氯化银沉淀提取金属银方法探讨

利用碳酸盐与氯化银在高温下作用生成碳酸银 ,碳酸银分解得到金属银 ,从而提取回收含银废液中的金属银 .     

Environmentally-induced stone decay: the cumulative effects of crystallization–hydration cycles on a Lincolnshire oopelsparite limestone

An investigation has been undertaken at St Andrew’s church, Walpole St Andrew, Norfolk, to establish the underlying causes of the observed stone decay to the upper parts of the six stone piers. The stone decay was first recorded in the early 1930s. The salt-contaminated masonry within the church has been shown to undergo severe salt decay during the summer, with little damage occurring over the winter months. The south aisle piers have been shown to decay 2.5 times faster than the north aisle piers. Although crystallization–hydration cycles have been identified, the rate of decay is at its greatest when the cycling is relatively infrequent. This was not the expected trend. Furthermore, it has been shown that during extended periods where the ambient relative humidity is less than 75%, the rate of decay reaches a maximum. It is the length of this ‘drying’ period that apparently has the greatest influence on the rate of decay and could explain the significant difference in the rate of decay between the south and north aisle piers. The results have serious implications for passive conservation, where it is often recommended to lower the ambient relative humidity to well below the equilibrium relative humidity of the salt contaminant, to avoid crystallization–hydration cycles. Since, at the time of building, the church was situated on the coast, it is possible that the sodium chloride contamination occurred during the building process (1440–1520), particularly since the area was prone to sea-flooding at this time. Alternatively, the salt could have been applied as a treatment during the general restoration of 1897. Whatever the source of the salt, it seems likely that the ambient environment was changed by the insertion of a sealed floor in 1897, which could account for the onset of the salt decay.     

水杨酸铁的流变相合成和红外光谱

用流变相反应法合成了水杨酸铁配合物，对样品在4000—400cm^-1。范围内的主要红外光谱吸收峰进行了归属，通过元素分析、TG和IR确定该配合物的组成为Fe(HSal)3．3H2O(HSal=O-OHC6H4CO2)。     

用正交试验选择FA-Ⅱ氯酸钠电解槽最佳工艺条件

本文探讨了在FA-Ⅱ氯酸钠电解槽中,电解氯化钠溶液制备氯酸钠的适宜工艺条件.采用正交试验方法,考察了电流密度、电解液PH值、电解温度、氯化钠含量等对电解电耗的影响,确定了FA-Ⅱ电解槽最佳工艺条件.     

SnCl_2溶液的配制及反常现象的探讨

本文探讨了S_nCl_2溶液的配制方法和配制过程中所出现的问题及S_nCl_2溶液性质的一些反常现象。     

氯化锶[^89Sr]治疗肿瘤骨转移疼痛的护理

总结了23例氯化锶[^89Sr]注射液治疗肿瘤骨转移的护理。23例患者经ECT骨扫描检查证实骨转移病灶为单处和多处不等,主要临床表现为玩固性骨疼痛,活动能力受限。给予氯化锶[^89Sr]注射治疗,并采取以下护理措施：注射前疼痛评估,注射前心理护理,治疗后跟踪随访,不良反应的观察及应对护理等。     

EDTA配位滴定法测定热处理盐浴中的氯化钡

研究了用EDTA配位滴定法,结合反滴定方式测定NaCl-BaCl2混合盐中的BaCl2时的相关问题.对照试验的结果表明,该方法测定BaCl2的结果准确、可靠.     

聚合氯化铝铁(PAFC)处理电镀废水的研究

采用PAFC处理电镀废水并与聚合氯化铝(PAC)和聚合氯化铁(PFC)处理效果进行对比实验,结果表明,PAFC兼有PAC和PFC的优点,形成的絮凝体大而实且沉降速度快。其除水色度比PFC好,除浊效果和絮凝体沉降性能又优于PAC。PAFC可以显著提高去除电镀废液色度的絮凝效果,可以提高Cr6 的去除率,且用量少,适用的pH范围也更广。     

Fe^3＋掺杂TiO2可见光催化降解酸性红的研究

研究了在可见光条件下,用实验室合成的Fe3＋掺杂TiO2为催化剂催化降解酸性红染料,重点考察了Fe3＋的掺杂量、Fe3＋掺杂TiO2为催化剂的添加量、酸性红溶液的初始浓度、溶液pH值、光照时间对降解率的影响.实验结果表明,Fe3＋掺杂比为1.5%、催化剂用量为1.5 g/L、pH为2.0、质量浓度为40 mg/L的酸性红100 mL,用白炽灯光照降解酸性红30 min,酸性红降解率可达98.45%.     

微波辐射相转移催化合成对羟基苯甲酸杉酯的研究

以对羟基苯甲酸和氯化苄等为原料,以十六烷基溴化铵为相转移催化剂合成对羟基苯甲酸苄酯。通过实验考察了催化剂用量及物料配比等因素对酯化反应的影响。结果表明:微波辐射功率350W,辐射时间3min,n(对羟基苯甲酸)∶n(氯化苄)=1∶2,n(正十六烷基三甲基溴化铵)∶n(对羟基苯甲酸)=0.025,产率可达96.7%。