大块非晶合金摩擦磨损变形特性的力信号分析

为了分析非晶合金的力学特性,提出了一种可实时观测大块非晶合金摩擦磨损变形特性的实验方法.实验分两步进行,首先对Zr基大块非晶合金与铜、铁、塑料进行同速度的干摩擦实验,然后单独对Zr基大块非晶合金进行不同速度下的干摩擦实验,都提取摩擦过程中的摩擦力信号,并利用扫描电子显微镜观察磨损形貌.与其他材料对比,分析Zr基大块非晶合金材料的摩擦磨损变形特性,从而确定其摩擦磨损主要是塑性变形和脆性断裂综合作用结果.另外随着转速提高,磨粒磨损使多角度的摩擦力高频率出现.     

介观结构对FeCo基纳米晶合金高温磁性的影响

FeCo基纳米晶合金具有良好的高频、高温磁性能,在航空航天领域有着广泛的应用前景,但其物理本质和微观机理尚不清楚。本文用原子力显微镜、高分辨场发射电子显微镜和透射电镜对FeCo纳米晶合金薄带横断面的介观结构进行了研究,发现退火温度和工作温度对其介观结构、介观尺寸上物质成份的迁移、滞留都有显著的影响,其结果决定着合金薄带的高温磁性能。     

船舶钛合金构件拉伸疲劳断口分析

对TC4钛合金试样拉伸疲劳断裂宏观试验结果、相应的断口和卸载表面观察分析研究,发现在试样断口上有明显的河流花纹走向、韧窝和韧性条带特征.其断裂机理是疲劳拉伸载荷作用下,在应力值比较高时一些沿层裂纹开始出现并扩展,同时微孔长大形成韧窝,并最后导致了材料断裂.     

Static recrystallization process comparison of AZ31 magnesium alloy deformed by cold compression and cold forging

We deformed AZ31 magnesium alloys by cold forging and cold compression process, and investigated their static recrystallization kinetics during the annealing process. The results demonstrate that the relationship between the annealing time and the fraction of recrystal grains can be described by the Johnson-Mehl-Avrami-Kolmogorov （JMAK） equation. Based on the kinetics analysis, we calculated that the activation energy of recrystallization by cold forging and cold compression were about 53.5 kJ/mol and 85.0 kJ/mol, respectively. The activation energy of cold compression process was higher than that of the cold forging process because the latter had high-rate deformation, which caused more energy storage during deformation.     

用集团变分法计算合金相图

用集团变分法计算了无序结构和A3B结构的相图,得出不同结构对应的稳定区域。     

Structure and Magnetic Properties of Fe1-xCx Solid Solution Prepared by Mechanical Alloying

Supersaturated solid solutions Fe1-xCx （0≤x≤0.9 ） of wide composition range have been prepared by mechanical alloying process. Nanocrystalline phase was formed for 0 ≤ x ≤ 0.67 and a large grain phase for 0.75 ≤ x ≤ 0.9. The large fraction of graphite volume puts off formation of nanocrystalline phase for high carbon content. In the large grain phase, magnetization follows simple magnetic dilution, and eoereivity He is mainly due to dissolution of carbon at grain boundaries. In the nanocrystalline phase the alloying effect of carbon is revealed by a distinct reduction of average magnetic moment. The increasing lattice constant with increasing carbon content is observed for x ≤ 0.5, suggesting that the high carbon concentration may enhance diffusion of carbon into the Fe lattice. It shows a discontinuity in the Hc variation with a grain size D of nanocrystalline phase. For small grain D below the critical value, Hc increases with D. For a large grain D, Hc decreases with increasing D. The solubility limit of carbon in a-Fe extended by nanocry- stalline phase formation is discussed.     

Effects of doping Fe and Al on microstructure and electrochemical characteristics of Mg-based hydrogen storage alloys

The Mg-based hydrogen storage alloys Mg2Ni, Mg2Ni0.7Fe0.3 and Mgl.7Alo.3Ni were successfully synthesized by a two-step process （sintering and ball milling）. The crystal structure and microstructure were examined by X-ray diffraction, Scanning Electron Microscope and Malvern particle size analyzer. New phase appears in the tripe alloys doped with A1 and Fe, and the particle size ranges from 3μm to 5 μm. The electrochemical performance studies indicate that the partial substitution of AI for Mg, and Fe for Ni significantly improve the cycle life, reversibility of hydrogen absorption and desorption. The diffusion process is the control step in the electrode reaction of hydrogen storage alloys.     

Zr-Al基大块非晶合金的晶化动力学效应

Zr65 Al10 Ni10 Cu15, Zr52.5 Al10 Ni10 Cu15 Be12.5 and Zr52.5 Al10 Ni14.6 Cu17.9 Ti5 bulk amorphous alloys were prepared by copper mould casting. The crystallization kinetics was measured by differential scanning calorimeter(DSC) with different heating rates, and the activation energy was calculated using Kissinger equation. The relationship between thermal stability and rate constant of crystallization reaction is discussed on the view of crystallization kinetics, and the effect of small atom Beryllium on thermal stability of bulk amorphous alloys is also studied.     

AgxZn1-x和AgxAl1-x双相合金超导体的超导态参数

A well-known pseudopotential is used to investigate the superconducting state parameters (SSP), viz., electronphonon coupling strength, Coulomb pseudopotential, transition temperature, isotope effect exponent and effective interaction strength for Ag _x Zn_{1 − x} and Ag _x Al_{1 − x} binary alloys theoretically for the first time. We have incorporated here five different types of the local field correction functions to show the effect of exchange and correlation on the aforesaid properties. Very strong influence of various exchange and correlation functions is concluded from the present study. Comparison with others such experimental values is encouraging, which confirms applicability of the model potential in explaining the superconducting state parameters of binary mixture.      

Heusler合金Co2YZ（Z=Si，Al，Ge，Ga）半金属性的第一原理研究

应用基于密度泛函理论（DFT）的投影扩充波函数（PAW）方法,分别在广义梯度近似GGA和GGA＋U（在位库仑能）近似下,研究了Heusler合金化合物Co2YZ（Z=Si,A1,Ge,Ga）的晶体结构、电子结构和磁性等物理性质．发现Heusler合金Co2YSi在平衡晶格常数时显示了亚铁磁半金属性质,并且在一定程度的晶格常数变化范围内保持其半金属性质．另外Co原子的磁矩对局域环境具有很强的依赖关系,即Z位元素的变换很大程度影响Co原子的磁矩．