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判断存在手性碳原子的环己烷R/S的简便方法 总被引:1,自引:0,他引:1
归纳阐述了存在手性碳原子的环己烷判断R/S的方法为"环己烷的构象转为费歇尔时,环碳在横向,编号61234561a,e,上下交替换,奇碳a上e下,偶碳e上a下.对映体椅型结构互转变,编号顺变逆,ae,键基团位不变,-对映构型只是R变S,S变R",并应用举例. 相似文献
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用Excel处理钠原子光谱实验数据,利用其"单变量求解"功能求量子缺,方法简单、快捷,且无需里德伯表. 相似文献
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Performing real-time note detection of multiple audio sources, such as guitar signals, is a difficult task due to the complex nature of these signals. For instance, guitar notes are close in pitch and the harmonic overtones of each note are strongly interlaced, thus preventing standard filtering techniques. In order to accomplish note detection, a harmonic matching pursuit algorithm has been used to decompose an audio signal in terms of elementary waveforms called harmonic atoms. These atoms are derived from the standard matching pursuit algorithm, and are part of an extended and overcomplete Gabor dictionary. In this paper, the search over Gabor dictionary is optimized by using signal modeling of the guitar signal in order to pre-calculate a parameter set; therefore avoiding a costly search over the extended Gabor dictionary. The parameter set defined for the proposed algorithm includes time-location, decay rate, frequency, scale and phase, which are calculated at the onset of each note played. This optimized algorithm is demonstrated through synthesized and real guitar signal examples. Considerable computational savings of this proposed algorithm over the harmonic matching pursuit algorithm are achieved. 相似文献
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研究了两个全同的二能级原子与单模真空辐射场相互作用系统中原子偶极矩的高阶压缩效应.通过数值计算,讨论了原子间偶极相互作用对原子偶极矩高阶压缩的影响. 相似文献
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The Hamiltonian of coupled three-level atoms interacting with light field in the cavity filled with Kerr-like medium is derived. A simplified analytic solution to the Schrodinger equation of the system is obtained. The case of A type atom with degenerate lower levels is discussed in detail. It is shown that the coupling strength between atoms and Kerr coefficient affect the system's dynamic behaviors, especially the modulation period and oscillation frequency of the squeezing parameters of the field and the collective dipole moment. Dynamic behaviors of the system are sensitive to the initial state of atoms. 相似文献
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晶体场理论的主要缺点是忽略了配位原子的价层电子结构特征,因而不能解释光谱化学序列.在考查光谱化学序列中配体配位原子的丰径大小及其价层电子结构特征的基础上。提出了配位原子的价层电子——中心原子d电子互斥模型,用以说明配体在光谱化学序列中的位序.还探讨了该互斥模型与分子轨道理论都可以说明光谱化学序列的原因. 相似文献
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基于瓜环-磷光体-重原子微扰剂形成三元包络物,在亚硫酸钠除氧条件下诱导产生咖啡因室温磷光做了研究.并且针对体系的影响因素:重原子、Q[6]、亚硫酸钠用量、放置时间长短和最佳pH范围等做了较详细的研究.此外还对体系的分析性能做了测试,初步建立了检测咖啡因的室温磷光分析方法. 相似文献
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文章提出一种利用二能级双原子与量子化光场的相互作用系统实现控制Z门的设计方案。研究结果表明:量子化光场初始时刻制备于相干态,双原子处于叠加态,在大失谐相互作用情况下,控制光场与叠加双原子的相互作用时间,就可以实现控制Z门。 相似文献
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