溴化（E）-1,1′-（六烷-1,6-二甲氨基）二（4-（E）-2-（噻吩基）乙烯基吡啶的合成、表征及光电性质的研究

合成和表征了一个新的吡啶衍生物溴化（E）-1,1′-（六烷-1,6-二甲氨基）二（4-（E）-2-（噻吩基）乙烯基吡啶,这是一种自组装膜合成的中间配体,具有特殊的结构特征和氧化还原性,以其为配体继续合成自组装膜材料,在共价和静电自组装膜研究的领域有很高的研究价值,本文对它的合成、表征及其紫外可见光谱和荧光光谱等的性质作一研究。     

一种基于能量谱葡萄糖浓度检测新方法的研究

葡萄糖浓度检测在治疗糖尿病过程中起着重要作用,采用近红外光谱方法测量葡萄糖浓度是国内外研究的热点．通过实验的方法,用800nm到1600nm的近红外光照射葡萄糖水溶液,对不同葡萄糖浓度对应的能量谱进行分析,发现在1111nm处的吸收峰特征比较明显,与葡萄糖浓度有着对应的关系,通过指数曲线拟合,建立葡萄糖浓度检测的数学模型．     

部分覆盖被动约束层阻尼板的动力特性分析

由薄板的基本方程出发,考虑粘弹性层与基板、约束层间的法向和切向相互作用力的影响,导出部分带状覆盖被动约束层阻尼（Passive Constrained Layer Damping,PCLD）板在两端简支另两端任意边界情况下的一阶常微分矩阵方程,方程的状态向量由4个独立的位移变量和内力变量组成,可方便地应用于位移和应力边界条件。同时,利用精细积分法和传递矩阵原理求解特征方程,计算了多种情况下PCLD板的固有频率和损耗因子。通过与参考文献结果相比,验证了本文方法的正确性。最后,分析了覆盖位置和覆盖率对结构减振特性的影响。     

无线传感器网络节点的物理层设计

比较和分析了无线传感器网络节点物理层设计的各种无线通信技术、现有的成熟标准、重要的射频参数以及不同的处理器方案,对节点物理层设计的各个主要方面进行了较为全面的研究.介绍了无线传感器网络节点的一种实现,给出了相关的测试数据以及一种“单处理器双工作频率”的新节能策略.分析了符合传感器网络MAC算法中节点周期性侦听要求的节点寿命估算问题.指出无线传感器网络节点物理层设计的关键考虑因素为:RF启动时间(决定MAC协议可以实现的最佳节点睡眠时间比例和最小的退避时间颗粒)、RF载波频率和调制方式(决定射频收发功耗)以及处理器工作在2个频率的片上系统的总体功耗.     

最优二叉树在通信编码中的应用

字符出现的频率不同,在传输中采用非等长二进制编码传输会提高传输效率,在字符的出现频率已知前提下,采用最优二又正则树算法,可以得到最佳前缀码.     

Unexpected changes of itinerary – adaptive functioning difficulties in daily transitions for adults with autism spectrum disorder

Adaptive functioning skills, also known as adaptive behaviours, refer to a multifaceted concept defined as behaviours necessary for age-appropriate, independent functioning in social, communication, daily living or motor areas. In light of the growing population of children with ASD who will eventually become adults, increased understanding of adaptive functioning during the transition to adulthood is of importance, but current research in this area lacks first-hand evidence presenting adaptive skills difficulties among older adolescents and adults with ASD. This article focuses on adaptive functioning skills in daily transitions for adults with Asperger’s syndrome (AS) or high-functioning autism (HFA). It draws on evidence from 12 interviews with individuals on the autism spectrum age 16–43, and 2 focus groups with 8 family members of people affected by ASD. Particular emphasis is placed on impact of adaptive functioning difficulties on well-being and quality of life for adults with ASD. Grounded theory approach has been used to analyse the gathered data. Interviewees reflected on daily challenges associated with unexpected changes in routine, sensory difficulties and social interactions. These in turn had an impact on their adaptive functioning skills by introducing complications in the process of making transitions between different contexts and decreasing interviewees’ ability to tackle challenges of daily life. Importance placed on societal expectations towards meeting bespoken standards and conforming to norms ruling the structure and interactions of daily life were also widely discussed. Frequently such expectations did not allow for factoring in the developmental nature of ASD and related difficulties, which as a result triggered additional complexity in managing daily transitions for adults on the spectrum. Further research addressing adaptive functioning skills in daily transitions for adults with ASD is needed.     

Infrared Absorption Spectra of Serpentine Cat＇s Eye from Sichuan Province of China

Infrared （IR） absorption spectra and X-ray powder diffraction （XRD） patterrns of sexpenfine cat＇s eye from Sichuan Province have been investigated, and infrared absorption bands of the serpentine have been assigned in this paper. The results indicate that the bands near 3 600 - 3 700 cm^-1 belong to the stretching absorption band VOH, the bands in 948 - 1 100 cm^-1 axe assigned to the stretching vibraling band Usvo, and the bands at 600 570 and 440 cm^-1 respectively belong to the bending vibration band VOH, δMg-O and δSi-O. The serpentine cat＇ s eye includes two types： chrysotile and antigorite. Chrysotile has a sharp and intensive band at 3 688 cm^-1 and a weak band at 3 643 cm^-1 , while antigorite has only one intensive band in the region. At vibration band VSi-O, chrysotile and antigorite have a similar feature at 1 071 cm^-1, but the band at 980 cm^-1 in anfigorite has been split into two bands in chrysotile - a strong one at 1 027 cm^-1 and a weak one at 949 cm^-1. In addition, antigorite has a characteristic bending vibrating band δMg-O at 570 cm^-1. Based on the analysis of the feature of crystal structure, their IR differences axe well explained.     

1016名学生PTC尝味能力基因频率的调查

目的:了解味盲基因频率和基因型频率在不同群体中的分布,从而为人种学及人类群体遗传学提供基本数据,并用于研究某些疾病。方法:本文是运用阈值法研究满、汉、回三民族人的尝味能力,并计算了味盲者和尝味者的基因频率。结果:三民族味盲基因频率分别为:满族:0.4588.汉族:0.2845 回族:0.4431。结论:满、汉、回三民族人对PTC尝味能力在统计学上存在显著差异,不同的民族有不同的基因库。     

普尔泰诱发蚕豆根尖细胞微核的研究

在农药普尔泰的正常使用浓度范围内，用不同浓度的普尔泰分别处理蚕豆根尖细胞4h和8h，监测其细胞微核诱变情况。结果表明，普尔泰对蚕豆根尖细胞微核的诱变，随着处理液浓度的增加、处理时间自延长，具有良好的剂量效应关系。用蒸馏水作对照处理，经t检验，差异极显著，说明普尔泰对蚕豆根尖细胞有明显的诱变作用。     

聚偏氟乙烯与无规-聚甲基丙烯酸甲酯相容性的研究

本文证明了PVDF与at-PMMA共混物中两者之间非常弱的相互作用 .随着PVDF质量分数的提高 ,共混物显示出更为异相的性质 .通过红外光谱的示差扫描技术 ,减去共混物谱图中PVDF和at-PMMA的谱图 ,显示在高PVDF含量时 ,υc=o吸收峰向低波数移动 ,表明它们之间的相互作用存在于PMMA的羰基和PVDF的H原子之间 .接触角测量表明随着PVDF含量的提高 ,膜的憎水性增强 .当PVDF的含量超过 30 % (质量 % )时 ,对水的接触角大于 90° ,显示了优异的憎水性 .但是 ,膜可以被正己烷完全润湿 ,因而对正己烷的接触角测量不到