PEO-PPO-PEO嵌段共聚物的聚集行为及其在胶团萃取中的应用

从分子水平研究了PEO-PPO-PEO嵌段共聚物聚集过程中分子基团微环境和构象的变化.FTIR光谱给出了温度、溶剂、嵌段共聚物组成等影响PEO-PPO-PEO嵌段共聚物胶团结构的定量信息。用无机盐和脂肪醇调控PEO-PPO-PEO嵌段共聚物聚集,荧光光谱技术提供了降低PPO链段与水的相互作用,推动嵌段共聚物在水中胶团化的证据。用水凝胶包埋PEO-PPO-PEO嵌段共聚物,实现了萃取水中低浓度多环芳烃的工艺循环。     

环戊基甲基酮连氮的合成及表征

以环戊基甲基酮和水合肼为原料,合成一种新的酮连氮化合物(环戊基甲基酮连氮,C14N2H24),采用1H NMR、13C NMR和IR表征确认产物的结构,并通过Gaussian 09计算对产物分子构型进行解析,表明(1E,2E)为最稳定构型;同时测定环戊基甲基酮连氮在常压下的基本物理化学性质,包括沸点(Tb,238.4℃...     

When Glass and Metal Corrode Together,VI: Chalconatronite

ABSTRACT

Chalconatronite, Na₂[Cu(CO₃)]₂·3H₂O, is formed as a corrosion product when copper alloys are exposed to sodium carbonate solutions in the air. This also happens when metals come into contact with corroding soda glass which forms alkaline surface films in reaction with humidity from clean air. More often, substantial amounts of formaldehyde are present indoors which react to formate via the Cannizzarro reaction and accumulate over time in the films. Twenty cases of chalconatronite (including two mentioned in the literature) are reported as occurring on heritage objects with glass in contact with copper alloys: Baroque reliquaries with set glass gems, enamel on metal (sixteenth century and a modern replica of intentionally unstable composition), Christmas tree glass baubles with wires, glass buttons with metal shanks, a glass figure with a wire support, miners’ lamps, and a glass framed daguerreotype. These confirmed identifications might help conservators in investigating similar cases to shed more light on the formation conditions.     

Near-infrared spectroscopy-derived total haemoglobin as an indicator of changes in muscle blood flow during exercise-induced hyperaemia

ABSTRACT

Blood flow changes in response to exercise have been attributed, among other factors, to the effect of vasodilators factors on the microvasculature, suggesting a close relationship between small blood vessels and conducting arteries. The main purpose of this study was to determine the relationship between the changes in near infrared spectroscopy (NIRS)-derived total haemoglobin ([tHb]) and muscle oxygen saturation (SmO₂) signals and femoral artery blood flow in response to resistance exercise at fast- and slow-velocity muscle contraction. The study randomised crossover design included twelve participants. NIRS and blood flow measurements were continuously monitored before, during, and 5 min after the exercise protocol. There was a significant correlation between [tHb] reperfusion slope ([tHb]_slope) and peak blood flow (BF_peak) after slow- and fast-velocity muscle contraction (r = 0.83, p = 0.0008 and r = 0.72, p = 0.0080, respectively). No significant correlation existed between the SmO₂ reperfusion slope (SmO_{2_slope}) and BF_peak after both slow- and fast-velocity muscle contraction exercise (r = ?0.46, p = 0.1253 and r = 0.33, p = 0.2841, respectively). This study demonstrated a strong relationship between the NIRS-derived [tHb] and Doppler ultrasound BF during the recovery period of dynamic resistance exercise at both slow- and fast-velocity contraction.     

FTIR Measurement of Cellulose Microfibril Angle in Historic Scots Pine Wood and Its Use to Detect Fungal Decay

Microfibril angle (MFA) – the orientation of cellulose fibres in the S2 layer of the secondary cell wall – is a key determinant of the stiffness and strength of timber. The microfibril angle depends on the way in which the timber was grown and its position within the tree. Microfibril angle can be measured by X-ray diffraction and other methods, but the methods in current use are slow or require advanced instrumentation. The aim of this study was to explore the use of polarised Fourier transform infrared (FTIR) microscopy as a relatively fast and inexpensive method for measuring MFA in historic Scots pine (Pinus sylvestris L.). The FTIR measurements were calibrated against X-ray measurements of MFA in modern Scots pine. We observed a wide range in MFA values and a radial pattern of MFA similar to modern Scots pine in undecayed Scots pine heartwood from sixteenth and seventeenth century beams in Scottish secular buildings. The density of the heartwood was also similar to modern plantation-grown Scots pine despite the much slower growth rate recorded in the ring widths of the historic timber. The sapwood, which had been attacked by both insect pests and fungi, showed an erratic reduction in density and a large increase in MFA compared to the modern material. The increased sapwood MFA was attributed to selective destruction of the S2 layer of the wood cell walls by fungal decay. Using MFA measurements in conjunction with density offers the possibility to estimate the mechanical properties of sound historic pine timber, to detect fungal decay more sensitively than by density alone, and to distinguish between pest and fungal attack in a way that relates directly to the remaining mechanical performance of the timber.     

When Glass and Metal Corrode Together,V: Sodium Copper Formate

A sodium copper formate, first described in 2002, can also form on copper alloys with sodium originating from soda glass hydrolysis. The frequent occurrence (50% of 250 cases of glass-induced metal corrosion) is due to the presence of formaldehyde emissions in storage and its direct reaction to formate in the alkaline surface films. The compound can be produced without the presence of acetate when chalconatronite or metal coupons immersed in soda solution are exposed to formaldehyde vapours. The crystal structure, derived from X-ray powder diffraction, yielded the sum formula Cu₄Na₄O(HCOO)₈(OH)₂·4H₂O. Except for the absence of acetate in the structure, this is in good agreement with the 2002 publication. To assess which kind of combined glass/metal objects are affected, a number of large museum collections were surveyed. Sodium copper formate was detected as a corrosion product using mainly micro-Raman spectroscopy, for instance, on 18 painted Limoges enamels, eight glass vessels with metal mountings, glass beads on metal wire from 11 bridal crowns, nine Christmas tree balls with wire decoration, 40 pieces of jewellery with glass gems, three daguerreotypes, and one miniature with cover glasses.     

光电探测系统的设计原理及应用

该文根据“非典”时期红外测温仪的应用，讨论了光电系统的设计思想和基本原理及应用。     

论二正（异）丙氧基-三嗪的合成

以三聚氯氰为起始原料合成了四种三嗪衍生物,并用红外光谱和质谱分析法对它们进行了表征.产品检测结果表明,四种三嗪衍生物有较高熔点,在常温下不易挥发.     

ATR-FTIR as a tool for assessing potential for chemical ageing in Spandex/Lycra®/elastane-based fabric collections

The Powerhouse Museum in Sydney, Australia houses the world's most significant and comprehensive collection of Speedo swimwear and accessories. The museum has identified a problem with the long-term storage of certain Spandex/Lycra^® items where the elastane fibre has degraded leading to oil formation. Attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) determined that most of these garments were manufactured using nylon-elastane fibres, and the elastane component comprises polyetherurethane or polyesterurethane polymers. Certain polyesterurethanes are known to be vulnerable to hydrolysis, and this was confirmed for a subset of the collection using two chemical testing protocols, and a thermal testing protocol that reproduced the oil formation. A polyetherurethane garment in the collection was unchanged by these tests. The oil from the thermal testing was confirmed as a breakdown product of the polyester component of the elastane fibre, using ATR-FTIR spectroscopy, X-ray photoelectron spectroscopy, and time-of-flight secondary ion mass spectrometry. The study demonstrates the value of ATR-FTIR for minimally invasive identification of elastane fabrics that may require specialized storage in a humidity-controlled environment.     

一种新兴的学科领域历史根源探究方法:RPYS

[目的/意义] 探索一个学科或研究领域的历史根源问题,找出对该学科领域起源具有重要作用的根源文献,对于学科的建设和研究具有重要意义。[方法/过程] 引入一种被称为“参考文献出版年图谱”（RPYS）的新方法,对其概念、特点和原理进行详细阐述,并将RPYS分析过程归纳为4个步骤。在此基础上,以健康信息素养研究领域为例,应用RPYS从参考文献的角度对该领域的历史根源文献进行识别和分析。[结果/结论] 结果表明,运用RPYS能够较为准确地揭示健康信息素养研究领域的历史根源文献,同时发现RPYS也可以用于学科或研究领域的研究热点、研究趋势的探究。