Experiments on Cu-isotope fractionation between chlorine-bearing fluid and silicate magma: implications for fluid exsolution and porphyry Cu deposits

Hydrothermal fluid is essential for transporting metals in the crust and mantle. To explore the potential of Cu isotopes as a tracer of hydrothermal-fluid activity, Cu-isotope fractionation factors between Cl-bearing aqueous fluids and silicate magmas (andesite, dacite, rhyolite dacite, rhyolite and haplogranite) were experimentally calibrated. Fluids containing 1.75–14 wt.% Cl were mixed together with rock powders in Au₉₅Cu₅ alloy capsules, which were equilibrated in cold-seal pressure vessels for 5–13 days at 800–850°C and 2 kbar. The elemental and Cu-isotopic compositions of the recovered aqueous fluid and solid phases were analyzed by (LA-) ICP–MS and multi-collector inductively coupled plasma mass spectrometry, respectively. Our experimental results show that the fluid phases are consistently enriched in heavy Cu isotope (⁶⁵Cu) relative to the coexisting silicates. The Cu-isotope fractionation factor (Δ⁶⁵Cu_FLUID-MELT) ranges from 0.08 ± 0.01‰ to 0.69 ± 0.02‰. The experimental results show that the Cu-isotopic fractionation factors between aqueous fluids and silicates strongly depend on the Cu speciation in the fluids (e.g. CuCl(H₂O), CuCl₂^– and CuCl₃²⁻) and silicate melts (CuO_1/2), suggesting that the exsolved fluids may have higher δ⁶⁵Cu than the residual magmas. Our results suggest the elevated δ⁶⁵Cu values in Cu-enriched rocks could be produced by addition of aqueous fluids exsolved from magmas. Together with previous studies on Cu isotopes in the brine and vapor phases of porphyry deposits, our results are helpful for better understanding Cu-mineralization processes.     

提升就业能力:缓解大学生就业难的重要选择

高等教育大众化条件下的大学生就业形势日趋严峻,缓解大学生就业结构性矛盾的难题需要不断增强毕业生的就业能力。合理调适专业、坚持特色育人、强化就业指导是现行教育体制下提升大学生就业能力的有效举措。     

液压泵零流量压力急增故障的分析与排除

针对液压泵在试验中成批出现零流量压力急剧增大的故障现象,从液压泵的工作原理出发对其进行分析,找到了故障原因,并采取了相应的措施,使故障有效排除,从根本上解决了生产中的疑难问题.     

基于多普勒频谱图的力量项目运动员左室舒张期室壁运动研究

通过测定和比较正常人和力量项目运动员在静息和逐级递增负荷运动时,室壁多普勒频谱图上E波和A波峰值速度,研究左室后壁主动松弛和被动充盈功能的变化。结果表明：在静息状态,力量项目组房缩期心房收缩对于左室舒张充盈的贡献小于正常组;在逐级递增负荷中,力量项目组心脏舒张功能的动员表现为同时动用主动舒张储备和左房收缩储备,显示出心脏主动舒张的能力强,左房收缩储备大。     

混凝土薄壁池体爆破方法研究

本文针对薄壁池体,从爆破工程实际出发以减小爆破公害、提高爆破效率为目的,提出适合薄壁池体的爆破新方法--"水土压爆破".通过分析论证、同常规方法的对比,可知新方法对于薄壁池体是爆破技术领域的一大进步.     

Mineralogy of the deep lower mantle in the presence of H2O

Understanding the mineralogy of the Earth''s interior is a prerequisite for unravelling the evolution and dynamics of our planet. Here, we conducted high pressure-temperature experiments mimicking the conditions of the deep lower mantle (DLM, 1800–2890 km in depth) and observed surprising mineralogical transformations in the presence of water. Ferropericlase, (Mg, Fe)O, which is the most abundant oxide mineral in Earth, reacts with H₂O to form a previously unknown (Mg, Fe)O₂H_x (x ≤ 1) phase. The (Mg, Fe)O₂H_x has a pyrite structure and it coexists with the dominant silicate phases, bridgmanite and post-perovskite. Depending on Mg content and geotherm temperatures, the transformation may occur at 1800 km for (Mg_0.6Fe_0.4)O or beyond 2300 km for (Mg_0.7Fe_0.3)O. The (Mg, Fe)O₂H_x is an oxygen excess phase that stores an excessive amount of oxygen beyond the charge balance of maximum cation valences (Mg²⁺, Fe³⁺ and H⁺). This important phase has a number of far-reaching implications including extreme redox inhomogeneity, deep-oxygen reservoirs in the DLM and an internal source for modulating oxygen in the atmosphere.     

肱动脉血压相关因素的研究

利用20天的时间,每天10:00到15:00随机抽查,测量本校1000名大学生(男女生各500人)左右侧肱动脉血压的差异性;测量江苏省徐州市醒狮居民小区居民500名(男女各250人),年龄在20至69岁之间,探究血压与年龄和性别之间的关系。在大学生组中,将测量所得的结果通过χ2检验,u检验,其p值均大于0.05;典型相关分析检验中,相关系数约为1,说明大学生左右肱动脉血压无显著差异。在居民组中,运用matlab 7.0对数据进行拟合,结果显示随年龄的增长,舒张压、收缩压均逐渐升高,且收缩压的增长要大于舒张压的增长,男性的脉压整体高于女性,大约在45岁之后,双方差异逐渐减小。     

新课程实施中的教师压力及其管理策略

在新课程实施过程中,课程理念的更新、教师角色的转换、教学范式的变革,给教师带来了前所未有的压力。持续不断的压力往往会引起教师心理上的过度紧张与焦虑,进而影响新课程的实施。因此,要对新课程实施中的教师压力给予充分的关注,并采取适当策略对其进行有效的管理,以真正实现教师与课程改革的共同成长。     

一种可以实现稳定单细胞包裹的无进样器的微流控平台

液滴单细胞包裹技术是实现单细胞研究的有效方法。采用负压作为驱动力包裹单细胞,不再需要常规实验中会引起细胞吸附和降低单细胞包裹率的进样器和管路。在细胞悬浮溶液中加入碘克沙醇溶液调整溶液密度,进一步改善细胞沉降问题。研究负压大小和T型沟道几何尺寸对液滴频率和体积的影响以及碘克沙醇调整溶液密度后对单细胞包裹率的影响。该微流控平台可实现稳定的单细胞包裹,并为单细胞分析提供有利工具。     

4周下肢间歇负压干预对优秀赛艇运动员心率变异性和儿茶酚胺的影响

目的探讨下肢间歇负压干预对赛艇运动员心率变异性(HRV)相关指标和儿茶酚胺的影响。方法将国家赛艇队的14名运动员分为试验组和对照组,试验组运动员每周用间歇负压干预5 d,持续4周,对照组无其他干预方式。试验期间均对2组运动员进行HRV相关指标和儿茶酚胺的测试。结果试验前2组运动员各指标均无统计学差异。开始干预后2组的变化如下:①在时域指标中,试验组正常窦性R-R间期标准差(SDNN)在第3周时高于对照组(P<0.05)。②在频域指标中,试验组高频(HF)值在第2周和第3周时高于对照组(P<0.05),而其高频与低频比(LF/HF)在第1、3和4周时低于对照组(P<0.05)。③2组儿茶酚胺组内、组间比较均无统计学差异,但试验组儿茶酚胺下降程度比对照组高。结论4周的间歇负压干预对运动员自主神经系统功能的恢复有明显促进作用,对儿茶酚胺的分泌也具有抑制趋势;这有利于降低运动员心脏负荷,促进运动后的生理恢复。