发现新型环境有机污染物的基本理论与方法

20世纪以来化学污染物导致的人类健康危害日益突出,数以万计的高生产量化学品伴随着生产和使用进入环境介质,给环境科学相关领域研究提出了若干新的科学问题。文章介绍了发现新型有机污染物研究方向设立的背景和科学意义,讨论了判别新型有机污染物分子结构、环境行为特征的基本原则,阐述了定量结构—性质关系模型预测、疑似目标/非目标分析、效应导向分析方法框架的技术思路和优势。对于新型有机污染物识别、行为和效应的深入探索,将为引领学科方向发展、完善化学品风险评估标准、揭示环境污染物的毒性和健康危害机制发挥重要的支撑作用。     

双重低碳营销补贴下供应链低碳策略的演化博弈

在政府给予制造商、零售商,制造商给予零售商的双重低碳营销补贴的背景下,考虑由上游制造商与下游零售商组成的二级供应链,研究供应链的减排活动及低碳营销问题,建立上下游企业以推动低碳产品流动为目标的低碳投入演化博弈模型,探讨上下游企业低碳投入行为的演化稳定策略。结果表明：制造商与零售商的低碳策略与双方低碳投入收益比和政府补贴密切相关,当低碳投入收益比和政府补贴不断变化时,出现多种演化稳定均衡。针对低碳投入中零售商的“搭便车”行为问题,分析了制造商低碳营销补贴机制下的演化博弈结果,并探讨补贴激励的适用条件。     

A highly alkaline-stable metal oxide@metal–organic framework composite for high-performance electrochemical energy storage

Most metal–organic frameworks (MOFs) hardly maintain their physical and chemical properties after exposure to alkaline aqueous solutions, thus precluding their use as potential electrode materials for electrochemical energy storage devices. Here, we present the design and synthesis of a highly alkaline-stable metal oxide@MOF composite, Co₃O₄ nanocube@Co-MOF (Co₃O₄@Co-MOF), via a controllable and facile one-pot hydrothermal method under highly alkaline conditions. The obtained composite possesses exceptional alkaline stability, retaining its original structure in 3.0 M KOH for at least 15 days. Benefitting from the exceptional alkaline stability, unique structure, and larger surface area, the Co₃O₄@Co-MOF composite shows a specific capacitance as high as 1020 F g⁻¹ at 0.5 A  g⁻¹ and a high cycling stability with only 3.3% decay after 5000 cycles at 5 A g⁻¹. The as-constructed solid-state flexible device exhibits a maximum energy density of 21.6 mWh cm⁻³.     

Diagnosis of CO2 dynamics and fluxes in global coastal oceans

Global coastal oceans as a whole represent an important carbon sink but, due to high spatial–temporal variability, a mechanistic conceptualization of the coastal carbon cycle is still under development, hindering the modelling and inclusion of coastal carbon in Earth System Models. Although temperature is considered an important control of sea surface pCO₂, we show that the latitudinal distribution of global coastal surface pCO₂ does not match that of temperature, and its inter-seasonal changes are substantially regulated by non-thermal factors such as water mass mixing and net primary production. These processes operate in both ocean-dominated and river-dominated margins, with carbon and nutrients sourced from the open ocean and land, respectively. These can be conceptualized by a semi-analytical framework that assesses the consumption of dissolved inorganic carbon relative to nutrients, to determine how a coastal system is a CO₂ source or sink. The framework also finds utility in accounting for additional nutrients in organic forms and testing hypotheses such as using Redfield stoichiometry, and is therefore an essential step toward comprehensively understanding and modelling the role of the coastal ocean in the global carbon cycle.     

Encapsulating metal organic framework into hollow mesoporous carbon sphere as efficient oxygen bifunctional electrocatalyst

Applying metal organic frameworks (MOFs) in electrochemical systems is a currently emerging field owing to the rich metal nodes and highly specific surface area of MOFs. However, the problems for MOFs that need to be solved urgently are poor electrical conductivity and low ion transport. Here we present a facile in situ growth method for the rational synthesis of MOFs@hollow mesoporous carbon spheres (HMCS) yolk–shell-structured hybrid material for the first time. The size of the encapsulated Zeolitic Imidazolate Framework-67 (ZIF-67) is well controlled to 100 nm due to the spatial confinement effect of HMCS, and the electrical conductivity of ZIF-67 is also increased significantly. The ZIF@HMCS-25% hybrid material obtained exhibits a highly efficient oxygen reduction reaction activity with 0.823 V (vs. reversible hydrogen electrode) half-wave potential and an even higher kinetic current density (J_K = 13.8 mA cm⁻²) than commercial Pt/C. ZIF@HMCS-25% also displays excellent oxygen evolution reaction performance and the overpotential of ZIF@HMCS-25% at 10 mA cm⁻² is 407 mV. In addition, ZIF@HMCS-25% is further employed as an air electrode for a rechargeable Zn–air battery, exhibiting a high power density (120.2 mW cm⁻² at 171.4 mA cm⁻²) and long-term charge/discharge stability (80 h at 5 mA cm⁻²). This MOFs@HMCS yolk–shell design provides a versatile method for the application of MOFs as electrocatalysts directly.     

我国低碳航运产业价值链的结构乘数效应

针对航运低碳投资支出巨大的问题,运用结构性乘数,对我国用于低碳航运产业价值链中的支出产生的乘数效应进行研究.由两部门计算的简单投资乘数为1.547 7,由四部门计算的投资乘数均值为1.293 1.从长期看,乘数效应反映出航运低碳产业的投资收益大于投资支出,对航运业低碳减排具有现实和经济意义.     

中国乘用车物质代谢与碳减排策略

中国是全球最大的汽车制造和消费国,汽车行业带来的资源消耗和温室气体排放受到了学者的广泛关注.辨析汽车行业的物质资源代谢特征和碳减排潜力可为落实循环经济政策和实现可持续发展提供科学依据.本文基于动态物质流模型,预测了中国乘用车中21种物质材料的代谢特征,评估了乘用车使用过程中的碳减排潜力.研究结果表明:①1949-201...     

Molecular design revitalizes the low-cost PTV-polymer for highly efficient organic solar cells

Developing photovoltaic materials with simple chemical structures and easy synthesis still remains a major challenge in the industrialization process of organic solar cells (OSCs). Herein, an ester substituted poly(thiophene vinylene) derivative, PTVT-T, was designed and synthesized in very few steps by adopting commercially available raw materials. The ester groups on the thiophene units enable PTVT-T to have a planar and stable conformation. Moreover, PTVT-T presents a wide absorption band and strong aggregation effect in solution, which are the key characteristics needed to realize high performance in non-fullerene-acceptor (NFA)-based OSCs. We then prepared OSCs by blending PTVT-T with three representative fullerene- and NF-based acceptors, PC₇₁BM, IT-4F and BTP-eC9. It was found that PTVT-T can work well with all the acceptors, showing great potential to match new emerging NFAs. Particularly, a remarkable power conversion efficiency of 16.20% is achieved in a PTVT-T:BTP-eC9-based device, which is the highest value among the counterparts based on PTV derivatives. This work demonstrates that PTVT-T shows great potential for the future commercialization of OSCs.     

京津冀物流业碳排放量测算及绿色协同发展路径研究

目前,京津冀区域内物流业正在深入协同发展,选取相关数据,通过统计京津冀物流业的能源消耗量,测算碳排放量,剖析其成因,从制定政策、推行标准、调整运输结构等方面构建京津冀物流业绿色协同发展路径,实现降低碳排放量的目的,为区域经济发展构建绿色物流体系,最终为京津冀区域经济的生态文明建设提供依据。     

以二氧化碳规模化利用技术为核心的碳减排方案

碳资源是人类社会发展进入工业时代的基石。人类大量使用含碳资源产生的二氧化碳(CO_2)不应给人类社会带来威胁,更不应是碳资源利用的终结者,而是人类实现可持续发展必须善加利用的资源。文章在国内CO_2利用技术研发取得了可喜进展的基础上,提出了几种未来可能适合于中国的以CO_2规模化利用技术为核心的碳减排方案,包括化石能源耦合CO_2的转化利用技术、零碳能源耦合CO_2的转化利用技术以及温和条件下CO_2直接转化利用技术等。基于我国能源消费结构、短中期化石能源的主导地位以及可再生能源日新月异的发展,化石能源的易获取性和低成本使得其耦合CO_2的转化利用技术方案近年来飞速发展,并可能将在近期带来巨大碳减排潜力和经济效益;零碳能源发电技术的突飞猛进有利于核能/可再生能源发电耦合CO_2生产燃料化学品技术的发展,成为中期最具竞争力的CO_2大规模利用技术;远期来说太阳能驱动的CO_2温和转化可以实现真正意义上的生态碳循环,是远期最有前景的CO_2还原技术。