ATR-FTIR as a tool for assessing potential for chemical ageing in Spandex/Lycra®/elastane-based fabric collections

The Powerhouse Museum in Sydney, Australia houses the world's most significant and comprehensive collection of Speedo swimwear and accessories. The museum has identified a problem with the long-term storage of certain Spandex/Lycra^® items where the elastane fibre has degraded leading to oil formation. Attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) determined that most of these garments were manufactured using nylon-elastane fibres, and the elastane component comprises polyetherurethane or polyesterurethane polymers. Certain polyesterurethanes are known to be vulnerable to hydrolysis, and this was confirmed for a subset of the collection using two chemical testing protocols, and a thermal testing protocol that reproduced the oil formation. A polyetherurethane garment in the collection was unchanged by these tests. The oil from the thermal testing was confirmed as a breakdown product of the polyester component of the elastane fibre, using ATR-FTIR spectroscopy, X-ray photoelectron spectroscopy, and time-of-flight secondary ion mass spectrometry. The study demonstrates the value of ATR-FTIR for minimally invasive identification of elastane fabrics that may require specialized storage in a humidity-controlled environment.     

低应变法检测缺陷模拟桩试验研究

低应变法广泛应用于桩身完整性检测,但各类具体缺陷引起的波阻抗变化存在很大模糊性,而波阻抗又是响应曲线波形的主要影响因素,从而使时程曲线的正确判读存在难度很大难度。以五种模拟桩所代表的具体缺陷特征对响应时程曲线的影响分析的基础上,总结相应的各种缺陷特征的低应变法检测判读技巧,具有一定的参考价值。     

一种新兴的学科领域历史根源探究方法:RPYS

[目的/意义] 探索一个学科或研究领域的历史根源问题,找出对该学科领域起源具有重要作用的根源文献,对于学科的建设和研究具有重要意义。[方法/过程] 引入一种被称为“参考文献出版年图谱”（RPYS）的新方法,对其概念、特点和原理进行详细阐述,并将RPYS分析过程归纳为4个步骤。在此基础上,以健康信息素养研究领域为例,应用RPYS从参考文献的角度对该领域的历史根源文献进行识别和分析。[结果/结论] 结果表明,运用RPYS能够较为准确地揭示健康信息素养研究领域的历史根源文献,同时发现RPYS也可以用于学科或研究领域的研究热点、研究趋势的探究。     

双锥体天线输入阻抗的计算

求解大锥角双锥体天线的输入阻抗,综合阻抗和增益两方面的因素可以确定θ0=45°角的双锥体天线其宽带特性最好．因此,本文着重针对θ0=45°角双锥体天线展开研究,利用计算机求出其输入阻抗的一级近似并画出阻抗特性和输入阻抗的函数图．     

芦丁在碳糊电极上的电化学行为

文章研究了芦丁在碳糊电极上的电化学行为.实验结果表明,芦丁在碳糊电极上的电极过程为一受扩散控制的两电子、两质子参与的准可逆过程.芦丁的氧化峰电流与芦丁浓度的平方根在1-100 mg/L范围内呈良好的线性关系.将该方法用于芦丁片中芦丁含量测定,结果满意.     

电化学腐蚀法制备扫描隧道显微镜针尖曲率半径最佳参数的研究

研究了电化学腐蚀法制备扫描隧道显微镜钨针尖过程中,腐蚀电压、浸入深度、偏离角度、溶液浓度、切断时间对针尖曲率半径的影响,结果表明当电压V=9.5V的情况下,浸入深度在1.5-2mm范围内,偏离角度〈1°,溶液浓度在2mol/L,切断时间在500m s以下,腐蚀后得到的钨针尖的曲率半径达到最佳值.     

基于LIBS技术铁等离子体电子温度和电子密度的研究

将1 064纳米脉冲Nd：YAG激光器聚焦于铁条表面产生等离子体.利用10条铁原子谱线做出Boltzmann图并求得等离子体的电子温度是6 474 K,同时利于铁原子谱线382.78纳米的Stark展宽求得等离子体的电子密度是2.7×1017cm-3.基于实验结果证明本实验的铁等离子体满足局部热力学平衡.     

无水溶胶凝胶法制备LiFe_（1-x）Co_xPO_4/C正极材料及其性能研究

在无水溶胶凝胶法基础上,以Fe3＋盐为铁源,添加聚乙二醇-400作为表面活性剂,制备了掺杂钴的LiFePO4/C正极材料（LiFe1-xCoxPO4/C,x=0,0.05,0.1）。并通过XRD、SEM、恒流充放电等方法研究了不同钴掺杂量对LiFePO4/C结构、形貌和电化学性能的影响。     

应用化学专业电化学应用核心课程体系构建与实践

以应用型人才培养为指向,结合专业定位和企业实际需要,构建适用、实用电化学应用课程体系;同时,建立以学生为主体的教学模式,以能力培养为导向的教学实践模式,发挥电化学应用核心课程体系对人才培养的重要作用.     

Electricity generation and brewery wastewater treatment from sequential anode-cathode microbial fuel cell

A sequential anode-cathode double-chamber microbial fuel cell (MFC), in which the effluent of anode chamber was used as a continuous feed for an aerated cathode chamber, was constructed in this experiment to investigate the performance of brewery wastewater treatment in conjugation with electricity generation. Carbon fiber was used as anode and plain carbon felt with biofilm as cathode. When hydraulic retention time (HRT) was 14.7 h, a relatively high chemical oxygen demand (COD) removal efficiency of 91.7%–95.7% was achieved under long-term stable operation. The MFC displayed an open circuit voltage of 0.434 V and a maximum power density of 830 mW/m3 at an external resistance of 300 ?. To estimate the electrochemical performance of the MFC, electrochemical measurements were carried out and showed that polarization resistance of anode was the major limiting factor in the MFC. Since a high COD removal efficiency was achieved, we conclude that the sequential anode-cathode MFC constructed with bio-cathode in this experiment could provide a new approach for brewery wastewater treatment.