Halogen bonding in the co-crystallization of potentially ditopic diiodotetrafluorobenzene: a powerful tool for constructing multicomponent supramolecular assemblies

Halogen bonding is emerging as a significant driving force for supramolecular self-assembly and has aroused great interest during the last two decades. Among the various halogen-bonding donors, we take notice of the ability of 1,4-diiodotetrafluorobenzene (1,4-DITFB) to co-crystallize with diverse halogen-bonding acceptors in the range from neutral Lewis bases (nitrogen-containing compounds, N-oxides, chalcogenides, aromatic hydrocarbons and organometallic complexes) to anions (halide ions, thio/selenocyanate ions and tetrahedral oxyanions), leading to a great variety of supramolecular architectures such as discrete assemblies, 1D infinite chains and 2D/3D networks. Some of them act as promising functional materials (e.g. fluorescence, phosphorescence, optical waveguide, laser, non-linear optics, dielectric and magnetism) and soft materials (e.g. liquid crystal and supramolecular gel). Here we focus on the supramolecular structures of multicomponent complexes and their related physicochemical properties, highlight representative examples and show clearly the main directions that remain to be developed and improved in this area. From the point of view of crystal engineering and supramolecular chemistry, the complexes summarized here should give helpful information for further design and investigation of the elusive category of halogen-bonding supramolecular functional materials.     

Dynamic response of RPC-filled steel tubular columns with high load carrying capacity under axial impact loading

Experimental investigation into impact-resistant behavior of reactive powder concrete (RPC)-filled steel tubular columns was conducted,and dynamic response of the columns under axial impact loading was studied by means of numerical simulation method.Increase coefficient of load carrying capacity and ratio of load carrying capacity between steel tube and RPC core of col-umns were obtained.     

Test and Analysis of an Existing Tunnel Vibration Induced by Blasting Construction of Diaphragm Wall

According to the blasting construction of the diaphragm wall of Puxi approaching section of East Fuxing Road river-crossing tunnel, the monitoring project of the vibration of the existing tun-nel induced by the blasting construction is put forward, which includes the sensors’ location, moni-tor method and the vibration monitoring system. Based on the monitoring data of the explosion vibration, the vibration wave forms, velocities, acceleration responses, main frequencies and fields of measure points are analyzed under the conditions of three locations and different charge quanti-ties. According to the safety-judging standard of explosion vibration, the conclusion that the exist- ing tunnel is safe under the explosion vibration is then drawn. Furthermore, the spectrum character-istics of three explosion vibrations and the spectrum changing properties of explosion vi-bration wave transmitting in different directions are concluded, which can provide reference to similar projects.     

酸性木聚糖酶产生菌产酶条件及部分酶学性质研究

从煤矿酸性废水中分离到一株产木聚糖酶青霉,通过酸性液体培养研究了菌体生长对pH的响应及木聚糖酶的产生特征,并测定了木聚糖酶的部分应用性质。结果表明：实验菌株嗜酸,菌丝生长最适pH为2．0,孢子萌发生长适宜pH为3．0—4．0;木聚糖诱导菌体在生长稳定期大量产生木聚糖酶,蛋白胨是菌体产酶的适宜氮源;菌株所产木聚糖酶属于酸性木聚糖酶,反应最适pH3．5、最适温度50℃-55℃,在最适反应条件下保温60min,残余酶活仍接近70％,适用于较强酸性的高温加工环境。     

利用废钢、废机铁生产球墨铸铁管件的试验研究

以废钢、废机铁及回炉料为主要原料,配以增碳剂和球化剂,通过中频炉熔炼,同步生产出了铁素体球墨铸铁管件及其Y形单铸试样。单铸试样的力学性能测试及金相组织观察结果表明:所生产的球墨铸铁其抗拉强度平均为455.0 MPa,屈服强度平均为328.2 MPa,布氏硬度平均为171.0 HBW,伸长率平均达到15.3%,优于GB/T 1348-2019中QT450-10的性能指标;基体组织为多边形铁素体,球状石墨分布均匀、圆整度较好、大小相差不大,有点状石墨存在,能够满足此类管件产品的性能要求。     

产品更新的财务特点及其净现值法的优化

由于市场竞争和技术推动,产品更新速度越来越快,其财务决策已经成为企业重要的决策之一。在此,对产品更新财务特点进行分析,并根据得出的结果对常用的产品更新财务决策方法即净现值法进行优化,以使企业得出更为准确的产品更新财务决策建议。     

冷轧薄板冲压性能的影响因素

概述了冷轧薄板的冲压性能的评价指标,详细介绍了冷轧薄板的化学成分、织构和晶粒尺寸、表面质量、厚度尺寸公差、冷轧工艺条件、拉伸试验值对冷轧薄板冲压性能的影响,并应用ANS YS/LS-DYNA软件对板材弯曲成形过程进行了模拟.     

显示器视觉特性化研究

目前显示器特性化常用仪器测量的方法使出版系统和一些网络用户要求更方便、快速地进行颜色通信和再现．实验利用人的眼睛视觉特点,采用同色闪烁光度测量法估计GoG参数,进行显示器特性化研究。实验表明,这种方法对L^o,a^o、b^o控制的精度分别是0．16,0．84,1．95,对色差CIELAB的控制糟度是2.31．     

链烷烃结构参数与热力学性质的相关性

以气态链烷烃为研究对象,选取两种结构参数,并与烷烃热力学性质关联,拟合成3个成性回归方程,其相关系数分别达到0．9985、0．9980和0．9889。结果表明：C原子数对烷烃热力学性质的影响最大,取代基数量、位置和种类的影响次之。本方法计算简单,参数具有较好的结构选择性和性质相关性,为预测烷烃热力学性质提供了一个有效的方法。     

基于技术标准合作的企业虚拟集群:内涵、特征与性质

基于技术标准合作的企业虚拟集群是一种基于网络的、以现代信息和通信技术为主要交流手段,以共同发展和利用技术标准为内容和目的的相互关联的企业与组织在虚拟空间的集聚.它是新时期产业组织形式的创新与发展,是市场全球化与网络经济条件下企业竞争与合作的重要组织形式,具有区别于传统地理集群的内涵、结构、特征与性质.