体质指数法、皮褶厚度法和生物电阻抗法判断青少年超重、肥胖的一致性

运用体质指数法、皮褶厚度法及生物电阻抗法,判断上海城区儿童青少年超重、肥胖发生率及其一致性。结果显示:3种方法在判断不同年龄、性别儿童青少年超重、肥胖上一致性较低;测量原理与精确性不同,青少年儿童体成分化学组成不成熟及诊断、筛查标准的差异可能是3种方法一致性较低的原因。提出应建立适合我国儿童青少年"多维模型"假设下的体脂率预测方程。     

中药白芍水萃取液的吸收光谱研究

从实验和理论上研究了中药白芍水萃取液在紫外光激励下的吸收光谱及其特性。研究结果表明,白芍水萃取液在275 nm处有一个明显的特征吸收峰。分析了其产生的机理,发现其最大吸光度与白芍水萃取液的体积分数之间存在良好的线性关系,为检测白芍有效成分含量提供了一种有效的方法。     

TBZ在MWCNT—DHP膜修饰电极上的电化学分析研究

在pH：2．0的B—R（Britton—Robinson）的缓冲溶液中,对制备的多壁碳纳米管,双十六烷基磷酸（MwcNT—D船）膜修饰电极进行了循环伏安法（CV）表征;分别研究了涕必灵（1BZ）在裸玻碳电极（GcE）和MWCNT—DHP膜修饰电极上的电化学行为,采用微分脉冲伏安法（DTV）,以MWCNT—DHP膜修饰电极为工作电极,建立了一个简单、快速、灵敏的涕必灵电化学分析检测体系;并结合固相萃取技术,测定了环境水中涕必灵含量,检测限达到2．0×10-8mol·L-1,平均回收率为97．28％-99．40％,RSD为1．3％～2．8％（n=6）。     

耦合谐振腔滤波器灵敏度的快速分析方法

针对传统蒙特卡罗法分析耦合谐振腔滤波器灵敏度耗时太长的问题,提出了一种基于理论梯度公式的快速灵敏度分析方法．文章详细推导了滤波器散射参数对终端阻抗和耦合系数的灵敏度解析表达式,并采用MATLAB编程实现了基于灵敏度表达式的数值算法．应用该算法对5阶交叉耦合谐振腔滤波器的灵敏度进行了分析,灵敏度分析结果对耦合谐振腔滤波器的设计和加工具有参考价值．     

锂离子电池石墨烯负极材料的制备与电化学性能

以天然石墨为原料,采用Hummers法制备氧化石墨烯,在硼氢化钠为还原剂制备石墨烯材料。采用XRD、电化学阻抗谱技术（EIS）、电化学充放电测试和红外分析等方法表征了石墨烯的结构和电化学性能。结果表明,石墨烯首次放电容量为866．4mAhg^-1,首次充电容量为305．2mAhg^-1,库仑效率为35．2％。     

Nineteenth century chrome yellow and chrome deep from Winsor & NewtonTM

The Winsor & Newton^TM (W&N) nineteenth century archive database includes digitised images of hand-written instructions and workshop notes for the manufacture of their artists’ materials. For the first time, all 183 production records for yellow lead chromate pigments were studied and evaluated. They revealed that W&N produced essentially three pigment types: lemon/pale based on mixed crystals of lead chromate and lead sulphate [Pb(Cr,S)O₄]; middle on pure monoclinic lead chromate [PbCrO₄]; and deep that contains the latter admixed with basic lead chromate [Pb₂CrO₅]; accounting for 53, 22, and 21% of the production, respectively. Production records for primrose (4%) were also included since the formulation results in mixed crystals with a high percentage of lead sulphate, which, according to the literature, leaves it more prone to degradation. Each pigment type is characterised by only one or two main synthetic pathways; process variations reveal a systematic and thorough search for a high-quality durable product. A comparison of the chemical composition of pigment reconstructions with early W&N oil paint tubes showed that their records entitled ‘pale’ and ‘lemon’ correlated with the pigment in their tube labelled chrome yellow and, ‘middle’ and ‘deep’ with the label chrome deep. Lemon and middle pigment formulations were made into oil paints to assess their relative photo-stability. The degradation process was followed by colorimetry and was studied by synchrotron radiation-based techniques. Based on the X-ray absorption spectroscopy data, the possibility for creating a stability index for chrome yellows is discussed.     

电化学法测定西维因水解速率参数

使用现代电化学分析方法,通过监测水解产物的生成情况,研究了本身无电化学活性的西维因(甲萘威)在水中的水解情况,在pH=7.0的BR缓冲液环境中西维因水解产物检测的灵敏度最高.考察了环境酸度以及环境温度对水解的影响,并测定了不同条件下的水解速率常数.发现西维因的水解过程符合一级反应方程,其水解受pH值、温度的影响.在酸性介质中西维因仍有一定的水解,但是水解的速率明显低于碱性介质中的水解速率.同时,环境温度也会影响水解速率,在较高温度下,不论环境酸度值为碱性或者酸性,西维因的水解速率均有所升高.     

Matlab/Simulink based dynamic simulation system for distance protection

To observe the inner operating process of distance protection, a Matlab/Simulink based dynamic simulation system for microprocessor-based distance protection is designed in this pa- per. As a modularized design, the simulation system is composed of several modules such as fault transient calculation, startup, Fourier algorithm, phase selection, impedance computing and im- pedance comparison etc. Some typical simulation cases, which focus on the main factors affect- ing distance relay's operation, have been simulated with the system. Simulation results show that the system is able to demonstrate the dynamic behaviors of distance protection under different op- erating conditions.     

能源革命中的电化学储能技术

储能技术在可再生能源并网及微电网、电网调峰提效、区域供能、电动汽车等应用中发挥着关键作用,是保障能源安全,落实节能减排,推动全社会绿色低碳发展的重大战略需求,对切实推进能源革命具有不可替代的作用。文章重点介绍具有重要市场前景的电化学储能技术,包括液流电池、锂离子电池、铅炭电池、钠基电池技术,并在分析电化学储能技术发展现状的基础上,阐述中国相关领域未来的发展战略。     

胱氨酸与烟草多酚氧化酶作用机理的探讨

通过酶活性测定和紫外-可见光谱研究了胱氨酸对烟草多酚氧化酶（简称PPO）活性的影响．结果表明，胱氨酸对烟草多酚氧化酶有抑制作用，其机制是胱氨酸中的硫醚与烟草多酚氧化酶活性中心的铜离子配位，但底物或产物抑制胱氨酸与多酚氧化酶的结合；胱氨酸还可以与酶促反应产物结合生成无色复合物．胱氨酸抑制烟草PPO的过程可分为两步：首先胱氨酸与烟草PPO结合生成中间产物，中间产物仍具有一定的酶活性；然后中间产物结构进一步发生变化，成为无活性的形式．