催化动力学光度法测定痕量钒(V)

研究了在酸性介质中痕量钒催化 H2 O2氧化抗坏学酸体系的反应和动力学条件 ,建立了催化动力学光度法测定痕量钒的新方法。该方法的检出限为 0 .0 5 ng/ m L ,线性范围为 0～ 0 .5μg/ 2 5 m L ,该方法用于水样及人发中痕量钒的测定 ,结果令人满意     

The innovative performance of in-house and contracted R&D in terms of patents and utility models

The standard empirical framework for analysing the R&D-patents relationship is widened both by examining the different role of in-house and contracted R&D in the innovative performance of firms, and by considering patents and utility models counts as measures of innovation output. Patents and utility models are considered to approximate for significant and incremental innovations, respectively. Applying count data econometrics to a panel data set of Spanish manufacturing firms surveyed in the period 1990-1996, a transcendental production function is estimated, which allows for non-constant elasticities of the R&D inputs. The results indicate that significant innovations are mainly gestated in-house, whereas contracted R&D seems more orientated towards innovations of incremental nature.     

Turning scientific and technological human capital into economic capital: the experience of biotech start-ups in France

This paper examines how scientific and technological (S&T) human capital is transformed into financial capital through the creation of firms by scientists. The analysis is based on a database describing the positions held by 132 founders from 62 French biotech SMEs. It shows that star scientists engage in highly risky but also valuable firms. Less famous scientists must develop their human capital rather than valorising a stock. The paper concludes by pointing to three paradoxes concerning the commitment and compensation scheme of star scientists and the managerial position of less known scientists.     

Commercialization of patents and external financing during the R&D phase

Using a unique database on Swedish patents owned by small firms and individuals, survival models estimate how different factors influence the decision to commercialize the patents. Such an analysis has seemingly never previously been undertaken. Since the owners know more about the patents than potential external financiers, problems related to asymmetrical information are present. To overcome these problems when inventors and small technology-based firms need financing, Sweden has for a long time relied on government support rather than private venture capital firms. The empirical results show that the larger is the share of patent-owners’ costs covered by government financial support during the R&D phase, the lower is the probability of patents being commercialized. This lower degree of commercialization is likely to depend on (1) the soft terms of the government loans, where the patent owner can avoid paying back the loan if the patent is never commercialized and/or (2) that the government is not able to select promising projects. The first explanation is related to moral hazard and the second one to adverse selection. The policy suggestion is for government to change the design of the loans, to base them on firms rather than projects.     

介孔纳米γ-Al_2O_3对稀土镧（Ⅲ）的吸附性能研究

以溴化十六烷基三甲铵（CTAB）为模板剂,采用溶胶-凝胶法合成介孔纳米γ-Al2O3,用透射电镜（TEM）、比表面测定（BET）、X射线衍射（XRD）、和N2的吸附-脱附技术、Zetaplus电位测定,对所得的介孔纳米γ-Al2O3进行了表征。考察了介孔纳米γ-Al2O3在静态条件下对La（Ⅲ）的吸附性能。探讨了溶液的初始浓度、pH值、时间和温度对吸附性能的影响。结果表明：介孔纳米γ-Al2O3对La（Ⅲ）有很好的吸附性能,其吸附行为符合Freundlich吸附等温式。     

[Bmim]BF4离子液体中微波辅助制备TiO2催化剂及活性研究

采用微波加热合成离子液体[Bmim]BF4,以该离子液体为反应介质,在微波辐射条件下制备TiO2光催化剂,在高压汞灯下用甲基橙溶液测试其光催化降解性能;并用XRD,IR,TG对其进行测试和表征。结果表明,制备TiO2光催化剂的较佳条件是:离子液体2.0mL,微波辐射功率600W、反应温度70℃、反应时间35min。并且用[Bmim]BF4作为反应介质,能够显著提高TiO2的光催化活性,所制备的TiO2不需要经过高温煅烧,就表现出极高的光催化活性。该催化剂对甲基橙的降解率在1.5h就可达到93.7%。     

从《榆树下的欲望》看尤金·奥尼尔对人性的解读

通过对奥尼尔经典作品之一《榆树下的欲望》中主要人物的分析,展现出奥尼尔的悲剧论,以及他对贪婪人性的敌对、失望和对唤起人性真实的渴望。他认为人的悲剧是由多方面因素造成的,而自身性格的弱点和缺陷是不可忽视的重要因素。故事试图向人们揭示出,当金钱成为衡量一切的标准时,人的自然情感是怎样被压抑和扭曲的。     

S2O8^2-/V2O5-CeO2型固体超强酸催化剂的制备研究

以NH4VO3为原料,（NH4）2S2O8为浸渍液,添加少量稀土Ce^4＋,用沉淀-浸渍法制备出新型S2O8^2-/V2O5-CeO2固体超强酸催化剂,以合成乙酸苄酯作为探针反应考察不同条件下制备的超强酸的催化活性。研究发现,当加入CeO2量为催化剂总量的1．0％,焙烧温度为500℃,浸渍液浓度为1．5mol／L,焙烧时间为3h时,催化剂的活性最好。     

ONP脱墨浆的可漂性研究

ONP脱墨浆往往需要进一步漂白。对5种用不同脱墨剂处理的ONP脱墨浆进行了H2O2漂白实验,结果表明不同脱墨剂处理的ONP白度增加幅度不相同,各脱墨浆的可漂性并不相同。实际使用ONP脱墨浆时需考虑其漂后白度增幅潜力。     

NiCo_2O_4纳米结构阵列的水热合成与氧析出特性研究

钴酸镍纳米材料具有良好的电催化氧析出反应(Oxygen Evolution Reaction,OER)活性,是一种很有发展潜力的非贵金属电催化材料。文章以碳纤维纸为基底,采用水热合成的方法对纳米结构钴酸镍的生长进行了系统的研究,分别考察了生长温度、前驱体浓度和配比、生长时间对产物的形貌、尺寸、物相结构、OER电化学性能的影响,通过对比分析后发现在生长温度100℃、生长时间5h、镍钴比为2:1时所获得的多孔片状钴酸镍纳米结构具有最佳的OER特性。