配合物{[Ni（bpe）（Hmtyaa）2（H2O）2]}n的合成和晶体结构

文章用2-（5-甲基-1,3,4-噻二唑）-硫乙酸配体和1,2-顺（4-吡啶）乙烷配体用水热法合成了一个镍配合物{[Ni（bpe）（Hmtyaa）：（H：0）：]}lq（1）（Hmtyaa=2-（5-甲基-1,3,4-噻二唑）-硫乙酸;bpe=1,2-顺（4-吡啶）乙烷,用X-射线单晶衍射仪测定了配合物的单晶结构,并对它进行了元素分析、红外光谱、热重和粉末X-射线衍射表征．配合物1属于单斜晶系C2／c空间群．X-射线单晶结构分析表明配合物1中镍原子采取六配位扭曲的八面体配位模式．bpe配体采取双齿桥连模式将临近的镍原子连接成一维链状结构,在配合物1中配位水与羧基氧以及配体中的氮原子之间的氢键作用将链状结构连成三维网状结构．     

Closed Loop Recycling of Chlorine for Sustainable Development of Polyurethane Industry

Increasing demand is fueling the booming polyurethane industry worldwide. An impeding issue for polyurethane industry is how to handle the large quantity of hydrogen chloride byproduct generated from the synthesis of intermediates, i.e., isocyanates. In the meantime, the traditional chloro-alkaline process suffers both from the high energy intensity of electrolysis method and the disparity in the chlorine and caustic soda market. To solve these problems, the state-of-the-art chlorine recycling technologies are reviewed and compared. Approaches for cost-effective utilization of chlorine in polyurethane industry are investigated. Chinese academies and enterprises’ on-going effort on the development of a novel hydrogen chloride oxidation process for the synthesis of chlorine is presented. With this process, the closed loop recycling of chlorine can be realized. Tremendous economic, environmental and social benefits can be expected. A wide adoption of this technology will significantly advance the sustainable development of polyurethane industry.     

测定硫铁矿中Pb、Zn含量的一种好方法

改进试样的溶样方法 ,用原子吸收分光光度法测定硫铁矿中铅、锌的含量 ,稳定性、重现性好 .     

In的掺杂对化学水浴沉积SnS薄膜电阻率的影响

SnS and SnS：In films were deposited onto glass substrates by chemical bath technique. The structure and surface morphology of the SnS：In films were studied by X-ray diffraction （XRD） and scanning electron microscope （SEM） respectively. Energy dispersive spectroscopy （EDS） showed the existence of In in the films. The undoped SnS film exhibited a rather high resistivity and InCl3 could reduce the resistivity of these films by two orders approximately. The band gaps of the SnS and SnS：In films were evaluated from the optical transmission spectra.     

硫酸氢钠催化合成丁酸戊酯

以正丁酸和戊醇为原料，硫酸氢钠为催化剂合成了丁酸戊酯．最佳合成条件：以0．1mol正丁酸为基准，醇酸摩尔比为1．2：1，催化剂用量0．2克，甲苯5毫升，反应时间30min，丁酸的酯化率可达99．3％，在无甲苯存在下，合成食品级丁酸戊酯，酯化率可达99．7％．     

A new electrochemical oscillatory system of bromate in alkaline solution

A new electrochemical oscillatory system of bromate in alkaline solution is reported.In Pt-Bromate-Alkaline solution system,two different types of electrochemical oscillations(Type Ⅰ and Type Ⅱ) can be observed.Type Ⅰ appears before hydrogen evolution and Type Ⅱ involves periodic hydrogen evolution.Type Ⅰ relates to the adsorption/desorption of the hydrogen on platinum electrode,and Type Ⅱ with periodic oscillation stems from the coupling of electrochemical reactions(the reduction of bromate and evolution hydrogen reaction) with mass transfer(diffusion and convection).More over,under the right conditions,the two types appear in different oscillatory modes,for example,simple periodical mode and mixed one,etc..Crossed cycle in the cyclic voltammograms,which is the basic characteristics for electrochemical oscillatory systems,has also been observed as expected.     

金属铜颜色的实验论证

铜是人类发现最早且广泛使用的金属之一，其颜色问题至今多有争议，一直不得定论，通过改进的氢气还原氧化铜的实验结果，论证了铜的确是一种黄色金属这一事实。     

氢分子离子HD+的薛定方程的求解方法

从实验室坐标系下的氢分子离子与原子核之间的相互作用,讨论异核和同核氢分子离子HD^＋的薛定谔方程的Born-Oppenheimer近似求解方法和绝热近似求解方法,同时展示四种展开波函数的方法,其中包括Bsplines技术的应用.     

硫化物标准溶液配制及其稳定性研究

本文采用去离子除氧水，由淀粉-醋酸锌-氯化钠-硫化钠等配制了硫化物标准溶液．实验结果表明，该法配制的硫化物标准溶液，室温下可稳定保存3个月，浓度基本不变，解决了硫化物标准溶液只能现配现标现用的稳定性问题．     

恒定电场对氢键系统中质子传递影响的计算机模拟

氢键系统大量存在于生命系统中,研究氢键结构及其特性对于揭示生命的奥秘具有重要的意义.用四阶Runge-Kutta方法数值分析了在恒定外场影响下氢键系统中的质子传递.结果表明恒定外场能够改变质子的传递速度,但质子仍能够稳定传递.