层状复合金属氧化物光催化材料的结构与光谱响应特征

由金属复合氧化物组成的层状材料,包括铌酸盐、钛酸盐、钛铌酸盐等,因其独特的结构和性质使其成为一种新型光催化材料而被广泛研究。通过调节层板组成、结构以及层间离子等可调变其光催化性能,通过插层（柱撑）、剥离组装等可形成丰富的光催化功能材料。本文就该方向的研究做一简要探讨,为进一步构建新型光催化材料提供参考。     

钾细菌的分离及对Cu^2＋的耐受性实验研究

利用分离培养基从草坪、芦苇地、公园以及菜园土壤中分离到一株高效钾细菌菌株,经纯化后,研究了钾细菌对铜的耐受阈值,并筛选了提高钾细菌Cu^2＋耐受阈的钝化剂。结果表明,钾细菌最高能耐受Cu^2＋的浓度为50mg/L。投加钝化剂粉煤灰和石灰后,钾细菌对Cu^2＋的耐受阈提高到80mg/L,粉煤灰对重金属铜的钝化性能优于石灰。     

Influence of casein phosphopeptide-amorphous calcium phosphate application,smear layer removal,and storage time on resin-dentin bonding

The aim of this study is to evaluate the influence of Tooth Mousse (TM) application, smear layer removal, and storage time on resin-dentin microtensile bond strength (μTBS). Dentin specimens were divided into two groups: (1) smear layer covered; (2) smear layer removed using 15% EDTA for 90 s. In each group, half the specimens were treated once with TM for 60 min. After bonding procedures using a two-step self-etching adhesive (Clearfil SE Bond (CSE); Kuraray Medical, Tokyo, Japan), an all-in-one adhesive (G-Bond (GB); GC Corp, Tokyo, Japan), and a total-etch adhesive (Adper Single Bond 2 (SB); 3M ESPE, St. Paul, MN, USA), the specimens were stored for 3 d or 6 months in deionized water at 37 °C, and μTBS was tested and analyzed. With the exception of SB (no TM application) and GB, the μTBS was significantly increased for CSE and SB using EDTA pre-conditioning and 3 d of storage (P≤0.001). Bond strength of GB decreased significantly when using EDTA (3 d storage, P<0.05). TM application only increased the μTBS of GB (no EDTA) and SB (with EDTA) after 3 d (P≤0.02). Comparing the adhesives after 3 d of storage, CSE exhibited the greatest μTBS values followed by GB and SB (P≤0.02). The factors of adhesive, EDTA, and TM did not show any significant impact on μTBS when specimens were stored for 6 months (P>0.05). The additional application of TM and EDTA for cavity preparation seems only to have a short-term effect, and no influence on μTBS of dentin bonds after a period of 6 months.     

SDS改性活性炭对铜离子的吸附研究

商品化活性炭(AC)经柠檬酸预处理,再用十二烷基硫酸钠(SDS)进行改性,将得到的改性活性炭(SDS-AC)用于铜离子的吸附,考察改性剂用量、吸附时间、p H、SDS-AC投加量对吸附效果的影响,同时研究SDS-AC吸附铜离子的吸附等温线。结果表明:0.3%的SDS改性剂量效果最佳,最大吸附量为38.7621 mg/g,约为AC吸附量的2.5倍;200 m L铜离子初始浓度为50 mg/L的溶液吸附性能最佳条件为SDS-AC投加量为0.200 0 g,p H值为5,吸附时间为60 min;Langmuir等温线更符合铜离子在SDS-AC中的吸附行为的描述。     

一维二元非金属型声子晶体禁带特性研究

选用非金属材料塑料和硅橡胶,组合成一维二元声子晶体匀直杆状结构。通过单一改变结构中非金属材料塑料的密度或者硅橡胶的密度,寻找单一材料密度变化与声子晶体杆禁带特性的关系。结果表明:当选取塑料密度为1190kg·m-3、硅橡胶密度为1300kg·m-3,晶格常数为0.3m,两种材料组份比相同时,一维二元非金属塑料/硅橡胶声子晶体存在低频禁带带隙,第1禁带起始频率为43.07Hz、禁带带宽为33.09Hz,第2禁带起始频率为99.84Hz,第2禁带带宽为52.49Hz;当单一改变塑料的密度,随着密度由小到大线性增加,结构第1带隙的起始频率由66.58Hz逐步减小到34.04Hz;第1带隙的截止频率为76.17Hz,保持不变,带隙宽度展宽;当单一改变材料硅橡胶的密度时,随着材料硅橡胶的密度由小到大线性增加,第1带隙的带宽由109.894HZ减小为18.3748Hz。对于一维二元非金属型声子晶体,选用密度更小的非金属材料与密度更大的非金属材料组合,更容易获得低频宽带带隙。另外,基于密度变化的同时还可以通过改变结构晶格常数的取值来获得更为理想的声子晶体禁带带隙。     

汽车驱动环稀土催渗强化研究

汽车驱动环通常采用渗碳淬火热处理强化,但往往由于其生产周期长,尺寸变形大,耐蚀及抗疲劳磨损性较差等问题,慢慢已无法适应用户生产需求。鉴于离子渗氮技术已经成功应用于汽车零部件上,为了帮助用户减少生产周期,减少生产成本,添加稀土催渗剂对驱动环强化工艺进行优化,最终证明改进工艺后的产品性能能够完全满足用户的使用需求。     

领域自适应大数据集浓缩方法

传统机器学习均假定测试域和训练域处于同一概率分布,但现实中往往因各种原因引起所采集到的样本数据可能存在扰动或噪音情况,导致概率密度估计不一定准确。为有效解决这一问题,提出一种新的领域自适应数据集概率密度估计（A-RSDE）算法。该算法可充分学习源域（训练域）概率密度分布知识,使目标域（测试域）概率密度估计更接近真实概率密度分布。实验证明,该算法具有有效性,且实现了数据浓缩的目的。     

平煤十三矿穿层钻孔抽采瓦斯浓度异常分析

针对突出煤层穿层钻孔抽采瓦斯浓度低的问题,从钻孔成孔过程的动力现象、成孔后孔口瓦斯流量、钻孔见煤长度和成孔后瓦斯抽采期间钻孔渗水等方面,分析了平煤十三矿己15.17-11111机巷底抽巷D12钻场附近和D23钻场附近,穿层钻孔抽采瓦斯浓度相差较大的原因;研究结果对改善穿层钻孔抽采瓦斯浓度效果,加快突出煤层的瓦斯治理具有借鉴作用。     

Cyclic-anion salt for high-voltage stable potassium-metal batteries

Electrolyte anions are critical for achieving high-voltage stable potassium-metal batteries (PMBs). However, the common anions cannot simultaneously prevent the formation of ‘dead K’ and the corrosion of Al current collector, resulting in poor cycling stability. Here, we demonstrate cyclic anion of hexafluoropropane-1,3-disulfonimide-based electrolytes that can mitigate the ‘dead K’ and remarkably enhance the high-voltage stability of PMBs. Particularly, even using low salt concentration (0.8 M) and additive-free carbonate-based electrolytes, the PMBs with a high-voltage polyanion cathode (4.4 V) also exhibit excellent cycling stability of 200 cycles with a good capacity retention of 83%. This noticeable electrochemical performance is due to the highly efficient passivation ability of the cyclic anions on both anode and cathode surfaces. This cyclic-anion-based electrolyte design strategy is also suitable for lithium and sodium-metal battery technologies.     

杂质对镁电解过程中的影响

对镁电解过程中的杂质,如SO42-、MgO、C、B等进行了研究,并对这 些杂质产生的各种影响做了论述.