低硅Beta分子筛的合成研究

分两步法合成了低硅Beta分子筛,并以丙烯酸与异戊醇酯化反应作探针反应考察了低硅Beta分子筛的酸性能。结果表明：所合成的Beta分子筛具有独特的结构和酸性特征,反应温度140℃,反应时间2.5 h的条件下,丙烯酸的转化率可达76%。     

取代基酞菁铜的合成与表征

首先以3,6-二羟基邻苯二甲腈和氯代正丁烷为起始反应物,在无水碳酸钾的催化作用下,经亲核取代反应,在DMF（N,N-二甲基甲酰胺）溶剂中合成了中间配体3,6-二丁氧基邻苯二腈,再以此配体和氯化亚铜为前体,采用DBU液相催化法合成了周边烷氧基取代的1,4,8,11,15,18,22,25-八丁氧基酞菁铜,经过元素分析、红外、荧光、紫外可见光谱和原子吸收表征证明,产物就是目标化合物取代基酞菁铜。     

一种稠油输送油溶性降粘剂的合成与优化

介绍了稠油在运输中遇到流动性差的问题,分析了胶质与沥青质的存在对高粘度的影响。选取甲基丙烯酸十八酯、苯乙烯、丙烯酰胺、马来酸酐为单体,利用溶液聚合法进行反应聚合。通过调节单体的配比,确定10∶2∶3∶0.5为最佳比例。再加入表面活性剂与溶剂进行复配,提高降粘效果。60℃下,将质量分数为5×10-4的降粘剂加入八面河稠油中降粘率能够达到50%。     

小分子抗癌新药nutlin-3的合成新法研究

以4-甲氧基-2-羟基苯甲醛和对氯苯甲醛为原料,采用7步反应初步合成了小分子抗肿瘤药物nutlin-3,TLC检测每一步反应,总收率40%。对中间体和目标产物的结构和纯度进行了IR和1H NMR表征。     

固态合成硬脂酸十八醇酯的研究

在无溶剂状态下,以十八醇和硬脂酸为原料,以对甲苯磺酸(PTSA)为催化剂,微波协助合成了硬脂酸十八醇酯.利用正交实验法探究了酯化反应的各种影响,其影响因素的大小依次为D>A>C>B;其反应的最优条件:醇酸物质的量比(A)为1∶1.2,催化剂用量(B)为0.2 g,微波辐射功率(C)为514 W,微波辐射时间(D)为40 m in,产率可达94.35%.     

固体超强酸SO42-/ZrO2-Al2O3的制备及催化酯化反应性能研究

制备了固体超强酸SO42-/ZrO2-Al2O3,并将其作为催化剂应用于乙酸正丙酯的合成.结果表明,SO42-/ZrO2-Al2O3对乙酸正丙酯的合成有较好的催化活性,酯化率可以达到98%以上.     

Anisotropic fluoride nanocrystals modulated by facet-specific passivation and their disordered surfaces

Rutile-type fluorides have been proven to be active components in the context of emerging antiferr-omagnetic devices. However, controlled synthesis of low-dimensional, in particular two-dimensional (2D), fluorides in a predictable and deterministic manner remains unrealized because of a lack of efficient anisotropic control, which impedes their further development in reduced dimensions. We report here that altered passivation of {110} growing facets can direct the synthesis of rutile-type fluoride nanocrystals into well-defined zero-dimensional (0D) particulates, one-dimensional (1D) rods and 2D sheets in a colloidal approach. The obtained nanocrystals show positive exchange bias and enhanced magnetic transition temperature from the coexistence of long-range antiferromagnetic order and disordered surface spins, making them strong alternatives for flexible magnetic devices and sensors.     

一种基于特征编码的Word文档数字水印算法

本文基于文本数字水印的特征编码思想,通过设置Word文档中字符的下划线格式以嵌入和检测水印。实验表明,该算法有较强的不可见性,能较好的嵌入和检测水印,从而达到数字水印的一般要求。     

Leveraging microgrants to support capacity-building workshops in low- and middle-income countries for meeting the Sustainable Development Goals

Twenty fifteen marked the year of assessment for the Millennium Development Goals (MDGs). The MDGs that achieved the greatest success were those where evidence-based practice (EBP) interventions were implemented. The ability to practice evidence-based medicine is grounded in the creation of and access to medical literature that synthesizes research findings. The role that global health literature played in the success of the MDGs demonstrates that medical libraries and librarians have a role to play in achieving the Sustainable Development Goals (SDGs).Librarians can hold capacity-building workshops that provide instruction on how to access evidence-based literature and also train health professionals to conduct synthesis research. Research findings conducted by in-country health professionals are more likely to address issues being faced by local communities and will afford the possibility of obtaining the necessary evidence-based answers that can then be used to implement policies to resolve public health issues identified in the SDGs.This paper discusses how an international team of librarians leveraged funding from a Medical Library Association/Librarians without Borders/Elsevier Foundation/Research4Life grant to hold a capacity-building workshop in Zimbabwe and follow-up online trainings. The workshop focused on accessing evidence-based resources and conducting synthesis research. Outcomes included the creation and policy implementation of evidence-based knowledge products in alignment with local needs and galvanizing a multisectoral group of key individuals who have gone on to collaborate toward the vision of creating a Zimbabwe innovation hub. Looking ahead, such grants can be leveraged to conduct capacity-building to support knowledge translation and other local training needs.     

Playing with rules around routines: children making mealtimes meaningful and enjoyable

Children attending early childhood education and care centres spend a lot of time fitting in with institutional routines. This paper uses ethnographic methods and sociocultural activity theory to describe and analyse the processes whereby young children in an early childhood centre collectively created meaning and interest during potentially boring routine mealtimes. The research explores the relationship between rules and children's playful activity. Using their imaginations children negotiated and played with and within the rules around ‘eating‐together’ times. While physically constrained in chairs around tables children enjoyed the freedom of playing with word sounds and meanings. Children actively, collaboratively and at times subversively, created their peer community culture.