废催化剂回收利用的方法和现状分析

本文首先介绍了废催化剂回收利用的重要意义和现状,然后着重介绍了含贵金属系废催化荆、含钼废催化剂和含钴废催化剂的回收方法和技术。     

用Cl-P_(204)萃淋树脂分离分光光度法测定高钼低铼溶液中的铼

研究了Cl－P_(204)萃淋树脂分离高含量钼溶液中微量铼的性能和条件．建立了一种在高钼低铼下，树脂柱分离硫脲显色分光光度法测定微量铼的方法．     

钼蓝比色法测定不同种质何首乌磷脂的含量

目的:探索何首乌的品种选育和质量控制的方法。方法:用钼蓝比色法测定不同种质何首乌的磷脂含量并对结果进行分析。结果:测定的37份不同种质何首乌其磷脂含量差异显著。结论:可利用钼蓝比色法对何首乌的磷脂进行含量测定。     

单纯形优化的示波电位催化动力学法测定痕量钼

Under the optimum experimental conditions (i. e. ,pH = 1.6, cKI = 10.6 mmol/L, cH2O2 = 5.4 mmol/L, cC6H8O6 = 1.30mmol/L) derived from simplex operations, trace molybdenum(Ⅵ) was determined through the agency of its catalytic effect on the reaction of H2O2 with I- in acid medium. The detection limit and linear calibration range of molybdenum were obtained as 0.5 × 10-6 mol/L and 0.5 × 10- 6 ～ 120 × 10- 6 mol/L respectively. This method was appli ed to the examination of the industrial waste water, and the recovery ratios were found to be in the range of 101% and 107%.     

兰家沟钼矿成矿热力学参数研究

成矿热力学参数是矿床成因研究的重要内容,共生的矿物必然能共同反映其形成时的成矿热力学环境。基于此,通过分析兰家沟钼矿不同成矿阶段的矿物共生组合,利用流体包裹体测定不同成矿阶段的成矿温度和压力范围,并基于热力学计算获得不同成矿阶段的矿物共生组合相图,进而得到兰家沟钼矿床3个成矿阶段的成矿热力学参数。在石英斑晶阶段,氧逸度的区间范围为10^-40~10^-25,硫逸度的区间范围为10^-40~10^-5。在斑岩型矿化阶段,pH值为6.9~6.1,氧化还原电位在-1.3~0.3 V。在石英大脉型矿化阶段,氧逸度应小于10^-13,硫逸度为10^-14~10^-6,矿床的成矿环境属于弱还原环境。这些研究结果有助于对兰家沟钼矿成矿环境的认识。     

Selective electrochemical production of hydrogen peroxide at zigzag edges of exfoliated molybdenum telluride nanoflakes

The two-electron reduction of molecular oxygen represents an effective strategy to enable the green, mild and on-demand synthesis of hydrogen peroxide. Its practical viability, however, hinges on the development of advanced electrocatalysts, preferably composed of non-precious elements, to selectively expedite this reaction, particularly in acidic medium. Our study here introduces 2H-MoTe₂ for the first time as the efficient non-precious-metal-based electrocatalyst for the electrochemical production of hydrogen peroxide in acids. We show that exfoliated 2H-MoTe₂ nanoflakes have high activity (onset overpotential ∼140 mV and large mass activity of 27 A g⁻¹ at 0.4 V versus reversible hydrogen electrode), great selectivity (H₂O₂ percentage up to 93%) and decent stability in 0.5 M H₂SO₄. Theoretical simulations evidence that the high activity and selectivity of 2H-MoTe₂ arise from the proper binding energies of HOO^* and O^* at its zigzag edges that jointly favor the two-electron reduction instead of the four-electron reduction of molecular oxygen.     

低品位钼镍矿中钼浸出试验的研究

对难选镍钼多金属矿进行了湿法工艺浸出试验研究。对纯碱用量、片碱用量、浸出液固比、浸出时间、浸出温度等条件进行了试验研究,确定了各个因素最佳条件:在碱性条件下、液固比为3∶1、温度90℃条件下浸出时间3h后,钼的浸出率达96%。     

氮化钼上肉桂醛的选择加氢

本文研究了Mo2N和Mo2N/Al2O3上肉桂醛选择加氢反应特性,并与Co/Al2O3进行了比较.结果表明,影响肉桂醛加氢的主要因素是肉桂醛在催化剂上的吸附和反应物的使用时间.使用新鲜原料时,Mo2N/Al2O3与Co/Al2O3上肉桂醛选择加氢反应性能相当,具有很高的C=O键加氢选择性.423K时,在反应原料使用较长时间后,由于吸收空气中的氧,反应过程中使Mo2N催化剂表面氧化而使其丧失C=O键选择加氢能力.     

碳化钼催化剂的制备及二苯并噻吩加氢脱硫性能

以MoO3为前躯体,正己烷/H2混合物为还原碳化气,采用程序升温碳化反应方法,在不同碳化温度和不同碳源进料速率的条件下碳化制备出碳化钼催化剂,并用XRD进行表征,同时研究了制备出来的碳化物催化剂对二苯并噻吩的加氢脱硫活性.结果表明:程序升温碳化反应到650℃,采用正己垸为碳化原料是可行的,且在适当的正己烷和H2物质的量比的条件下能够制备出高度分散并且对二苯并噻吩具有较高加氢脱硫活性的负载型碳化钼催化剂.     

ICP-MS快速测定地质样品中的铀、钍、钨、钼

建立一种使用电感耦合等离子体质谱仪快速测定地质样品中的铀、钍、钨、钼元素的方法.实验表明铀、钍、钨、钼检出限分别为：0.03,0.02,0.05,0.03μg/g.四种元素相对标准偏差均小于10%,测定值均与推荐值吻合.该法适于大批量地质样品中铀、钍、钨、钼同时快速测定.