也较浅;PR-g-MAH的用量为20%时,制备的热熔胶具有最高的剥离强度,达到110 N cm-1。     

精处理高速混床出水pH降低的原因分析

广东惠州平海发电厂在高速混床投运时出现产水pH降低现象,本文通过试验和分析,认为引起这一现象的原因是混床树脂混和不均,和树脂交叉污染,在碱性水工况下运行时释放出氯离子,导致高速混床产水pH降低。     

新型含硫萃淋树脂吸附贵金属的研究：石油亚砜萃淋树脂吸附富集金

测定了石油亚砜萃淋树脂的吸附性能，其饱和吸附容量Ｑ＝９０ｍｇＡｕ／ｇ树脂，金的吸附反应速率常数Ｋ＝１．０２×１０￣（－３）ｓ￣（－１），热焓△Ｈ＝－６．７０ｋＪ／ｍｏｌ，自由能变化△Ｇ￣（２９８）＝－２０．５９ｋＪ／ｍｏｌ，熵变△Ｓ＝４６．６Ｊ／ｍｏｌ·Ｋ．树脂吸附金的反应符合Ｆｒｅｕｎｄｌｉｃｈ等温吸附式．探讨了树胎吸附金的反应机理．用酸性硫脲或亚硫酸钠溶液均能定量洗脱吸附在树脂上的Ａｕ（Ⅲ），树脂可再生使用．     

Ischemia modified albumin: A novel marker for acute coronary syndrome

Early identification of patients with acute myocardial infarction is of prime importance due to the associated very high mortality. Only 22% of the patients presenting at emergency cardiology care with chest pain have coronary disease. A number of biochemical tests like CKMB and Troponin-T/I have been introduced for early detection of the coronary syndrome (ACS). Ischemia modified albumin (IMA) has been recently introduced as a marker of myocardial ischemia. We estimated serum IMA in four sequential samples from 25 patients admitted to ICCU. Twenty five healthy volunteers formed the control group from which the normal range was derived. IMA was significantly raised in ischemia patients than in controls as well as compared to the patients who did not have cardiac ischemia. IMA demonstrated good discrimination between the ischemic and the non-ischemic patients with an Odds Ratio of 16.9 (6.29–46.87) than CKMB which showed an Odds Ratio of 2.07 (1.18–6.08). Sensitivity and specificity of IMA for the detection of ACS was 78.0% and 82.7% compared to 58.0% and 60.0%, respectively for the CK-MB assay. The area under the ROC curve of IMA for ischemic v/s non-ischemic patients was 0.834. IMA appears to be developing into a new and very potent marker, of cardiac ischemia.     

对强制许可制度与观念的协调研究

强制许可是我国专利制度中的一个重要组成部分，但从实施的情况来看，自我国实施专利制度以来，其实施率为零，从而导致了法律界，知识产权的人士对我国制定强制许可制度的必要生产生怀疑，是否有必要继续保贸强制许可制度的问题也油然而生，本根据专利强制许可的形成依据，所产生的效果，结合国内外知识产权法津制度中对强制许可的规定，限制和要求等，对我国实行强制许可制度的必要性进行了论述，同时，结合与国际条约，国际公约以及国与国之间的协定等对强制许可制度法律条款的制定，协调，以及国内对强制许可的认识规定等，进行了协调研究，论证了我国现行历史阶段，应当保留强制许可的观点，并对强制许可法律，法规的修改提出了建议。     

Measuring scientific contributions with modified fractional counting

We develop and propose a new counting method at the aggregate level for contributions to scientific publications called modified fractional counting (MFC). We show that, compared to traditional complete-normalized fractional counting, it eliminates the extreme differences in contributions over time that otherwise occur between scientists that mainly publish alone or in small groups and those that publish with large groups of co-authors. As an extra benefit we find that scientists in different areas of research turn out to have comparable average contributions to scientific articles. We test the method on scientists at Norway’s largest universities and find that, at an aggregate level, it indeed supports comparability across different co-authorship practices as well as between areas of research. MFC is thereby useful whenever the research output from institutions with different research profiles are compared, as e.g., in the Leiden Ranking. Finally, as MFC is actually a family of indicators, depending on a sensitivity parameter, it can be adapted to the circumstances.     

水溶性树脂交联剂的合成

水溶性树脂作为聚合物的交联剂,广泛的应用在油田堵水调剖作业。本试验以苯酚和糠醛为实验原料,对水溶性树脂交联剂的生产工艺进行优化。研究结果表明：在碱金属为催化剂的条件下,以苯酚：糠醛（物质的量）=1：2.3进行反应,在70℃的下持续反应4小时,可以促使苯环上的邻、对位都进行羟甲基化反应,合成水溶性树脂交联剂。     

碳纤维在档案修裱黏合剂中改性应用的探析

目前的档案修裱黏合剂普遍使用纯淀粉浆糊,但纯淀粉浆糊形成的淀粉膜抗拉力弱、脆性大、易断裂,使得修裱后的纸张强度与耐久性不高。针对这一问题,将淀粉浆糊中添加不同比例的碳纤维进行改性,通过检测纯淀粉浆糊与改性淀粉浆糊所修裱的纸张的物理与化学性能,包括耐折度、撕裂度、抗张强度、pH值、白度,对比分析不同比例碳纤维改性淀粉浆糊对档案纸张强度的影响。结果表明,当碳纤维在淀粉中的质量比为1%时,修裱纸张的各项性能得到了显著提升。     

水溶性酚醛树脂改性离合器摩擦材料的制备与性能研究

分别采用水溶性酚醛树脂法、浸浆缠绕法和贴胶缠绕法3种工艺制备了汽车用离合器面片,研究了3种工艺对离合器面片的摩擦磨损性能、物理性能和力学性能的影响。结果表明：采用水溶性酚醛树脂工艺制备的离合器面片耐热性好,摩擦系数大小适中、热稳定性好,磨损率低,硬度、孔隙率适中,而且剪切强度和断裂应变最大,综合性能最为优异。     

纳米微晶纤维素增强糠醇树脂的研究

通过化学接枝的方法对糠醇树脂进行了NCC增强改性。结果表明,NCC增强糠醇树脂呈现出“镶嵌”式的球形突起构造;红外光谱图显示NCC成功接枝到了糠醇树脂上;热力学测试表明NCC的改性对糠醇树脂的低温热力学性能几乎没有影响;强度测试表明采用4％～5％的NCC添加浓度有助于提高树脂强度。